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ChemCatChem, ISSN 1867-3880, 07/2018, Volume 10, Issue 14, pp. 3096 - 3106
We report a combined experimental and computational investigation of the Suzuki–Miyaura cross‐coupling of amides enabled by [Pd(NHC)(allyl)Cl] precatalysts.... 
reaction mechanisms | density functional calculations | palladium | amides | cross-coupling reactions | C-N | CHEMISTRY, PHYSICAL | N-HETEROCYCLIC CARBENES | SUPPORTED PRECATALYSTS | GENERAL-METHOD | BUCHWALD-HARTWIG | SECONDARY AMIDES | ZETA VALENCE QUALITY | PD-NHC PRECATALYST | BASIS-SETS | ARYL CHLORIDES | Amides | Palladium
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 10/2018, Volume 51, Issue 10, pp. 2589 - 2599
Conspectus Transition-metal-catalyzed cross-coupling reactions represent a most powerful tool for the rapid construction of C–C and C–X bonds available to... 
ROOM-TEMPERATURE | ELECTRONICALLY-ACTIVATED AMIDES | BUCHWALD-HARTWIG | ARYL ESTERS | HETEROCYCLIC CARBENE COMPLEXES | ORGANOMETALLIC CHEMISTRY | PD-NHC PRECATALYST | STERIC PROPERTIES | CHEMISTRY, MULTIDISCIPLINARY | SUZUKI-MIYAURA | GENERAL-METHOD
Journal Article
Russian Chemical Reviews, ISSN 0036-021X, 2017, Volume 86, Issue 6, pp. 459 - 473
One of the topical research areas dealing with Pd-catalyzed cross-coupling reactions is the development of regenerable catalytic systems through immobilization... 
ORGANIC-SYNTHESIS | N-HETEROCYCLIC CARBENE | AQUEOUS-MEDIUM | PD-NHC | C-C | HETEROGENEOUS RECYCLABLE CATALYST | MIZOROKI-HECK | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | METAL-COMPLEXES
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 05/2019, Volume 21, Issue 9, pp. 3304 - 3309
A general class of well-defined, air-stable, and readily available Pd(II)-NHC precatalysts (NHC = N-heterocyclic carbene) for Suzuki and Buchwald-Hartwig... 
KETONE SYNTHESIS | MIYAURA | HETEROCYCLIC CARBENE COMPLEXES | TWISTED AMIDES | BONDS | CHEMISTRY, ORGANIC | PD-NHC PRECATALYST | CLEAVAGE | DESIGNING PD | PEPPSI | GENERAL-METHOD
Journal Article
Organic Letters, ISSN 1523-7060, 12/2018, Volume 20, Issue 23, pp. 7563 - 7566
Direct transamidation of secondary amides was developed via nickel catalysis. In the presence of trimethylsilyl chloride and manganese, Ni­(diglyme)­Cl2 with a... 
ACTIVATION | LIGANDS | CONVERSION | ESTERS | CHEMISTRY, ORGANIC | PD-NHC PRECATALYST | DERIVATIVES | DISCOVERY | PEPPSI | CARBOXYLIC-ACIDS | GENERAL-METHOD
Journal Article
Organic Letters, ISSN 1523-7060, 12/2017, Volume 19, Issue 24, pp. 6510 - 6513
A general, highly selective method for the room temperature Suzuki–Miyaura cross-coupling of commonly encountered primary benzamides is reported. A combination... 
COOPERATIVE CATALYSIS | KETONE SYNTHESIS | C-N | BUCHWALD-HARTWIG | NICKEL CATALYSIS | N BOND ACTIVATION | HETEROCYCLIC CARBENE COMPLEXES | TWISTED AMIDES | CHEMISTRY, ORGANIC | PD-NHC PRECATALYST | DIARYL KETONE
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 08/2018, Volume 83, Issue 15, pp. 7622 - 7632
Rationally designed fluorene-based mono- and bimetallic Pd–PEPPSI complexes were synthesized and demonstrated to be effective for the one-pot sequential... 
CROSS-COUPLING REACTIONS | LIGANDS | ARYLATION | CONSTRUCTION | COMPLEXES | CHEMISTRY, ORGANIC | PD-NHC PRECATALYST | N-HETEROCYCLIC CARBENES | ARYL CHLORIDES | AMIDES | ALKALOIDS
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 02/2018, Volume 16, Issue 8, pp. 1322 - 1329
The development of new transamidation reactions for the synthesis of amides is an important and active area of research due to the central role of amide... 
Journal Article
Organic Letters, ISSN 1523-7060, 05/2018, Volume 20, Issue 10, pp. 2976 - 2979
A protocol for the nickel-catalyzed alkylation of amides was established. The use of alkylboranes as nucleophilic partners allowed the use of mild reaction... 
DECARBONYLATIVE SILYLATION | ELECTRONICALLY-ACTIVATED AMIDES | KETONE SYNTHESIS | SECONDARY AMIDES | CARBON-NITROGEN BOND | CLEAVING ALKYLATION | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | PD-NHC PRECATALYST | GENERAL-METHOD | ALKYL-HALIDES
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 06/2018, Volume 2018, Issue 20-21, pp. 2352 - 2365
Journal Article
ACS Catalysis, ISSN 2155-5435, 02/2018, Volume 8, Issue 2, pp. 1003 - 1008
We report the Ni-catalyzed Suzuki–Miyaura coupling of aliphatic amide derivatives. Prior studies have shown that aliphatic amide derivatives can undergo... 
cross-coupling | nickel | catalysis | aliphatic | amides | ORGANOBORON COMPOUNDS | ROOM-TEMPERATURE | CHEMISTRY, PHYSICAL | DECARBONYLATIVE CYANATION | ARYLBORONIC ACIDS | ELECTRONICALLY-ACTIVATED AMIDES | KETONE SYNTHESIS | N-C CLEAVAGE | CARBON-NITROGEN BOND | PD-NHC PRECATALYST | ACYL-TRANSFER REAGENTS
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2018, Volume 16, Issue 8, pp. 1322 - 1329
The development of new transamidation reactions for the synthesis of amides is an important and active area of research due to the central role of amide... 
PRIMARY CARBOXAMIDES | C CLEAVAGE | EFFICIENT CATALYST | SECONDARY AMIDES | TWISTED AMIDES | ESTERS | CHEMISTRY, ORGANIC | DECARBONYLATIVE CYANATION | PD-NHC PRECATALYST | AMIDE BOND FORMATION | CATALYZED TRANSAMIDATION | Amides | Amines | Chemical synthesis | Metals | Functional groups | Reagents
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 03/2019, Volume 48, Issue 10, pp. 3214 - 3222
We report the preparation and full characterization of a series of hydroxyl functionalized 1,2,3-triazolylidene- based PEPPSI complexes 2a-c and their... 
ORTHO-SUBSTITUTED BIARYLS | ROOM-TEMPERATURE | PALLADIUM COMPLEXES | C-N | MIYAURA | HETEROCYCLIC CARBENE COMPLEXES | LIGANDS SYNTHESIS | PD-NHC PRECATALYST | ARYL CHLORIDES | HIGHLY EFFICIENT | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
TETRAHEDRON, ISSN 0040-4020, 11/2018, Volume 74, Issue 47, pp. 6829 - 6838
A series of N-aryl (2a,b) or benzyl (2c,d) substituted piperidoimidazolinium salts and their palladium complexes (3a-d) were prepared and characterized by H-1,... 
NHC COMPLEXES | PEPPSI-Pd-NHC | HETEROCYCLIC CARBENE LIGANDS | PD-PEPPSI-IPENT | REACTIVITY | CHEMISTRY, ORGANIC | Palladium | Suzuki-miyaura coupling | DFT calculations | SUZUKI-MIYAURA | Piperidoimidazolin-2-ylidene | CROSS-COUPLING REACTIONS | AMINATION | RESTRICTED FLEXIBILITY | ARYL CHLORIDES | PRECATALYST
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 07/2019, Volume 2019, Issue 27, pp. 4357 - 4361
The first fluoride and palladium co‐catalyzed conversion of amide to ester through an aerobic oxidative coupling pathway is reported. This new approach... 
Cooperative catalysis | Amides | Palladium | Fluorides | Aerobic oxidative coupling | EFFICIENT SYNTHESIS | ESTERIFICATION | CHEMISTRY, ORGANIC | METAL-FREE TRANSAMIDATION | BOND-CLEAVAGE | GENERAL-METHOD | DECARBONYLATIVE BORYLATION | ELECTRONICALLY-ACTIVATED AMIDES | SECONDARY AMIDES | N-C CLEAVAGE | PD-NHC PRECATALYST | Catalysis
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2019, Volume 25, Issue 11, pp. 2663 - 2674
Journal Article