X
Search Filters
Format Format
Subjects Subjects
Subjects Subjects
X
Sort by Item Count (A-Z)
Filter by Count
pentacoordinate (345) 345
chemistry, inorganic & nuclear (281) 281
chemistry, organic (232) 232
reactivity (182) 182
silicon (161) 161
pentacoordinate silicon (156) 156
chemistry (136) 136
chemistry, multidisciplinary (136) 136
complexes (90) 90
crystal-structure (83) 83
molecular-structure (70) 70
stereochemistry (63) 63
chemistry, physical (56) 56
derivatives (53) 53
hexacoordinate silicon-compounds (52) 52
coordination (51) 51
silicon-compounds (50) 50
hexacoordinate silicon (44) 44
bond (41) 41
silicates (41) 41
nucleophilic-substitution (40) 40
ligands (37) 37
nmr (35) 35
analysis (31) 31
crystal (31) 31
stabilized silyl cations (31) 31
electronic-structure (30) 30
organosilicon compounds (30) 30
crystal-structures (28) 28
structural-characterization (27) 27
ab-initio (26) 26
chemistry/food science, general (26) 26
pentacoordinate silicon-compounds (26) 26
molecules (25) 25
silatranes (24) 24
aldehydes (23) 23
si-29 nmr (23) 23
catalysis (22) 22
exchange (22) 22
hexacoordinate (22) 22
hypercoordination (22) 22
pentacoordinate silicon complexes (22) 22
synthesis (22) 22
solid-state (21) 21
ligand (20) 20
organic chemistry (20) 20
organo-silicon compounds (20) 20
rearrangement (20) 20
research (20) 20
silanes (20) 20
spectroscopy (20) 20
crystallography (19) 19
gas-phase (19) 19
neutral hexacoordinate (19) 19
phosphorus (19) 19
silane (19) 19
carbonyl-compounds (18) 18
crystal structure (18) 18
hypervalent silicon (18) 18
inorganic chemistry (18) 18
molecular structure (18) 18
x-ray structure (18) 18
chemical properties (17) 17
nmr spectroscopy (17) 17
pentacoordinate allylsilicates (17) 17
substitution (17) 17
amides (16) 16
penta-coordinated molecules (16) 16
physics, atomic, molecular & chemical (16) 16
chelates (15) 15
coordination chemistry (15) 15
germanium (15) 15
intramolecular coordination (15) 15
nuclear magnetic resonance spectroscopy (15) 15
silicon compounds (15) 15
structure (15) 15
x-ray-structure (15) 15
hydrolysis (14) 14
k ee chemistry, organic (14) 14
organic-synthesis (14) 14
reagents (14) 14
salts (14) 14
sio2 (14) 14
solid-state structures (14) 14
atoms (13) 13
carbon (13) 13
physical chemistry (13) 13
tin (13) 13
x-ray (13) 13
anions (12) 12
chirality (12) 12
geochemistry & geophysics (12) 12
hypervalent compounds (12) 12
lambda-5-spirosilicate (12) 12
mechanism (12) 12
stereodynamics (12) 12
thermolysis (12) 12
usage (12) 12
acid (11) 11
behavior (11) 11
more...
Language Language
Publication Date Publication Date
Click on a bar to filter by decade
Slide to change publication date range


Journal of Computational Chemistry, ISSN 0192-8651, 10/2015, Volume 36, Issue 28, pp. 2095 - 2102
The recently postulated concept of “ultrastability” and “electron‐deficient aromaticity” (Vach, Nano Lett 2011, 11, 5477; Vach, J Chem Theory Comput 2012, 8,... 
silicon nanoclusters | ab initio calculations | prismanes | strain energy | silicon hydrides | CARBON | ANALOGS | REACTIVITY | TRIPLE BOND | CUBANE | CHEMISTRY, MULTIDISCIPLINARY | MOLECULES | DENSITY | AROMATICITY | HEXASILABENZENE | PENTACOORDINATE | Methane | Silicon | Analysis | Silane
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2014, Volume 20, Issue 39, pp. 12411 - 12415
Reaction of the donor‐stabilized silylene 1 (which is three‐coordinate in the solid state and four‐coordinate in solution) with BEt3 and BPh3 leads to the... 
Lewis acids | silicon | bonding analysis | boron | coordination chemistry | Lewis bases | REACTIVITY | STRUCTURAL-CHARACTERIZATION | CHEMISTRY, MULTIDISCIPLINARY | SILYLENE | METAL-CARBONYL-COMPLEXES | LIGAND | DENSITY-FUNCTIONAL THEORY | BOND | PENTACOORDINATE SILICON(IV) COMPLEXES | Crystal structure | Silicon compounds | Lewis acid | Solid state | Spectroscopy | Quantum chemistry | Formations | Bonding
Journal Article
Inorganic Chemistry Communications, ISSN 1387-7003, 02/2018, Volume 88, pp. 11 - 20
The review essentially highlights the chronological development in organosilicon chemistry. The versatile application of silicon in organic, coordination,... 
Organosilicon | Click silylation | Higher coordinate silicon | Silatranes | TRANSANNULAR INTERACTION | MOLECULAR-STRUCTURE | HYDROSILYLATION | SILATRANE DERIVATIVES | CRYSTAL-STRUCTURES | CHEMISTRY, INORGANIC & NUCLEAR | N-METHYL | PENTACOORDINATE SILICON | ALUMATRANE | TRIS(2-HYDROXYETHYL)AMINE | SOL-GEL PROCESS | Silicon | Silane
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 12/2019, Volume 903, p. 120997
The preparation and structures of 6,6-diorganylbenzo[d,h][1,3,6,7,2]dioxadiazasilonines containing the N→Si intramolecular dative bond are described. The... 
Si containing azobenzene | Pentacoordinate silicon | NMR | X-ray | DYES | MOLECULAR-STRUCTURE | IV) COMPLEXES | CHEMISTRY, ORGANIC | X-RAY-DIFFRACTION | STRUCTURAL-CHARACTERIZATION | CRYSTAL | SPECTRAL CHARACTERIZATION | SOLID-STATE | CHEMISTRY, INORGANIC & NUCLEAR | TRIDENTATE DIANIONIC O | AZOBENZENE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 13, pp. 4304 - 4307
Intramolecular isomerization in pentacoordinate compounds can play an essential role for the adjustment of defined stereochemical information. Here, we present... 
ASYMMETRIC-SYNTHESIS | ENANTIOSELECTIVE SYNTHESIS | KINETIC RESOLUTION | COMPLEXES | STEREOCHEMISTRY | HYDROSILYLATION | REACTIVITY | PENTACOORDINATE | INVERSION | CHEMISTRY, MULTIDISCIPLINARY | METATHESIS | Substitution reactions | Silicon | Research | Chemical properties | Chirality
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2014, Volume 20, Issue 31, pp. 9620 - 9626
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2017, Volume 23, Issue 70, pp. 17764 - 17774
Journal Article
Helvetica Chimica Acta, ISSN 0018-019X, 01/2020, Volume 103, Issue 1, p. n/a
Nowadays, the quest of new radical precursors based on heteroatom complexes occupies an increasingly prominent position in contemporary research. Herein, we... 
chlorosilane | photoreduction | silylium | radicals | cyclic voltammetry | hypercoordinated silicon compounds | allylation | C−S bond | C-S bond | OXIDATION | ACTIVATION | REAGENTS | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS | SILICATES | GENERATION | PENTACOORDINATE | (TMS)SIH | Pyridines | Photocatalysis | Computer applications | Irradiation | Silicon | Sulfur | Fragmentation
Journal Article
Journal of Computational Chemistry, ISSN 0192-8651, 03/2015, Volume 36, Issue 6, pp. 355 - 360
Designing and characterizing the compounds with exotic structures and bonding that seemingly contrast the traditional chemical rules are a never‐ending goal.... 
14 valence electrons | pentaatomic planar tetracoordinate silicon | a large‐scale global search | DENSITY FUNCTIONALS | a large-scale global search | COUPLED-CLUSTER SINGLES | CARBON | BORON | PENTACOORDINATE | CHEMISTRY, MULTIDISCIPLINARY | PHOTOELECTRON-SPECTROSCOPY | MP2 ENERGY | MOLECULES
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 02/2009, Volume 42, Issue 2, pp. 303 - 314
Journal Article
International Journal of Quantum Chemistry, ISSN 0020-7608, 09/2018, Volume 118, Issue 17, p. n/a
The nature of the complexes PhTH3H3ZO and PhSiF3H3ZO (T = Si, Ge, and Sn; Z = N, P, and As) has been investigated at the MP2/aug’‐cc‐pVTZ(PP) level. These... 
pentacoordinate silicon (IV) complex | tetrel bonds | N‐oxides | phenyltrifluorosilane | ab initio calculations | N-oxides
Journal Article