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DALTON TRANSACTIONS, ISSN 1477-9226, 07/2017, Volume 46, Issue 27, pp. 8751 - 8755
Treatment of SiCl4 with lithium dithiocarbamates of the formula type Li[R2NCS2] (R = Ph, iPr) in a molar ratio of 1:2 afforded the respective six-coordinate... 
TE | SE | SI | ZWITTERIONIC LAMBDA-SI-5-SILICATES | STRUCTURAL-CHARACTERIZATION | ATOMS | PENTACOORDINATE SILICON(IV) COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
International Journal of Quantum Chemistry, ISSN 0020-7608, 09/2018, Volume 118, Issue 17, p. n/a
The nature of the complexes PhTH 3 H 3 ZO and PhSiF 3 H 3 ZO (T = Si, Ge, and Sn; Z = N, P, and As) has been investigated at the MP2/aug’‐cc‐pVTZ(PP) level.... 
pentacoordinate silicon (IV) complex | tetrel bonds | N‐oxides | phenyltrifluorosilane | ab initio calculations | N-oxides
Journal Article
by Xu, HL and Cheng, JB and Li, HB and Yang, X and Li, QZ
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, ISSN 0020-7608, 09/2018, Volume 118, Issue 17
The nature of the complexes PhTH3-H(3)ZO and PhSiF3-H(3)ZO (T= Si, Ge, and Sn; Z= N, P, and As) has been investigated at the MP2/aug'-cc-pVTZ(PP) level. These... 
tetrel bonds | HYDROGEN-BOND | CENTER-DOT-O | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | CO-CRYSTALS | MOLECULES | pentacoordinate silicon (IV) complex | NONCOVALENT INTERACTION | phenyltrifluorosilane | MATHEMATICS, INTERDISCIPLINARY APPLICATIONS | ab initio calculations | DIHYDROGEN BOND | N-oxides | PHOSPHINE OXIDES | HALOGEN BOND
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 06/2007, Volume 46, Issue 13, pp. 5419 - 5424
The neutral heteroleptic hexacoordinate silicon(IV) complexes 4 and 5 (SiO6 skeletons) and the neutral pentacoordinate silicon(IV) complexes 7-9 (SiO4N... 
CRYSTALLIZATION | CYANATO-N | THIOCYANATO-N LIGANDS | BIDENTATE LIGANDS | REACTIVITY | CHELATE | STRUCTURAL-CHARACTERIZATION | BEARING | ZWITTERIONIC PENTACOORDINATE | SOLID-STATE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, ISSN 1553-3174, 02/2016, Volume 46, Issue 2, pp. 311 - 316
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 12/2005, Volume 11, Issue 24, pp. 7379 - 7386
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2014, Volume 20, Issue 31, pp. 9620 - 9626
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 04/2005, Volume 44, Issue 7, pp. 2337 - 2346
A series of novel hexacoordinate silicon(IV) complexes with an SiO2N4 skeleton (compounds (OC-6-12)-3, (OC-6-12)-4, (OC-6-12)-5, (OC-6-12)-6, and (OC-6-2 '... 
ATOMS LI | ZIRCONIUM | ANALOGS | STEREOCHEMISTRY | REACTIVITY | CRYSTAL-STRUCTURES | PENTACOORDINATE | DERIVATIVES | GAUSSIAN-BASIS SETS | ELECTRONIC-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR | Silicon compounds | Nuclear magnetic resonance spectroscopy | Usage | Research | Chemical properties | Coordination compounds
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 02/2004, Volume 43, Issue 4, pp. 1568 - 1573
Three new neutral cis-hexacoordinate bis(beta-diketonato) silicon(IV) complexes, (thd)(2)SiX2, where X = Me (1), (BuO)-Bu-t (2), and (AmO)-Am-t (3), and thd =... 
FILMS | PRECURSOR | GERMANIUM | CHEMICAL-VAPOR-DEPOSITION | LIGANDS | DIELECTRICS | REACTIVITY | PENTACOORDINATE | EXCHANGE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2014, Volume 20, Issue 39, pp. 12411 - 12415
Reaction of the donor‐stabilized silylene 1 (which is three‐coordinate in the solid state and four‐coordinate in solution) with BEt 3 and BPh 3 leads to the... 
Lewis acids | silicon | bonding analysis | boron | coordination chemistry | Lewis bases | REACTIVITY | STRUCTURAL-CHARACTERIZATION | CHEMISTRY, MULTIDISCIPLINARY | SILYLENE | METAL-CARBONYL-COMPLEXES | LIGAND | DENSITY-FUNCTIONAL THEORY | BOND | PENTACOORDINATE SILICON(IV) COMPLEXES | Crystal structure | Silicon compounds | Lewis acid | Solid state | Spectroscopy | Quantum chemistry | Formations | Bonding
Journal Article
Dalton Transactions, ISSN 1477-9226, 06/2015, Volume 44, Issue 33, pp. 14959 - 14974
The novel donor-stabilised silylene 5 was prepared in a four-step synthesis, starting from bis(2,6-diisopropylphenyl) carbodiimide (Dipp-NvCvN-Dipp), and its... 
BONDED COMPOUNDS | PHOSPHASILENE | FACILE ACCESS | PHC(NTBU)SIX X | IV) COMPLEXES | CHEMISTRY | NEUTRAL 6-COORDINATE | PENTACOORDINATE SILICON(IV) COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 2011, Volume 40, Issue 38, pp. 9844 - 9857
Journal Article
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, ISSN 1042-6507, 2012, Volume 187, Issue 3, pp. 343 - 356
Reaction of tetraethoxysilane (TEOS) with substituted catechols (I-X), 7,8-dihydroxyflavone (XI), 3,3',4'-trihydroxyflavone (XII),... 
sixcoordinate silicates | THERMOLYSIS | flavones and fluorone | STEREOCHEMISTRY | REACTIVITY | CHEMISTRY, ORGANIC | ION | CHEMISTRY, INORGANIC & NUCLEAR | REARRANGEMENT | PHCCSIF3 | Substituted catechols | Si-29 NMR | NEUTRAL HEXACOORDINATE | PENTACOORDINATE | SKELETONS
Journal Article
Dalton Transactions, ISSN 1477-9226, 08/2015, Volume 44, Issue 33, pp. 14959 - 14974
The novel donor-stabilised silylene 5 was prepared in a four-step synthesis, starting from bis(2,6-diisopropylphenyl)carbodiimide (Dipp-N&z.dbd; C&z.dbd;... 
Spectroscopy | Synthesis | Nitrous oxides | Precursors | Ligands | Bonding | Dipping | Crystal structure
Journal Article
Zeitschrift fur Anorganische und Allgemeine Chemie, ISSN 0044-2313, 2003, Volume 629, Issue 7-8, pp. 1403 - 1411
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2019, Volume 25, Issue 28, pp. 6955 - 6962
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2013, Volume 19, Issue 42, pp. 14296 - 14303
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 04/2004, Volume 357, Issue 6, pp. 1955 - 1958
Reaction of tetramethoxysilane with 1,3-diphenylpropane-1,3-dione and benzilic acid (molar ratio 1:2:1) in tetrahydrofuran/n-pentane yielded the neutral... 
Silicon | Chelates | Hexacoordination | Coordination chemistry | hexacoordination | BIS(2,4-PENTANEDIONO)DIACETATOSILICON | STEREOCHEMISTRY | REACTIVITY | STRUCTURAL-CHARACTERIZATION | SOLID-STATE | CHEMISTRY, INORGANIC & NUCLEAR | silicon | LIGANDS | coordination chemistry | chelates | PENTACOORDINATE | PI-PI INTERACTIONS
Journal Article