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chemistry, multidisciplinary (27) 27
pentavalent-uranyl (25) 25
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Chemical science (Cambridge), ISSN 2041-6520, 2017, Volume 8, Issue 1, pp. 108 - 116
The uranyl( ) complex UO Cl(L) of the redox-active diimino-dipyrrin anion, L is reported and its reactions with inner- and outer-sphere reductants studied. The... 
FUNCTIONALIZATION | OXIDE | LIGANDS | URANIUM COMPLEXES | OXO | PENTAVALENT-URANYL | COORDINATION | ION | CRYSTAL | CHEMISTRY, MULTIDISCIPLINARY | SILYLATION | Reduction | Uranium | Equivalence | Reagents | X-rays | Ligands | Crystallography | Radicals
Journal Article
Chemical science (Cambridge), ISSN 2041-6520, 2018, Volume 9, Issue 38, pp. 7520 - 7527
The tripodal heptadentate Schiff base trensal ligand allowed the synthesis and characterization of stable uranyl( ) complexes presenting UO ⋯K or UO ⋯Fe... 
URANIUM | SINGLE-MOLECULE MAGNET | OXO-GROUP | REDUCTION | COMPLEXES | CATION-CATION INTERACTIONS | PENTAVALENT-URANYL | STRUCTURAL-CHARACTERIZATION | COORDINATION | CHEMISTRY, MULTIDISCIPLINARY | CHAIN MAGNET
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2014, Volume 53, Issue 3, pp. 819 - 823
Single‐chain magnets (SCMs) are materials composed of magnetically isolated one‐dimensional (1D) units exhibiting slow relaxation of magnetization. The... 
actinides | cations | uranium | polymetallic complexes | single‐chain magnets | single-chain magnets | COMPLEX | BEHAVIOR | COMPOUND | REACTIVITY | ION | CHEMISTRY, MULTIDISCIPLINARY | PENTAVALENT URANYL | DYNAMICS | MOLECULE-MAGNET | COMMUNICATION | CYANIDE | Communications
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2015, Volume 51, Issue 56, pp. 11309 - 11312
A 1D zig-zag coordination polymer based on a cation–cation [(U O )Mn ] repeated unit shows single chain magnet (SCM) behaviour with a high energy barrier of... 
URANIUM(III) COMPLEXES | BEHAVIOR | CATION-CATION INTERACTIONS | REACTIVITY | ION | MOLECULE-MAGNET | MODEL | ANISOTROPY | CHEMISTRY, MULTIDISCIPLINARY | COMMUNICATION | PENTAVALENT URANYL | Coordination polymers | Synthesis | Barriers | Cationic polymerization | Chains (polymeric) | Magnetic properties | Structural analysis | Physics
Journal Article
Nature (London), ISSN 0028-0836, 2008, Volume 451, Issue 7176, pp. 315 - 317
Uranium occurs in the environment predominantly as the uranyl dication [UO2](2+). Its solubility renders this species a problematic contaminant(1-3) which is,... 
URANIUM | LIGANDS | ACTIVE-SITES | MULTIDISCIPLINARY SCIENCES | COMPLEXES | REACTIVITY | CHEMISTRY | PENTAVALENT-URANYL | COORDINATION | OXYGENATION REACTIONS | BASE | Oxidation-reduction reaction | Cations | Research | Structure | Chemical bonds | Chemistry | Uranium | Chemical compounds | Innovations | Reduction | Covalence | Transition metals | Contaminants | Solubility | Radicals | Covalent bonds
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2012, Volume 51, Issue 50, pp. 12584 - 12587
Switching on uranium(V) reactivity: The silylated uranium(V) dioxo complex [(Me3SiOUO)2(L)2] (A) is inert to oxidation, but after two‐electron reduction to... 
actinides | uranium | Schiff base macrocycles | silylation | uranyl complexes | OXYGEN-EXCHANGE | ACTIVATION | DISPROPORTIONATION | CAGE CLUSTERS | COMPLEXES | PENTAVALENT-URANYL | COORDINATION | CHEMISTRY, MULTIDISCIPLINARY | ACTINYL IONS | ELECTRONIC-STRUCTURE | Schiff bases | Uranium
Journal Article
Chemical Communications, ISSN 1359-7345, 2009, Issue 17, pp. 2402 - 2404
A DFT study of the reduction and silylation of the uranyl U-O bond in a macrocyclic complex shows the importance of the initial dipotassiation in THF solution,... 
URANIUM | OXIDE | MECHANISM | COMPLEXES | CHEMISTRY | PENTAVALENT-URANYL | COORDINATION | CP2UO | CHEMISTRY, MULTIDISCIPLINARY | ACTINYL IONS
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 36, pp. 10775 - 10779
The reduction of UVI uranyl halides or amides with simple LnII or UIII salts forms highly symmetric, linear, oxo‐bridged trinuclear UV/LnIII/UV,... 
molecular magnetism | f-block chemistry | reduction | uranyl complexes | lanthanides | URANIUM | PENTAVALENT-URANYL | COORDINATION | ION | CHEMISTRY, MULTIDISCIPLINARY | SILYLATION | FUNCTIONALIZATION | MAGNET | OXO-GROUP | PACMAN COMPLEXES | LIGAND | Halides | Magnetism | Reduction | Salts | Electronic structure | Uranium | Amides | Chains (polymeric) | Polymers | Communications | Communication
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2016, Volume 22, Issue 34, pp. 11954 - 11957
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2016, Volume 55, Issue 46, pp. 14325 - 14329
Actinide oxo clusters are an important class of compounds due to their impact on actinide migration in the environment. The photolytic reduction of uranyl(VI)... 
actinides | cluster compounds | pentavalent uranyl | uranium | uranyl compounds | OXIDATION | DISPROPORTIONATION | CRYSTAL-STRUCTURE | BOND-VALENCE PARAMETERS | CHEMISTRY, MULTIDISCIPLINARY | SILYLATION | KINETICS | PENTAVALENT-URANIUM | OXO COMPLEXES | BIOREDUCTION | PEROXIDE | Nuclear industry | Nuclear energy | Spent reactor fuels | Uranium | Reactor fuel reprocessing | Chemical properties | Catalysis
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2011, Volume 50, Issue 40, pp. 9456 - 9458
New bonds for the uranyl: The controlled conversion of an uranyl oxo group ([UO2]+) into covalently bonded UOH and UOSi groups is described for pentavalent... 
actinides | uranyl hydroxide | oxo functionalization | pentavalent uranyl | schiff‐base macrocycle | schiff-base macrocycle | OXYGEN-EXCHANGE | CATALYSIS | ACTIVATION | INFRARED-SPECTROSCOPY | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | DICATION | REDUCTION | LIGAND | LEWIS-ACID COORDINATION | HYDROXIDE
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 2016, Volume 45, Issue 40, pp. 15910 - 15921
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2013, Volume 19, Issue 51, pp. 17528 - 17540
Journal Article