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ACCOUNTS OF CHEMICAL RESEARCH, ISSN 0001-4842, 08/2017, Volume 50, Issue 8, pp. 1838 - 1846
The carbonyl group holds a prominent position in chemistry and biology not only because it allows diverse transformations but also because it supports key... 
PRO AMIDE BONDS | SIDE-CHAINS | PI-ASTERISK INTERACTION | CRYSTAL-STRUCTURE | COLLAGEN TRIPLE-HELIX | CARBONYL-CARBONYL INTERACTIONS | PEPTIDE-BOND ISOSTERES | CONFORMATIONAL STABILITY | CHEMISTRY, MULTIDISCIPLINARY | ALPHA-HELICES | HYDROGEN-BONDS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2018, Volume 140, Issue 2, pp. 727 - 734
Since the seminal studies by Pauling in 1930s, planarity has become the defining characteristic of the amide bond. Planarity of amides has central implications... 
STEREOCHEMICAL INFORMATION | COOPERATIVE CATALYSIS | KETONE SYNTHESIS | CHEMICAL DRIVING-FORCE | CRYSTAL-STRUCTURE | N-C CLEAVAGE | ACYL TRANSFER | PEPTIDE-BOND | QUANTITATIVE SCALE | CHEMISTRY, MULTIDISCIPLINARY | BRIDGEHEAD BICYCLIC LACTAMS
Journal Article
SCIENCE, ISSN 0036-8075, 11/2005, Volume 310, Issue 5749, pp. 827 - 834
We describe two structures of the intact bacteria[ ribosome from Escherichia coli determined to a resolution of 3.5 angstroms by x-ray crystallography. These... 
TRANSLOCATION | AMINOACYL-TRANSFER-RNA | MESSENGER-RNA | CRYOELECTRON MICROSCOPY | MULTIDISCIPLINARY SCIENCES | ESCHERICHIA-COLI | PEPTIDE-BOND FORMATION | CRYO-EM | ELONGATION-FACTOR G | PROTEIN-SYNTHESIS | SUBUNIT
Journal Article
MOLECULAR CELL, ISSN 1097-2765, 07/2013, Volume 51, Issue 1, pp. 35 - 45
Translation factor elF5A, containing the unique amino acid hypusine, was originally shown to stimulate Met-puromycin synthesis, a model assay for peptide bond... 
EF-P | MESSENGER-RNA | CRYSTAL-STRUCTURE | BIOCHEMISTRY & MOLECULAR BIOLOGY | PEPTIDE-BOND FORMATION | SYNTHESIS INITIATION-FACTORS | TRANSFER-RNA | PROTEIN-SYNTHESIS | SACCHAROMYCES-CEREVISIAE | ELONGATION-FACTOR-P | 70S RIBOSOME | CELL BIOLOGY
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2016, Volume 81, Issue 23, pp. 11548 - 11555
Amides are unquestionably one of the most important functional groups in organic chemistry because of their presence in numerous interesting molecules such as... 
LEWIS-ACID CATALYST | ROOM-TEMPERATURE | SOLVENT-FREE CONDITIONS | BASE-FREE CONDITIONS | EFFICIENT RECYCLABLE CATALYST | PEPTIDE-BOND FORMATION | CHEMISTRY, ORGANIC | IONIC LIQUIDS | DIRECT AMIDATION | ALDOXIMES REARRANGEMENT | CARBOXYLIC-ACIDS | Amides | Research | Chemical properties | Carboxylic acids | Chemical synthesis
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 10/2015, Volume 137, Issue 40, pp. 12997 - 13006
The peptide bond formation with the amino acid praline (Pro) on the ribosome is slow, resulting in translational stalling when several Pro have to be... 
SITE | FACTOR EF-P | AMINOACYL-TRANSFER-RNA | MECHANISM | CIS-TRANS ISOMERIZATION | STABILITY | PEPTIDE-BOND FORMATION | TRANSLATION | PROTEINS | CHEMISTRY, MULTIDISCIPLINARY | PROLINE RESIDUES
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 07/2014, Volume 16, Issue 13, pp. 3421 - 3423
An n ->pi* interaction stems from the delocalization of the electron pair (n) of a donor group into the antibonding orbital (pi*) of a carbonyl group.... 
REACTION PATHS | SUBSTITUENTS | CHEMISTRY, ORGANIC | CONFORMATIONAL STABILITY | PEPTIDE-BOND | PYRAMIDALIZATION | INTERMOLECULAR INTERACTIONS | HYDROGEN-BONDS | AMIDES
Journal Article
Nature Communications, ISSN 2041-1723, 07/2016, Volume 7, Issue 1, p. 12026
Nascent polypeptides can induce ribosome stalling, regulating downstream genes. Stalling of ErmBL peptide translation in the presence of the macrolide... 
TRANSFERASE CENTER | ANTIBIOTICS | TRANSFER-RNA ACCOMMODATION | STRUCTURAL BASIS | ACTIVE-SITE | MULTIDISCIPLINARY SCIENCES | RESOLUTION | PEPTIDE-BOND FORMATION | PROTEIN-SYNTHESIS | POSTTRANSCRIPTIONAL MODIFICATION | RIBOSOME
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 11/2017, Volume 53, Issue 94, pp. 12700 - 12703
We measured the binding energy and bonding parameters between model nucleotide functional groups and model clay mineral surfaces in solutions of acidic pH. We... 
Journal Article
CHEMISTRY-A EUROPEAN JOURNAL, ISSN 0947-6539, 04/2014, Volume 20, Issue 14, pp. 3894 - 3897
Complexes comprising the Lewis acidic Zr-IV metal and protein binding polyoxotungstate ligands of Lindqvist-, Keggin- and Wells-Dawson-type were found to... 
MOLECULAR-INTERACTIONS | CATALYSIS | WELLS-DAWSON | SPECIFICITY | CHEMISTRY, MULTIDISCIPLINARY | NUCLEOSIDE TRIPHOSPHATE DIPHOSPHOHYDROLASE | PEPTIDE-BOND HYDROLYSIS | SPECTROSCOPY | polyoxometalates | NEUTRAL PH | metalloproteases | INHIBITORS | KEGGIN-TYPE POLYOXOMETALATE | human serum albumin | hydrolysis
Journal Article
Journal of Biomolecular NMR, ISSN 0925-2738, 10/2002, Volume 24, Issue 2, pp. 149 - 154
Journal Article
The Journal of Physical Chemistry B, ISSN 1520-6106, 02/2009, Volume 113, Issue 5, pp. 1253 - 1272
Hybrid quantum mechanical/molecular mechanical (QM/MM) approaches have been used to provide a general scheme for chemical reactions in proteins. However, such... 
PROTON-TRANSFER REACTIONS | QUANTUM-MECHANICAL CALCULATIONS | MULTICONFIGURATION MOLECULAR-MECHANICS | HYDRATION FREE-ENERGY | DENSITY-FUNCTIONAL CALCULATIONS | PEPTIDE-BOND FORMATION | CHEMISTRY, PHYSICAL | PHOTOSYNTHETIC REACTION-CENTER | DNA-POLYMERASE-BETA | TRANSITION-STATE THEORY | CHEMICAL-PROCESSES
Journal Article
Chemical Communications, ISSN 1359-7345, 2015, Volume 51, Issue 29, pp. 6395 - 6398
N-Protonation of amides is critical in numerous biological processes, including amide bonds proteolysis and protein folding as well as in organic synthesis as... 
Journal Article
JOURNAL OF PHYSICAL CHEMISTRY B, ISSN 1520-6106, 02/2019, Volume 123, Issue 8, pp. 1808 - 1814
The hydration of N-methylacetamide (NMA) in solution has been determined by neutron diffraction with isotopic Hydrogen/Deuterium substitution (NDIS), augmented... 
AB-INITIO | FREQUENCY | LIQUID WATER | GAS-PHASE | CHEMISTRY, PHYSICAL | PEPTIDE-BOND | AMIDE-I MODE | MOLECULAR-DYNAMICS SIMULATION | SOLVATION | TRANS | HYDRATION
Journal Article
ACCOUNTS OF CHEMICAL RESEARCH, ISSN 0001-4842, 04/2013, Volume 46, Issue 4, pp. 1039 - 1049
Proline residues have unique roles in protein folding, structure, and function. Proline and the aromatic amino acids comprise the encoded cyclic protein... 
PROTEIN STRUCTURES | CIS-TRANS ISOMERISM | PI INTERACTION | PRO PEPTIDE-BOND | CRYSTAL-STRUCTURES | BIOLOGICAL RECOGNITION | SH3 DOMAINS | PANCREATIC TRYPSIN-INHIBITOR | WATER SOLUTION | LINEAR PEPTIDES | CHEMISTRY, MULTIDISCIPLINARY | Analysis | Proline | Amino acids | Research | Structure | Properties | Protein-protein interactions | Proteins | Residues | Charging | Hydrogen | Amides | Polarity
Journal Article
RSC Advances, ISSN 2046-2069, 2015, Volume 5, Issue 113, pp. 93248 - 93251
A simple, solvent-free methodology is reported for the direct conversion of esters to amides using lithium hydroxide as a catalyst. The approach allows for the... 
PEPTIDE-BOND FORMATION | ACIDS | CHEMISTRY, MULTIDISCIPLINARY | DIRECT AMIDATION | TRANSFERASE
Journal Article
Journal of Bioscience and Bioengineering, ISSN 1389-1723, 09/2018, Volume 126, Issue 3, pp. 293 - 300
-Stereospecific amidohydrolase from sp. 82F2 (DAH) recognizes -amino acyl ester derivatives as substrates and catalyzes hydrolysis and aminolysis to yield... 
Aminolysis | d-Stereospecific amidohydrolase | Active site pocket | Substrate specificity | Peptide bond formation activity
Journal Article
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