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European Journal of Organic Chemistry, ISSN 1434-193X, 01/2014, Volume 2014, Issue 1, pp. 39 - 43
The ring opening of 3‐nitro‐4‐(phenylsulfonyl)thiophene with amines and proper modification of the resulting 1,3‐diene enables a simple and versatile approach... 
Peri­cyclic reactions | Synthetic methods | Sulfur heterocycles | Nitrogen heterocycles | Pericyclic reactions
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2017, Volume 56, Issue 37, pp. 11126 - 11142
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 02/2018, Volume 83, Issue 4, p. 1717
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2019, Volume 58, Issue 29, pp. 9969 - 9973
We report an unprecedented domino polycyclization from readily available 2,4‐dienals and cyclic α,β‐unsaturated imines that is initiated by an iso‐Nazarov... 
pericyclic reactions | domino reactions | diversity-oriented synthesis | polycyclization | iso-Nazarov reaction | Stereoselectivity | Imines | Organic chemistry | Chemical Sciences
Journal Article
2016, ISBN 9780128036402
Pericyclic Reactions: A Mechanistic and Problem-Solving Approach provides complete and systematic coverage of pericyclic reactions for researchers and graduate... 
Organic cyclic compounds | Chemical reactions | Pericyclic reactions
Web Resource
2016, ISBN 9780128036402
Pericyclic Reactions: A Mechanistic and Problem-Solving Approach provides complete and systematic coverage of pericyclic reactions for researchers and graduate... 
Organic cyclic compounds | Chemical reactions | Pericyclic reactions
Web Resource
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 12/2012, Volume 77, Issue 23, pp. 10824 - 10834
We analyze the error compensations that are responsible for the relatively good performance of the popular B3LYP/6-31G* model chemistry for molecular... 
DISPERSION CORRECTIONS | AUXILIARY BASIS-SETS | BENCHMARK DATABASE | AB-INITIO | PERICYCLIC-REACTIONS | REACTION ENERGETICS | CHEMISTRY, ORGANIC | NONCOVALENT INTERACTIONS | DENSITY-FUNCTIONAL THEORY | LIGAND INTERACTION ENERGIES | ACTIVATION BARRIERS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2017, Volume 56, Issue 34, pp. 10033 - 10038
High on cycloaddi(c)tions: The impact of the Woodward–Hoffmann [4n+2] rule for thermally allowed cycloaddition reactions and the challenges associated with... 
catalysis | cycloaddition | history of science | pericyclic reaction | synthetic methods | 10-MEMBERED RINGS | ORGANIC-SYNTHESIS | BENZENE PROBLEM | PERICYCLIC-REACTIONS | STEPWISE MECHANISMS | ALDOL REACTIONS | TRANSITION-STATES | CHEMISTRY, MULTIDISCIPLINARY | TROPONE | AROMATICITY | QUANTUM CONTRIBUTIONS | Cycloaddition
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2019, Volume 58, Issue 16, pp. 5338 - 5342
Complexity‐increasing Domino reactions comprising C−H allenylation, a Diels–Alder reaction, and a retro‐Diels–Alder reaction were realized by a versatile... 
pericyclic reactions | C−H activation | domino reactions | indolone alkaloids | manganese | DIRECTING GROUP | CATALYZED SYNTHESIS | ARYLATION | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | ALKENES | C-H activation | ESTERS | ACCESS | KEY | ALKENYLATION | Pyridine | Diels-Alder reaction | Pyridines | Organic chemistry | Chemical reactions | Activation | Cascade chemical reactions | Manganese | Alkynes
Journal Article
Comptes Rendus Chimie, ISSN 1631-0748, 06/2017, Volume 20, Issue 6, pp. 643 - 647
Three representative 6,7-dihydro-5H-cyclopenta[b]pyridin-4-amines were synthesized using an intramolecular inverse electron demand... 
Heterocycles | Cycloaddition | Nitrogen heterocycles | Pericyclic reactions | Alkynes
Journal Article
1977, Organic chemistry series, 35, Volume 35, 2 v. ill.
Book
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2019, Volume 58, Issue 15, pp. 5075 - 5079
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 2019, Volume 141, Issue 3, pp. 1217 - 1221
We report an ambimodal trispericyclic transition state leading to [6+4]-, [4+6]-, and [8+2]cycloadducts in the reactions of 8,8-disubstituted heptafulvenes... 
TROPONE | REARRANGEMENT | COMPLEX | BIFURCATIONS | CYCLOADDITIONS | PERICYCLIC-REACTIONS | DIMERIZATION | MECHANISMS | SELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY | TRIFURCATION
Journal Article
Angewandte Chemie-International Edition, ISSN 1433-7851, 2018, Volume 57, Issue 6, pp. 1683–1687 - 1687
The phosphorus analogues of cyclopentadienone, tricyclopentanone and housene were accessed from bis(cyclopropenyl)diphosphetanedione 3, that was prepared by... 
pericyclic reactions | main-group elements | small ring systems | valence isomerization | phosphorus | TETRA-TERT-BUTYLTETRAHEDRANE | SYSTEM | AB-INITIO | COMPLEXES | PHOSPHAALKYNE | CHEMISTRY, MULTIDISCIPLINARY | THERMAL WALK-REARRANGEMENT | SMALL RINGS | PHOSPHAETHYNOLATE | CYCLOBUTADIENES | Pyrolysis | Dioxane | Isomerization | Phosphorus | Photolysis | Sodium | Pentanone
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2019, Volume 25, Issue 57, pp. 13047 - 13047
Chlorosulfates are molecules that have been known about for over a century, though their chemistry has not evolved much since then. The transformation of... 
pericyclic reactions | density functional calculations | domino reactions | ring expansion | sulfur heterocycles
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2018, Volume 83, Issue 8, pp. 4769 - 4774
We demonstrate that the electrocyclic (EC) ring-closure of cethrene in solution proceeds in a conrotatory mode both thermally and photochemically. The facile... 
BIPHENALENYLIDENE | ELECTROCYCLIC-REACTIONS | ENERGY | CONSERVATION | PERICYCLIC-REACTIONS | ISOMERIZATION | STEREOCHEMISTRY | RADICAL CATIONS | CHEMISTRY, ORGANIC | ORBITAL SYMMETRY | FORBIDDEN
Journal Article
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2018, Volume 57, Issue 11, pp. 2754 - 2756
All roads lead to Rome: The biosynthesis of the leporins in Aspergillus sp. involves an unprecedented pericyclic reaction cascade. The enzyme LepI directs the... 
natural products | retro-Claisen rearrangement | Diels–Alder reaction | pericyclic reaction | leporin | CORE | MECHANISM | IKARUGAMYCIN | SPINOSYN | CHEMISTRY, MULTIDISCIPLINARY | ENZYME | SPNF | 4+2 CYCLOADDITION | DIELS-ALDERASE | CHEMOENZYMATIC SYNTHESIS | Diels-Alder reaction | Physiological aspects | Biosynthesis | Cycloaddition
Journal Article