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Chemical Society Reviews, ISSN 0306-0012, 4/2015, Volume 44, Issue 8, pp. 258 - 2528
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 01/2016, Volume 358, Issue 1, pp. 26 - 29
A novel selective catalytic reduction method of tertiary phosphine oxides to the corresponding phosphines has been developed. Notably, the reaction proceeds... 
organocatalysis | phosphines | phosphine⋅boranes | silanes | reduction | phosphinėboranes | CATALYTIC WITTIG REACTION | ACID | SECONDARY | CHEMISTRY, ORGANIC | BORANES | WASTE | phosphine.boranes | ESTERS | CHEMISTRY, APPLIED | Oxides | Silane | Catalysis | Reduction | Synthesis | Catalysts | Selective catalytic reduction | Phosphine oxide | Phosphines | Adducts
Journal Article
Chemistry : a European Journal, ISSN 0947-6539, 2011, Volume 17, Issue 40, pp. 11290 - 11295
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2019, Volume 25, Issue 18, pp. 4670 - 4672
Extensive DFT calculations provide detailed mechanistic insights into the metal‐free reduction of phosphine oxide Ph3P=O by using chlorination reagents O=CClX... 
phosphine | frustrated Lewis pair | phosphine oxide | hydrogenation | DFT calculations | ACCURATE | DESIGN | SECONDARY | ZETA-VALENCE QUALITY | CHEMISTRY, MULTIDISCIPLINARY | SOLVENT | CHEMISTRY | ATOMS | BASIS-SETS | Chemical tests and reagents | Hydrogenation | Reduction | Chlorination | Catalysts | Phosphine | Reagents | Carbon dioxide | Phosphine oxide | Reduction (metal working)
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2018, Volume 57, Issue 46, pp. 15253 - 15256
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2017, Volume 23, Issue 58, pp. 14434 - 14438
Reduction of phosphine oxides to the corresponding phosphines represents the most straightforward method to prepare these valuable reagents. However, existing... 
phosphine oxides | disiloxane | silane reductions | chemoselective methods | synthetic methods | CATALYTIC WITTIG REACTION | SULFIDES | SECONDARY | TERTIARY | CHEMISTRY, MULTIDISCIPLINARY | PHENYLSILANE | WASTE | CARBOXYLIC-ACIDS | Nitriles | Oxides | Aldehydes | Analysis | Silane | Carbonyl compounds | Reduction | Transformation | Phosphine | Reagents | Catalysis | Phosphines | Functional groups | Carbonyls
Journal Article
Chemical Communications, ISSN 1359-7345, 05/2015, Volume 51, Issue 37, pp. 7839 - 7842
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2013, Volume 19, Issue 42, pp. 14210 - 14214
In contrast to tertiary phosphine oxides, the deoxygenation of aminophosphine oxides is effectively impossible due to the need to break the immensely strong... 
chemoselectivity | reduction | main group elements | aminophosphine oxide | in situ protection | Main group elements | Aminophosphine oxide | Reduction | In situ protection | Chemoselectivity
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 5, pp. 535 - 538
A secondary phosphine oxide-phosphine mixed tridentate ligand and its ruthenium complex have been developed. This complex shows excellent catalytic activity... 
OXIDE LIGAND | KETONES | RUTHENIUM(II) | CHEMOSELECTIVE HYDROGENATION | TRANSITION-METAL | COMPLEXES | BOND FORMATION | ALDEHYDES | ASYMMETRIC HYDROGENATION | PRE-LIGANDS | CHEMISTRY, MULTIDISCIPLINARY | Reduction | Ruthenium | Catalytic activity | Catalysis | Coordination compounds | Aldehydes | Phosphine oxide | Ruthenium compounds | Carbonyls
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 50, pp. 15989 - 15992
A new method for the iodine‐catalyzed reduction of phosphine oxides with phosphites at room temperature is reported. The mild reaction conditions, scalability,... 
phosphines | phosphine oxides | iodine | phosphites | reduction | REAGENT | DIIODINE | TRIPHENYLPHOSPHINE | CHEMISTRY, MULTIDISCIPLINARY | DENSITY FUNCTIONALS | PHOSPHONATE | TERTIARY PHOSPHINE | DEOXYGENATION | DERIVATIVES | Oxides | Temperature requirements | Regeneration | Reduction | Purification | Phosphine | Oxygen transfer | Phosphorus | Inorganic salts | Phosphine oxide | Phosphines | Iodine
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 10/2016, Volume 57, Issue 40, pp. 4443 - 4451
[Display omitted] •Through this digest, we will summarize results on newly developed phosphine-catalyzed reactions.•Catalytic Wittig, Mitsunobu, Staudinger,... 
Reduction | Wittig | Catalysis | Staudinger | Phosphine | Silane
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 09/2018, Volume 2018, Issue 33, pp. 4614 - 4627
A series of enantiomerically enriched tertiary phosphine oxides have been prepared via the Pd‐catalyzed cross‐coupling reactions of enantiomerically pure... 
Optical activity | Ligand design | Enantioselectivity | Cross‐coupling | Phosphine oxides | Cross-coupling | ROUTE | NUCLEOPHILIC-SUBSTITUTION | ARYLATION | STEREOCHEMISTRY | CHEMISTRY, ORGANIC | CATALYZED FORMATION | ABSOLUTE-CONFIGURATION | REDUCTION | SECONDARY PHOSPHINE OXIDES | LIGAND | EFFICIENT | Oxides | Palladium | Enantiomers | Dimethyl sulfide
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2017, Volume 23, Issue 69, pp. 17463 - 17468
1,1′‐Biphenyl‐2,2′‐diphosphanes with an achiral bridge spanning C‐5 and C‐5′ form atropisomers that are enantiomers. Accessing them in an atropisomerically... 
asymmetric induction | diphosphanes | asymmetric catalysis | biaryls | atropisomerism | BIPHENYL SERIES | CATALYSIS | HYDROGENATION | ENANTIOSELECTIVE REDUCTION | CHIRALLY MODIFIED BOROHYDRIDES | BORANE | CHEMISTRY, MULTIDISCIPLINARY | KETONES | BINAP | ASYMMETRIC ALLYLIC ALKYLATION | OXIME ETHERS | Thermodynamics | Catalysis | Enantiomers | Diastereomers | Hydrogenation | Biphenyl | Ligands | Selectivity
Journal Article
Zeitschrift fur Anorganische und Allgemeine Chemie, ISSN 0044-2313, 08/2017, Volume 643, Issue 14, pp. 916 - 921
Recently, Brønsted acids, such as phosphoric acids, carboxylic acids, and triflic acid, were found to catalyze the reduction of phosphine oxides to the... 
Brønsted acid | 1,1,3,3-Tetramethyldisiloxane | Reduction | Poly(methylhydrosiloxane) | Triphenylphosphine oxide | 1,1,3,3‐Tetramethyldisiloxane | CATALYTIC WITTIG REACTION | ROOM-TEMPERATURE | Bronsted acid | MOLECULAR-STRUCTURE | SECONDARY | CRYSTAL | BORANES | CHEMISTRY, INORGANIC & NUCLEAR | ZU PHOSPHINEN
Journal Article