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phosphine-boranes (138) 138
chemistry, organic (132) 132
chemistry, multidisciplinary (94) 94
ligands (88) 88
chemistry, inorganic & nuclear (80) 80
complexes (70) 70
chemistry (56) 56
phosphine-borane (44) 44
phosphine-borane adducts (41) 41
phosphorus (41) 41
derivatives (40) 40
catalysis (39) 39
phosphine boranes (31) 31
boranes (29) 29
boron (28) 28
oxides (24) 24
phosphines (24) 24
chemistry, physical (23) 23
reactivity (23) 23
reduction (22) 22
ammonia-borane (19) 19
asymmetric catalysis (19) 19
asymmetric-synthesis (19) 19
hydrogenation (19) 19
hydrophosphination (19) 19
rhodium (19) 19
amine-borane (18) 18
phosphorus-boron bonds (18) 18
route (18) 18
adducts (17) 17
catalysts (17) 17
alkynes (16) 16
chemical sciences (16) 16
synthesis (16) 16
amine-boranes (15) 15
asymmetric hydrogenation (15) 15
chemical properties (15) 15
dehydrogenation (15) 15
mechanism (15) 15
frustrated lewis pairs (14) 14
hydroboration (14) 14
index medicus (14) 14
palladium (14) 14
transition-metal-complexes (14) 14
alkenes (13) 13
phosphine-borane complexes (13) 13
borane (12) 12
crystal-structure (12) 12
ligand (12) 12
molecular-structure (12) 12
phosphine (12) 12
polymerization (12) 12
polymers (12) 12
analysis (11) 11
coordination chemistry (11) 11
organic chemistry (11) 11
phosphane (11) 11
chiral ligands (10) 10
enantioselective hydrogenation (10) 10
enantioselective synthesis (10) 10
homogeneous catalysis (10) 10
research (10) 10
resolution (10) 10
[ chim.orga ] chemical sciences/organic chemistry (9) 9
activation (9) 9
alkylation (9) 9
amines (9) 9
inorganic polymers (9) 9
organophosphorus compounds (9) 9
phosphine borane (9) 9
structure (9) 9
acid (8) 8
boranes - chemistry (8) 8
catalyzed formation (8) 8
chemistry, applied (8) 8
conjugate addition (8) 8
coordination (8) 8
highly enantioselective hydrogenation (8) 8
hydrides (8) 8
hydrogen storage (8) 8
mass spectrometry (8) 8
nuclear magnetic resonance spectroscopy (8) 8
olefins (8) 8
phosphin (8) 8
precursors (8) 8
aryl halides (7) 7
asymmetric synthesis (7) 7
chiral phosphines (7) 7
efficient (7) 7
hydrogen (7) 7
ketones (7) 7
lewis-acid (7) 7
lithium (7) 7
organic-synthesis (7) 7
phosphines - chemistry (7) 7
phosphinoboranes (7) 7
primary phosphine-boranes (7) 7
secondary phosphines (7) 7
stereochemistry (7) 7
transition-metal (7) 7
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Angewandte Chemie International Edition, ISSN 1433-7851, 04/2015, Volume 54, Issue 16, pp. 4836 - 4841
Journal Article
Synlett, ISSN 0936-5214, 01/2019, Volume 30, Issue 1, pp. 73 - 76
Abstract An effective method for the P-alkylation of N -arylphosphinecarboxamides was demonstrated. Primary N -arylphosphinecarboxamides without additional... 
letter | alkylation | phosphinecarboxamides | secondary phosphines | alkyl halides | arylalkylphosphinecarboxamides | PHOSPHINE BORANES | LIGANDS | HETEROCYCLES | CHEMISTRY, ORGANIC
Journal Article
Science, ISSN 0036-8075, 11/2006, Volume 314, Issue 5802, pp. 1124 - 1126
Although reversible covalent activation of molecular hydrogen (H₂) is a common reaction at transition metal centers, it has proven elusive in compounds of the... 
Protons | Transition metals | Colors | Hydrogen | Boranes | Reports | Hydrides | Nuclear magnetic resonance | Kinetics | Phosphines | Adducts | CLUSTER-FREE HYDROGENASE | PHOSPHORUS | MECHANISM | MOLECULAR-HYDROGEN | HYDRIDES | MULTIDISCIPLINARY SCIENCES | AB-INITIO | REACTIVITY | PHOSPHINE-BORANE ADDUCTS | MAIN-GROUP ELEMENTS | DIHYDROGEN COMPLEXES | Research | Structure | Analysis | Covalence | Hydrogen storage | Dehydrogenation | Activation | Cleaning | Carbon
Journal Article
Chemical Science, ISSN 2041-6520, 2018, Volume 9, Issue 15, pp. 3664 - 3671
A pyridine-boryl radical promoted reductive coupling reaction of aldehydes with 1,1-diarylethylenes has been established via a combination of computational and... 
VISIBLE-LIGHT | ORGANIC-SYNTHESIS | PHOSPHINE-BORANES | STABLE RADICALS | HETEROCYCLIC CARBENE BORANES | C-C BOND | TRANSFER HYDROGENATION | CARBONYL PROPARGYLATION | CHEMISTRY, MULTIDISCIPLINARY | ENANTIOENRICHED HOMOPROPARGYLIC ALCOHOLS | POLARITY-REVERSAL CATALYSIS
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 02/2017, Volume 53, Issue 12, pp. 2048 - 2051
This work describes the first transition metal-free stereospecific synthesis of (E)-(1-fluoro-2-arylvinyl)phosphine boranes through the addition of... 
Chemical Sciences
Journal Article
Organometallics, ISSN 0276-7333, 11/2013, Volume 32, Issue 22, pp. 6804 - 6811
The ambiphilic species Al(C6H4(o-PPh2))3 (2) was synthesized and fully characterized, notably using X-ray diffraction. Species 2 exhibits... 
FREE HYDROGEN ACTIVATION | TRANSITION-METAL-COMPLEXES | PHOSPHINE-BORANE | MOLECULAR-STRUCTURE | DIHYDROGEN ACTIVATION | OPTICAL-PROPERTIES | CHEMISTRY, ORGANIC | COORDINATION | FRUSTRATED LEWIS PAIRS | LIGAND | C-H | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Nature Chemistry, ISSN 1755-4330, 10/2013, Volume 5, Issue 10, pp. 817 - 829
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2014, Volume 20, Issue 11, pp. 2990 - 2996
Metal‐free systems, including frustrated Lewis pairs (FLPs) have been shown to bind CO2. By reducing the Lewis acidity and basicity of the ambiphilic system,... 
organocatalysis | carbon dioxide | reduction | main group elements | frustrated Lewis pairs | FREE HYDROGEN ACTIVATION | N-HETEROCYCLIC CARBENE | METHANOL | CO2 REDUCTION | CONVERSION | COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | HOMOGENEOUS HYDROGENATION | PHOSPHINE-BORANE | FIXATION | Greenhouse effect | Carbon dioxide | Catalysts | Methyl alcohol | Deoxygenation | Derivatives | Catalysis | Conversion | Basicity
Journal Article