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DALTON TRANSACTIONS, ISSN 1477-9226, 07/2018, Volume 47, Issue 25, pp. 8402 - 8417
Hydroalumination of R-P(H)-C equivalent to C-tBu with bulky H-Al[CH(SiMe3)2]2 afforded the new P-H functionalized Al/P-based frustrated Lewis pair... 
ACTIVATION | COPPER(I) COMPLEXES | ADDUCT FORMATION | HYDROGEN-BOND | CRYSTAL-STRUCTURE | CRYSTALLOGRAPHIC CHARACTERIZATION | STRUCTURAL-CHARACTERIZATION | DIALKYLALUMINUM HYDRIDE | C-H | PHOSPHORUS-COMPOUNDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 01/2018, Volume 47, Issue 25, pp. 8402 - 8417
Hydroalumination of R-P(H)-C≡C-tBu with bulky H-Al[CH(SiMe3)2]2 afforded the new P–H functionalized Al/P-based frustrated Lewis pair R-P(H)-C[=C(H)-tBu]-AlR2... 
Organic chemistry | Quantum chemistry | Hydrogen bonds | Imines | Aluminum | Nitriles | NMR spectroscopy | Ring opening | Substrates | Benzonitrile
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2019, Volume 58, Issue 1, pp. 273 - 277
The reactions of the cyclic alkyl amino carbene (CAAC) 1 with phosphaalkynes generate the kinetically unstable CAAC‐derived phosphirenes 4 and 5, which undergo... 
phosphirene | P=P bonds | phosphinium | diphosphenes | N-heterocyclic olefins | N-HETEROCYCLIC CARBENE | CONJUGATED POLYMERS | X-RAY-STRUCTURE | COMPLEXES | CHEMISTRY | MULTIPLE BONDS | CHEMISTRY, MULTIDISCIPLINARY | Substitutes | Phosphorus | Cleavage | Cations | Dimerization | Phosphaalkynes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2017, Volume 56, Issue 21, pp. 5765 - 5769
The reaction of the bulky diphosphenes (Rind)P=P(Rind) (1; Rind=1,1,3,3,5,5,7,7‐octa‐R‐substituted s‐hydrindacen‐4‐yl) with two molecules of N‐heterocyclic... 
phosphinidenes | double bond-breaking | diphosphenes | N-heterocyclic carbenes | phosphorus | PHOSPHINIDENE | BULKY RIND GROUPS | NOBEL LECTURE | TRANSITION-METAL-COMPLEXES | ZWITTERIONIC PHOSPHASILENE | COORDINATION | CHEMISTRY, MULTIDISCIPLINARY | UNUSUAL REACTIVITY | CHEMISTRY | OLEFIN-METATHESIS | MULTIPLE BONDS | Heterocyclic compounds | Chemical properties | Temperature effects | Cleavage
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 06/2018, Volume 2018, Issue 22, pp. 2863 - 2869
The first pyrroloazaphosphinines with nitrogen at the junction, 7a and 7b, have been prepared by a special route involving the collapse of the phosphorus... 
Azaphosphinines | Phosphorus | Multiple bonds | Synthesis design | Polymers
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2012, Volume 18, Issue 32, pp. 9780 - 9783
Phosphaalkenes: Deoxygenation of oxaphosphirane complexes 1 and 2 by using TiIII complexes gave mixtures of E/Z phosphaalkene complexes 3 a, b and 4 a, b.... 
density functional calculations | tungsten | radicals | alkenes | phosphorus | ORGANIC-SYNTHESIS | SUBSTITUTION | MECHANISM | RING-EXPANSION | COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | PROTONATION | REDUCTION | CONSTRUCTION | ASYMMETRIC EPOXIDATION | CYCLIZATION | Cleavage | Pathways | Mathematical analysis | Bonding | Deoxygenation
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 12/2019, Volume 48, Issue 48, pp. 17729 - 17734
Three equivalents of LGa {L = HC[C(Me)N(2,6-i-Pr2C6H3)](2)} react with AsX3 (X = Cl, Br) by insertion into two As-X bonds, followed by the elimination of LGaX2... 
PHOSPHORUS | MONOMERIC IMIDES | CHEMISTRY | CRYSTAL-STRUCTURES | BASIS-SETS | OXIDATIVE ADDITION | MULTIPLE BONDS | THERMAL-DECOMPOSITION | GALLIUM | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie, ISSN 0044-8249, 01/2019, Volume 131, Issue 1, pp. 279 - 283
The reactions of the cyclic alkyl amino carbene (CAAC) 1 with phosphaalkynes generate the kinetically unstable CAAC‐derived phosphirenes 4 and 5, which undergo... 
P=P-Bindungen | Diphosphene | Phosphinium | N-Heterocyclische Olefine | Phosphiren | Substitutes | Phosphorus | Cleavage | Cations | Dimerization | Phosphaalkynes
Journal Article
Organometallics, ISSN 0276-7333, 10/2014, Volume 33, Issue 19, pp. 5066 - 5069
Photochemical reactions of diruthenium tetrahydride complexes containing cyclopentadienyls as auxiliary ligands with carbon dioxide were studied for the... 
PHOTOINDUCED ELIMINATION | SATURATED-HYDROCARBONS | COORDINATION CHEMISTRY | PHOSPHORUS LIGANDS | FORMIC-ACID | MOLECULAR-HYDROGEN | CRYSTAL-STRUCTURE | RHENIUM CLUSTER COMPLEX | METAL HYDRIDE COMPLEXES | CHEMISTRY, ORGANIC | HOMOGENEOUS CATALYSIS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2004, Volume 126, Issue 47, pp. 15572 - 15582
The first isolation of diarylstannanethione (tin−sulfur double-bond compound) and diarylstannaneselone (tin−selenium double-bond compound), Tbt(Ditp)SnX (Tbt... 
KINETICALLY STABILIZED DIARYLSTANNYLENE | SILICON DOUBLE-BOND | GERMANIUM | MOLECULAR-STRUCTURE | ELECTRONIC SPECTRA | STABLE COMPOUND | ORGANIC MOLECULES | GROUP-14 ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | PHOSPHORUS DOUBLE-BOND | RAY CRYSTAL-STRUCTURE | Tin | Chemical properties | Research | Ketones | Structure | Chemical synthesis
Journal Article
Chemistry Letters, ISSN 0366-7022, 9/2015, Volume 44, Issue 9, pp. 1240 - 1242
Thermal reactions of Mes*-substituted triphospha[3]radialene (Mes*: 2,4,6-tri-t-butylphenyl) with [M(CO)5·(thf)] (M = Cr, W) resulted in the formation of the... 
PHOSPHORUS | LIGANDS | CHEMISTRY | BEARING | DPCB | PHOSPHAALKENE | CHEMISTRY, MULTIDISCIPLINARY | METAL-COMPLEXES
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 2011, Volume 40, Issue 3, pp. 711 - 717
The reactions of N Mo(OR)(3) (R = Bu-t, Pr-i) with (Me3Si)(2)NPNSiMe3 (1), (Me3Si)(2)(NPNBu)-Bu-t (2), (Me3Si)(2)NPS((NBu)-Bu-t) (3) and... 
IMIDOPHOSPHENIC ACID | MOLYBDENUM | TRIPLE BONDS | COMPLEXES | TUNGSTEN | POLYMERIZATION | PHOSPHAZENES | TITANIUM | METATHESIS | CATALYSTS | CHEMISTRY, INORGANIC & NUCLEAR | Phosphorus compounds | X-rays | Chemical bonds | Ligands | Terminals | NMR spectroscopy | Bonding | Molybdenum
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2007, Volume 72, Issue 10, pp. 3823 - 3829
A kinetic study is reported for aminolysis of aryl diphenylphosphinothioates (2a−i). The phosphinothioates 2a − i are less reactive than aryl... 
Amines - chemistry | Phosphinic Acids - chemistry | Oxygen - chemistry | Phosphorus - chemistry | Sulfhydryl Compounds - chemistry | Molecular Structure | Kinetics | Electrons | Sulfur - chemistry | Phosphorus compounds | Aromatic amines | Chemical properties
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2009, Volume 131, Issue 29, pp. 10041 - 10048
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 12/2016, Volume 53, Issue 1, pp. 192 - 195
The first acyclic 4π-electron -P[double bond, length as m-dash]Si-Si[double bond, length as m-dash]P- motif with two four coordinate silicon substituents... 
Drug Stability | Molecular Conformation | Butadienes - chemistry | Phosphorus - chemistry | Models, Molecular | Ligands | Amidines - chemistry | Silicon - chemistry
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 02/2020, Volume 56, Issue 15, pp. 2268 - 2271
Chelating phosphines are widely used as robust and reliable ligands in catalysis. We show that the anionic iron(i) complex [Fe-I(N(SiMe3)(2))(2)](-) is able to... 
VALENT NICKEL | DIIRON CENTER | ACTIVATION | MILD CONDITIONS | STILBENE RADICAL-ANION | 2-COORDINATE | CRYSTAL-STRUCTURES | COORDINATION | LIGAND | CARBON-PHOSPHORUS BOND | CHEMISTRY, MULTIDISCIPLINARY
Journal Article