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pi-activated alcohols (20) 20
chemistry, organic (16) 16
allylic alcohols (8) 8
alcohols (5) 5
alkylation (5) 5
catalysis (5) 5
hydroxy group (5) 5
nucleophilic-substitution (5) 5
propargylic alcohols (5) 5
alcohol (4) 4
chemistry, multidisciplinary (4) 4
friedel-crafts alkylation (4) 4
homogeneous catalysis (4) 4
acids (3) 3
article (3) 3
bond formation (3) 3
carbocations (3) 3
catalyzed direct substitution (3) 3
dehydration (3) 3
direct amination (3) 3
direct nucleophilic-substitution (3) 3
direct substitution (3) 3
friedel-crafts reactions (3) 3
index medicus (3) 3
substitution (3) 3
sulfonamides (3) 3
acid (2) 2
alkohole (2) 2
amidation (2) 2
amination (2) 2
amines (2) 2
analysis (2) 2
aromatic-compounds (2) 2
asymmetric catalysis (2) 2
benzyl alcohols (2) 2
beta-dicarbonyl compounds (2) 2
boronic acids (2) 2
c-n (2) 2
carbon (2) 2
chemical properties (2) 2
chemical reactions (2) 2
chemical synthesis (2) 2
cyclisation (2) 2
derivatives (2) 2
diols (2) 2
electron-deficient amines (2) 2
fluorinated alcohols (2) 2
green chemistry (2) 2
heteroatom-centered nucleophiles (2) 2
katalyse (2) 2
molecular structure (2) 2
n-alkylation (2) 2
one-pot synthesis (2) 2
organic chemistry (2) 2
oxalic acid (2) 2
pd-sn catalysis (2) 2
recyclable catalyst (2) 2
secondary benzylation (2) 2
solvent-free (2) 2
synthetic methods (2) 2
1,3-chirality transfer (1) 1
1,3-dicarbonyl compounds (1) 1
2-acyl imidazoles (1) 1
2-propanol (1) 1
[ chim.cata ] chemical sciences/catalysis (1) 1
[ chim.orga ] chemical sciences/organic chemistry (1) 1
acid-catalyzed benzylation (1) 1
aerobic n-alkylation (1) 1
alkylation reactions (1) 1
alkylations (1) 1
allylation (1) 1
allylic substitution (1) 1
amidation reaction (1) 1
amides (1) 1
analogue (1) 1
aniline compounds - chemistry (1) 1
antagonistic activity (1) 1
anticancer drugs (1) 1
antineoplastic agents - chemistry (1) 1
antineoplastic agents - metabolism (1) 1
aromatic compounds (1) 1
aromatic-aldehydes (1) 1
asymmetric allylic alkylation (1) 1
asymmetric hydroformylation (1) 1
asymmetric-synthesis (1) 1
balancing (1) 1
baylis-hillman acetates (1) 1
benzyl alcohols - chemistry (1) 1
benzylic acetates (1) 1
benzylic alcohols (1) 1
beta-keto phosphonates (1) 1
bimetallic (1) 1
bindungsbildung (1) 1
bismuth (1) 1
bispyridine-scandium (1) 1
bond-formation (1) 1
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Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 11, pp. 3085 - 3089
Journal Article
Synthesis, ISSN 0039-7881, 04/2016, Volume 48, Issue 7, pp. 935 - 959
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 08/2016, Volume 2016, Issue 23, pp. 4077 - 4083
A direct sulfination of nonactivated alcohols with arylsulfonylmethyl isocyanides under mild conditions [10 mol‐% of Bi(OTf)3, 25 °C] was developed to afford... 
Bismuth | Domino reactions | Nonactivated alcohols | Synthetic methods | Sulfinates | SOLVENT-FREE CONDITIONS | ONE-STEP SYNTHESIS | PI-ACTIVATED ALCOHOLS | FRIEDEL-CRAFTS REACTIONS | CHEMISTRY, ORGANIC | BAYLIS-HILLMAN ACETATES | HYDROXY GROUP | ALLYLIC ALCOHOLS | PROPARGYLIC ALCOHOLS | DIRECT NUCLEOPHILIC-SUBSTITUTION | ELECTRON-DEFICIENT AMINES
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2019, Volume 25, Issue 15, pp. 3950 - 3956
A combination of pentafluorophenylboronic acid and oxalic acid catalyses the dehydrative substitution of benzylic alcohols with a second alcohol to form new... 
alcohols | substitution | homogeneous catalysis | etherification | boronic acids | MITSUNOBU | PI-ACTIVATED ALCOHOLS | FRIEDEL-CRAFTS REACTIONS | NUCLEOPHILIC-SUBSTITUTION | CHEMISTRY, MULTIDISCIPLINARY | MILD | TRIFLATE | AMINATION | ALLYLIC ALCOHOLS | AMINES | DERIVATIVES | Catalysis | Oxalates | Oxalic acid | Alcohols | Substitutes | Acids | Aromatic compounds | Tetrahydrofuran | Alcohol | Ethers | Dehydration | Diols
Journal Article
Organic Letters, ISSN 1523-7060, 04/2014, Volume 16, Issue 7, pp. 2026 - 2029
A simple, iron-based catalytic system allows for the inter- and intramolecular arylation of unactivated secondary alcohols. This transformation expands the... 
SYSTEM | SUBSTITUTION | PI-ACTIVATED ALCOHOLS | PROPARGYLIC ALCOHOLS | CHEMISTRY, ORGANIC | BIS(OXAZOLINYL)PYRIDINE-SCANDIUM(III) TRIFLATE COMPLEXES | FRIEDEL-CRAFTS ALKYLATION | AROMATIC-COMPOUNDS | DERIVATIVES | BENZYL ALCOHOLS | 2-ACYL IMIDAZOLES
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 10/2017, Volume 2017, Issue 38, pp. 5729 - 5738
The direct sulfonamidation of primary and secondary benzylic alcohols catalyzed by a 2,3,4,5‐tetrafluorophenylboronic acid/oxalic acid co‐catalytic system was... 
Synthetic methods | Sulfonamides | Organocatalysis | Boronic acids | Alcohols | RELAY RACE METHODOLOGY | PI-ACTIVATED ALCOHOLS | FRIEDEL-CRAFTS REACTIONS | CHEMISTRY, ORGANIC | FREE ALLYLIC ALCOHOLS | HYDROGEN AUTOTRANSFER PROCESS | DIRECT AMINATION | DIRECT NUCLEOPHILIC-SUBSTITUTION | AEROBIC N-ALKYLATION | DIRECT AMIDATION | CARBOXYLIC-ACIDS
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2014, Volume 79, Issue 7, pp. 2934 - 2943
Journal Article
SYNTHESIS-STUTTGART, ISSN 0039-7881, 01/2014, Volume 46, Issue 1, pp. 25 - 34
Direct nucleophilic substitution reactions of allylic alcohols are environmentally friendly, since they generate only water as a byproduct, allowing access to... 
S(N)1 reaction | HETEROATOM NUCLEOPHILES | PI-ACTIVATED ALCOHOLS | C BOND FORMATION | 1,3-DICARBONYL COMPOUNDS | carbocations | CHEMISTRY, ORGANIC | HYDROXY GROUP | green chemistry | BETA-DICARBONYL COMPOUNDS | allylic alcohols | CATALYZED DIRECT SUBSTITUTION | HOMOGENEOUS CATALYSIS | allylic substitution | FLUORINATED ALCOHOLS | FRIEDEL-CRAFTS ALKYLATION
Journal Article
ADVANCED SYNTHESIS & CATALYSIS, ISSN 1615-4150, 02/2011, Volume 353, Issue 2-3, pp. 469 - 474
A calcium-catalyzed direct amination of pi-activated alcohols with different nitrogen nucleophiles under very mild reaction conditions is presented. The high... 
ROOM-TEMPERATURE | direct amination | ACID | BENZYLIC ALCOHOLS | CHEMISTRY, ORGANIC | SULFONAMIDES | CARBOXAMIDES | AMIDATION REACTION | NUCLEOPHILES | calcium catalysts | DIRECT SUBSTITUTION | ALLYLIC ALCOHOLS | room temperature alkylation of amines | N-ALKYLATION | CHEMISTRY, APPLIED | pi-activated alcohols
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2019, Volume 17, Issue 8, pp. 2044 - 2054
N-Alkyl amides have wide applications in the biological, pharmaceutical and organic chemical industry. Accordingly, their synthesis has attracted great... 
Journal Article
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 2/2019, Volume 17, Issue 8, pp. 244 - 254
N -Alkyl amides have wide applications in the biological, pharmaceutical and organic chemical industry. Accordingly, their synthesis has attracted great... 
HETEROATOM-CENTERED NUCLEOPHILES | SOLVENT-FREE | C-N | PI-ACTIVATED ALCOHOLS | SECONDARY BENZYLATION | CATALYZED DIRECT SUBSTITUTION | PROPARGYLIC ALCOHOLS | CHEMISTRY, ORGANIC | BOND FORMATION | RECYCLABLE CATALYST | HYDROXY GROUP | Organic chemistry | Chemical industry | Catalysts | Amides | Alcohol | Organic chemicals | Chemical synthesis | Chemical industries | Alkylation | Alcohols
Journal Article
Organic Letters, ISSN 1523-7060, 11/2018, Volume 20, Issue 22, pp. 7057 - 7061
Diastereodivergent sulfonamidation of diastereomixtures of diarylmethanols bearing a chiral auxiliary using a sulfonylamine was achieved by use of SnCl2 and... 
CARBON | DIRECT AMINATION | ALLYLIC ALCOHOLS | PI-ACTIVATED ALCOHOLS | AMIDATION | CHEMISTRY, ORGANIC | BOND FORMATION | MONTMORILLONITE | DIRECT NUCLEOPHILIC-SUBSTITUTION | EFFICIENT | BENZYL ALCOHOLS
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 03/2017, Volume 58, Issue 12, pp. 1090 - 1093
A Re O catalyzed cycloetherification of monoallylic diols is described. The reaction features short reaction time, mild reaction conditions and exclusive... 
Lewis acid | Oxa-heterocycles | Rhenium catalyst | Monoallylic alcohol | Cycloetherification | CHIRALITY TRANSFER | DEHYDRATIVE CYCLIZATION | TETRAHYDROPYRANS | PI-ACTIVATED ALCOHOLS | STEREOCHEMISTRY | COMPLEXES | CHEMISTRY, ORGANIC | 1,3-CHIRALITY TRANSFER | TRANSPOSITION | Cycloetherificatioh | ALLYLIC ALCOHOLS | INTRAMOLECULAR OXYPALLADATION REACTION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2017, Volume 56, Issue 36, pp. 10900 - 10904
Journal Article
CHEMICAL SOCIETY REVIEWS, ISSN 0306-0012, 2015, Volume 44, Issue 11, pp. 3666 - 3690
Heterobimetallic catalysts, bearing a metal-metal bond between a transition metal (TM) and a tin atom, are very promising due to their ability in mediating a... 
OPENING METATHESIS POLYMERIZATION | CHIRAL 1,3,2-DIOXAPHOSPHORINANE MOIETIES | ASYMMETRIC HYDROFORMYLATION | PD-SN CATALYSIS | PI-ACTIVATED ALCOHOLS | DUAL-REAGENT CATALYSIS | NUCLEOPHILIC-SUBSTITUTION | CHEMISTRY, MULTIDISCIPLINARY | PLATINUM COMPLEXES | ENANTIOSELECTIVE HYDROFORMYLATION | METHYL ACETATE
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 11/2014, Volume 79, Issue 22, pp. 11234 - 11240
A rhenium-catalyzed N-selective allylic amination reaction of N-hydroxycarbamates has been developed. This reaction occurs with excellent N/O selectivity and... 
OXIDATION | HYDROXYLAMINES | AMINATION | AMINES | PI-ACTIVATED ALCOHOLS | ENE REACTION | ISOMERIZATION | ALLYLATION | AMIDATION | CHEMISTRY, ORGANIC | ALKYLATIONS | Silicon compounds | Chemical reactions | Rhenium | Chemical properties | Analysis
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 09/2016, Volume 81, Issue 17, pp. 8035 - 8042
An intermolecular alkylation of sulfonamides with trichloroacetimidates is reported. This transformation does not require an exogenous acid, base, or... 
ANTAGONISTIC ACTIVITY | INTERMOLECULAR AMINATION | ASYMMETRIC-SYNTHESIS | ACID-CATALYZED BENZYLATION | PI-ACTIVATED ALCOHOLS | DIPHENYLMETHYL TRICHLOROACETIMIDATE | NUCLEOPHILIC-SUBSTITUTION | CHEMISTRY, ORGANIC | N-ALKYLATION | THROMBOXANE A | C-H BONDS | Research | Chemical properties | Transition metal compounds | Sulfonamides | Alkylation
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 10/2014, Volume 768, pp. 42 - 49
Facile insertion reaction of SnCl across pentamethylcyclopentadienyl complexes of Ir(III) and Rh(III) resulted in the formation of Ir–SnCl and Rh–SnCl... 
Iridium | Rhodium | Catalyst | Alkylation | Bimetallic | ASYMMETRIC CATALYSIS | TRANSITION-METAL COMPLEXES | PD-SN CATALYSIS | PI-ACTIVATED ALCOHOLS | NUCLEOPHILIC-SUBSTITUTION | CHEMISTRY, ORGANIC | SUBSTITUTION-REACTION | SELECTIVE ALKYLATION | CHEMISTRY, INORGANIC & NUCLEAR | OXIDATIVE-ADDITION-REACTIONS | HOMOGENEOUS CATALYSIS | N-SULFONYL ALDIMINES
Journal Article
by Yang, JM and Chu, XQ and Ji, SJ
CHINESE JOURNAL OF ORGANIC CHEMISTRY, ISSN 0253-2786, 12/2014, Volume 34, Issue 12, pp. 2462 - 2470
A novel 4-methylbenzenesulfonic acid (PTSA)-catalyzed intermolecular amination of N-acyliminium species with various N-sources via benzylic C(sp(3))-O... 
ORGANIC-SYNTHESIS | ONE-POT SYNTHESIS | PI-ACTIVATED ALCOHOLS | BORROWING HYDROGEN | CHEMISTRY, ORGANIC | CATALYZED DIRECT AMINATION | HYDROXY GROUP | green chemistry | DIRECT SUBSTITUTION | N-acyliminium ion | BENZYLIC ACETATES | ALKYLATION REACTIONS | PEPTIDE-SYNTHESIS | gem-diamines
Journal Article
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