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polyvalent iodine (439) 439
chemistry, organic (417) 417
chemistry (287) 287
polyvalent iodine compounds (247) 247
chemistry, multidisciplinary (233) 233
organic-synthesis (211) 211
hypervalent iodine (149) 149
oxidation (143) 143
index medicus (115) 115
iodine (106) 106
derivatives (104) 104
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hypervalent iodine reagents (98) 98
reagents (93) 93
cyclization (66) 66
molecular structure (64) 64
alcohols (59) 59
ketones (59) 59
synthesis (57) 57
chemical properties (55) 55
diaryliodonium salts (53) 53
one-pot synthesis (51) 51
m-chloroperbenzoic acid (47) 47
hypervalent compounds (43) 43
oxidation-reduction (43) 43
alkenes (42) 42
carbonyl-compounds (41) 41
stereoisomerism (39) 39
iodonium salts (38) 38
salts (38) 38
benzene (37) 37
acid (36) 36
analysis (36) 36
aldehydes (35) 35
chemistry, applied (34) 34
selective oxidation (34) 34
efficient (32) 32
secondary alcohols (31) 31
arylation (30) 30
bond formation (30) 30
organic chemistry (30) 30
iodine - chemistry (29) 29
hypervalent iodine reagent (28) 28
iod (28) 28
aromatic compounds (27) 27
paper (27) 27
alkynes (26) 26
halogenation (25) 25
arenes (24) 24
catalysts (24) 24
complexes (24) 24
letter (24) 24
o-iodoxybenzoic acid (24) 24
esters (23) 23
indoles (23) 23
chemistry, inorganic & nuclear (22) 22
functionalization (22) 22
activation (21) 21
chemical tests and reagents (21) 21
coupling reactions (21) 21
efficient synthesis (21) 21
ibx (21) 21
iodine compounds (21) 21
phenols (21) 21
amination (20) 20
amines (20) 20
carboxylic-acids (20) 20
dess-martin periodinane (20) 20
directions (20) 20
iodobenzene dichloride (20) 20
n bond formation (20) 20
oxidation-reduction reaction (20) 20
stereoselective-synthesis (20) 20
copper (19) 19
heterocycles (19) 19
olefins (19) 19
organic compounds (19) 19
acids (18) 18
c-h bonds (18) 18
chemical reactions (18) 18
hypervalent iodine chemistry (18) 18
palladium (18) 18
synthetic applications (18) 18
c-h activation (17) 17
generation (17) 17
intramolecular cyclization (17) 17
iodosylbenzene (17) 17
ionic liquid (17) 17
ligands (17) 17
metal-free conditions (17) 17
research (17) 17
room-temperature (17) 17
structure (17) 17
alkaloids (16) 16
conversion (16) 16
in-situ generation (16) 16
models, molecular (16) 16
nucleophilic-substitution (16) 16
organic-chemistry (16) 16
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Angewandte Chemie International Edition, ISSN 1433-7851, 07/2015, Volume 54, Issue 28, pp. 8287 - 8291
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2016, Volume 55, Issue 11, pp. 3652 - 3656
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 04/2014, Volume 9, Issue 4, pp. 972 - 983
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2012, Volume 134, Issue 37, pp. 15505 - 15511
A direct metal-free amination of arylalkynes has been developed, which proceeds by reaction of the terminal alkyne with the hypervalent iodine reagent... 
ORGANIC-SYNTHESIS | IODONIUM SALTS | COUPLING REACTIONS | POLYVALENT IODINE COMPOUNDS | OXIDATIVE AMIDATION | TERMINAL ALKYNES | N BOND FORMATION | ALKYNYLIODONIUM SALTS | PAUSON-KHAND REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | GENERAL-METHOD | Chemical bonds | Iodine compounds | Chemical properties | Analysis | Acetylene
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 09/2016, Volume 2016, Issue 25, pp. 4260 - 4264
The gold‐catalyzed, iodine(III)‐mediated direct oxidative acyloxylation of the C(sp 3 )–H bonds of methyl sulfides for the synthesis of various α‐thioaryl and... 
Gold | C–H activation | Synthetic methods | Acyloxylation | Hypervalent compounds | Iodine | OXIDATION | ACTIVATION | C(SP)-H ACETOXYLATION | FUNGUS EPICOCCUM-NIGRUM | ARYL SULFIDES | CHEMISTRY, ORGANIC | SULFUR | C-H BONDS | FUNCTIONALIZATION | C-H activation | MILD CONDITIONS | POLYVALENT IODINE COMPOUNDS | Chemical tests and reagents | Sulfides | Sulfur
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 12/2011, Volume 50, Issue 50, pp. 11849 - 11851
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 11/2017, Volume 82, Issue 22, pp. 11691 - 11702
We have developed an efficient method for direct formation of epoxide groups from carbon(sp(2))carbon(sp(3)) single bonds of beta-keto esters; the reaction is... 
ALPHA-OXIDATION | ORGANIC-SYNTHESIS | ACID | ELECTROPHILIC TRIFLUOROMETHYLATING REAGENTS | MECHANISTIC INSIGHTS | CHEMISTRY | CHEMISTRY, ORGANIC | DONOR ABILITIES | POLYVALENT IODINE | BETA-KETO-ESTERS | TRIPTOLIDE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2012, Volume 134, Issue 17, pp. 7242 - 7245
A new approach to direct intermolecular allylic amination has been developed using metal-free conditions at room temperature. The reaction employs a... 
FUNCTIONALIZATION | AEROBIC OXIDATIVE AMINATION | HYPERVALENT IODINE | POLYVALENT IODINE COMPOUNDS | MEDIATED AZIRIDINATION | AMBIENT-TEMPERATURE | N BOND FORMATION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | C-H AMINATION | TERMINAL ALKENES | Chemical bonds | Iodine compounds | Allylic compounds | Amines | Chemical properties | Analysis
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 04/2012, Volume 51, Issue 14, pp. 3462 - 3465
The ring and I: hypervalent iodine compounds avoid the issues of toxicity or complicated ligands of many transition-metal-based systems. A highly... 
hypervalent iodine | aminohydroxylation | amino alcohols | cyclization | stereoselective synthesis | OXIDATION | BENZENE | CHEMISTRY, MULTIDISCIPLINARY | SPIROLACTONIZATION | ALKENES | KETONES | OLEFIN AMIDOHYDROXYLATION | DIAMINATION | CHEMISTRY | POLYVALENT IODINE | DEAROMATIZATION | Iodine compounds | Synthesis | Alkenes | Toxicity | Ureas | Ligands | Derivatives | Iodine
Journal Article
Chemistry – An Asian Journal, ISSN 1861-4728, 12/2016, Volume 11, Issue 24, pp. 3583 - 3588
Hypervalent iodine(III) compounds containing iodine–nitrogen bonds are very attractive amination reagents in organic synthesis. Heteroaromatic (aryl)iodonium... 
I−N bond | indoles | iodine | imides | heterocycles | I-N bond | ORGANIC-SYNTHESIS | METAL-FREE CONDITIONS | REAGENTS | ORGANOHYPERVALENT IODINE | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | SYNTHETIC APPLICATIONS | DIAMINATION | CHEMISTRY | POLYVALENT IODINE | C-H AMINATION | Precipitation (Meteorology) | Chemical tests and reagents | Structure | Analysis | Crystals | Crystal structure | Iodine
Journal Article
Advanced Synthesis and Catalysis, ISSN 1615-4150, 05/2013, Volume 355, Issue 7, pp. 1243 - 1248
Hydrochloric acid activates the oxidative iodination of aromatic compounds with the iodine- hydrogen peroxide system through the formation of an iodine(I)... 
oxidation | halogenation | iodination | hydrogen peroxide | oxidative iodination | ORGANIC-SYNTHESIS | ARENES | CHEMISTRY, ORGANIC | SULFURIC-ACID | COUPLING REACTIONS | CHEMISTRY | SYSTEMS | POLYVALENT IODINE | CHEMISTRY, APPLIED | EFFICIENT | Hydrochloric acid | Proteins | Hydrogen peroxide | Chemical tests and reagents | Aromatic compounds | Acetonitrile | Telomerase | Sulfuric acid | Anisole
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2016, Volume 55, Issue 1, pp. 413 - 417
Molecular structures of the most prominent chiral non‐racemic hypervalent iodine(III) reagents to date have been elucidated for the first time. The formation... 
hypervalent iodine | diacetoxylation | hydrogen bonding | chirality | alkenes | OXIDATION | ASYMMETRIC-SYNTHESIS | REAGENTS | FUNCTIONALIZATIONS | DIRECTED EVOLUTION | CHEMISTRY, MULTIDISCIPLINARY | SPIROLACTONIZATION | CHEMISTRY | POLYVALENT IODINE | METAL-FREE | Catalysis | Catalysts | Enantiomers | Hydrogen | Hydrogen bonding | Iodine | Alkenes | Styrenes | Reagents | Chemical bonds | Oxidation | Communications | Communication
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2016, Volume 55, Issue 41, pp. 12655 - 12658
Journal Article