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Chemistry : a European journal, ISSN 1521-3765, 2018, Volume 24, Issue 70, pp. 18735 - 18742
.... The rate of reaction was found to be second‐order in both [FeO42−] and [H+]. These results are consistent with a proposed mechanism in which the first step involves the initial equilibrium protonation of FeO42− to give FeO3(OH... 
diferrate | O−O coupling | ferrate | water oxidation | DFT calculations | MOLECULAR CALCULATIONS | O-O coupling | EFFECTIVE CORE POTENTIALS | AB-INITIO | DIMER COMPLEX | O BOND FORMATION | CATALYST | CHEMISTRY, MULTIDISCIPLINARY | RUTHENIUM(II) COMPLEXES | SINGLE-SITE | OXYGEN EVOLUTION | KINETICS | Phosphates | Oxidation-reduction reaction | Hydrogen-ion concentration | Analysis | Potassium ferrate | Reaction kinetics | Protonation | Oxidation | Kinetics | Spectrophotometry | pH effects
Journal Article
Analytical chemistry (Washington), ISSN 0003-2700, 11/2009, Volume 81, Issue 21, pp. 8797 - 8800
The classic electrochemical catalytic mechanism, often referred to as the EC′ mechanism, is traditionally represented by the two reactions A + e ⇄ B (E A/B 0, k A/B 0, αA/B) and B + P ⇄ A + Q (K eq, k f, k b... 
OXIDATION | NANOPARTICLES | CHEMISTRY, ANALYTICAL | ELECTRON-TRANSFER | DIFFUSIONAL PATHWAYS | DNA | KINETICS | ELECTROCATALYSIS | POTENTIAL STEP CHRONOAMPEROMETRY | CARBON NANOTUBES | VOLTAMMETRY | Observations | Models | Catalysis | ELECTRON TRANSFER | DISTRIBUTION | CATALYTIC EFFECTS | cyclic voltammetry | SUBSTRATES | INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY | DIFFUSION | catalytic | quasicatalytic
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2015, Volume 137, Issue 3, pp. 1258 - 1272
The photochemical reactions of Tp′Rh­(PMe3)­H2 (1) and thermal reactions of Tp′Rh­(PMe3)­(CH3)H (1a, Tp′ = tris­(3,5-dimethylpyrazolyl)­borate) with substrates... 
POTENTIAL BASIS-SETS | ALIPHATIC ETHERS | TRANSITION-METAL-COMPLEXES | OXIDATIVE-ADDITION | RHODIUM-TRISPYRAZOLYLBORATE | THERMODYNAMIC SELECTIVITY | FLUORINATED PYRIDINES | POLARIZATION FUNCTIONS | SIGMA-COMPLEXES | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | Silicon compounds | Chemical properties | Chemical reaction, Rate of | Structure | Carbon compounds | Analysis
Journal Article