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Organic Letters, ISSN 1523-7060, 06/2017, Volume 19, Issue 11, pp. 2853 - 2856
In this report, we describe the application of palladium-based oxidative addition complexes (OACs) as effective precatalysts for C–N, C–O, and C–F... 
PD-CATALYZED FLUORINATION | HALIDES | PALLADIUM PRECATALYSTS | DESIGN | TEMPERATURE | ARYLATION | SECONDARY | CHEMISTRY, ORGANIC | PALLADACYCLE PRECATALYST | ARYL | ACID-ESTERS
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 10/2018, Volume 51, Issue 10, pp. 2589 - 2599
Conspectus Transition-metal-catalyzed cross-coupling reactions represent a most powerful tool for the rapid construction of C–C and C–X bonds available to... 
ROOM-TEMPERATURE | ELECTRONICALLY-ACTIVATED AMIDES | BUCHWALD-HARTWIG | ARYL ESTERS | HETEROCYCLIC CARBENE COMPLEXES | ORGANOMETALLIC CHEMISTRY | PD-NHC PRECATALYST | STERIC PROPERTIES | CHEMISTRY, MULTIDISCIPLINARY | SUZUKI-MIYAURA | GENERAL-METHOD
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 09/2017, Volume 50, Issue 9, pp. 2244 - 2253
Conspectus Over the past decade, the use of Pd–NHC complexes in cross-coupling applications has blossomed, and reactions that were either not previously... 
ORGANOZINC REAGENTS | ORTHO-SUBSTITUTED BIARYLS | CATALYZED C-C | ARYL HALIDES | PEPPSI-IPENT | NHC | PRE-CATALYST | CHEMISTRY, MULTIDISCIPLINARY | SUZUKI-MIYAURA | PRECATALYST | BASE
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 12/2015, Volume 56, Issue 48, pp. 6791 - 6794
[Display omitted] Substituted pyridazine-3,6-diamines are attractive but poorly precedented scaffolds in medicinal chemistry and are challenging targets in... 
3,6-Diaminopyridazines | Buchwald protocol | Substituted pyridazine-3,6-diamines | Brettphos precatalyst
Journal Article
ACS Catalysis, ISSN 2155-5435, 04/2018, Volume 8, Issue 4, pp. 2989 - 2994
The use of fluorinated arylboronic acid building blocks in cross-coupling has remained challenging, because of their acute base sensitivity. We report a... 
GENERAL-SOLUTION | boronic acid | PROTODEBORONATION | ARYLATION | CHEMISTRY, PHYSICAL | POLYFLUOROPHENYL | SUZUKI-MIYAURA | CROSS-COUPLING REACTIONS | precatalyst | HETEROCYCLIC CARBENE COMPLEXES | PALLADIUM PRECATALYST | cross-coupling | palladium | ARYL | fluorine | transmetalation
Journal Article
Nature Communications, ISSN 2041-1723, 03/2016, Volume 7, Issue 1, p. 11073
Palladium-catalysed C(sp(2))-N cross-coupling (that is, Buchwald-Hartwig amination) is employed widely in synthetic chemistry, including in the pharmaceutical... 
HALIDES | CROSS-COUPLING REACTIONS | AMINATION | AMMONIA | MONOARYLATION | C-N | MULTIDISCIPLINARY SCIENCES | MEDICINAL CHEMISTS | BROMIDES | ARYL CHLORIDES | PRECATALYST
Journal Article
Chemical Communications, ISSN 1359-7345, 2015, Volume 51, Issue 47, pp. 9632 - 9635
The two-step mechanochemical preparation of carbene–pyridine complexes of palladium and platinum is reported. The organometallic products, which represent a... 
Journal Article
ACS Catalysis, ISSN 2155-5435, 2015, Volume 5, Issue 5, pp. 3120 - 3123
The synthesis of NiCl­(o-tolyl)­(TMEDA) (3; TMEDA = tetramethylethylenediamine) and its application in coupling reactions is described. In combination with a... 
cross-coupling | nickel | precatalyst | homogeneous catalysis | air stability | HALIDES | CHEMISTRY, PHYSICAL | LIGAND | BROMIDES | ARYL CHLORIDES
Journal Article
Organic Letters, ISSN 1523-7060, 01/2018, Volume 20, Issue 1, pp. 208 - 211
A method for the coupling of aryl chlorides and thiophenols using an air-stable nickel(0) catalyst is described. This thioetherification procedure can be... 
HALIDES | ROOM-TEMPERATURE | HETEROARYL CHLORIDES | AMINATION | PHOSPHITE COMPLEXES | HYDROCYANATION | CHEMISTRY, ORGANIC | BOND FORMATION | LIGAND | NNN PINCER COMPLEXES | PRECATALYST
Journal Article
Organic Letters, ISSN 1523-7060, 07/2015, Volume 17, Issue 13, pp. 3370 - 3373
The non-nucleophilic organic superbase P2Et phosphazene can enable a broad range of palladium-catalyzed cross-coupling reactions, including C-C, C-N, and C-O... 
PALLADIUM PRECATALYSTS | AMINATION | PALLADACYCLE PRECATALYSTS | LIGANDS | BUCHWALD-HARTWIG | ARYL HALIDES | HYDROXYLATION | CHLORIDES | CHEMISTRY, ORGANIC | SUZUKI-MIYAURA
Journal Article
Organic Letters, ISSN 1523-7060, 03/2019, Volume 21, Issue 5, pp. 1253 - 1257
The direct, highly chemoselective Suzuki-Miyaura cross-coupling of trifluoromethanesulfonamides (triflamides) by selective N-C(O) amide bond cleavage is... 
C CLEAVAGE | KETONE SYNTHESIS | DESTABILIZATION | RELEVANCE | TWISTED AMIDES | ESTERS | CHEMISTRY, ORGANIC | INTERCONVERSION | ARYL | PRECATALYST
Journal Article
ACS Catalysis, ISSN 2155-5435, 09/2015, Volume 5, Issue 9, pp. 5596 - 5606
Complexes of the type (η3-allyl)­Pd­(L)­(Cl) (L = PR3 or NHC), have been used extensively as precatalysts for cross-coupling and related reactions, with... 
precatalyst | catalyst activation | cross-coupling | catalysis | palladium | DFT calculations | Suzuki-Miyaura reaction
Journal Article
Organic Letters, ISSN 1523-7060, 12/2018, Volume 20, Issue 23, pp. 7563 - 7566
Direct transamidation of secondary amides was developed via nickel catalysis. In the presence of trimethylsilyl chloride and manganese, Ni­(diglyme)­Cl2 with a... 
ACTIVATION | LIGANDS | CONVERSION | ESTERS | CHEMISTRY, ORGANIC | PD-NHC PRECATALYST | DERIVATIVES | DISCOVERY | PEPPSI | CARBOXYLIC-ACIDS | GENERAL-METHOD
Journal Article
Chemical Communications, ISSN 1359-7345, 05/2011, Volume 47, Issue 18, pp. 5181 - 5183
Pd-PEPPSI-IPent has proven to be an excellent catalyst for the Negishi cross-coupling reaction of secondary alkylzinc reagents with a wide variety of... 
REAGENTS | COMPLEXES | CHLORIDES | CARBON-CARBON | CATALYST | REDUCTIVE ELIMINATION | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | PRECATALYST | GRIGNARD
Journal Article
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 02/2019, Volume 17, Issue 7, pp. 1722 - 1726
An operationally simple mechanochemical method for the Pd catalysed Buchwald-Hartwig amination of arylhalides with secondary amines has been developed using a... 
LIGANDS | MECHANOCHEMISTRY | COMPLEXES | NHC | CHEMISTRY, ORGANIC | N-HETEROCYCLIC CARBENES | ARYL CHLORIDES | PRECATALYST | CATALYSTS
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 05/2019, Volume 21, Issue 9, pp. 3304 - 3309
A general class of well-defined, air-stable, and readily available Pd(II)-NHC precatalysts (NHC = N-heterocyclic carbene) for Suzuki and Buchwald-Hartwig... 
KETONE SYNTHESIS | MIYAURA | HETEROCYCLIC CARBENE COMPLEXES | TWISTED AMIDES | BONDS | CHEMISTRY, ORGANIC | PD-NHC PRECATALYST | CLEAVAGE | DESIGNING PD | PEPPSI | GENERAL-METHOD
Journal Article
Organometallics, ISSN 0276-7333, 06/2014, Volume 33, Issue 11, pp. 2902 - 2905
The synthesis and characterization of the new six- and seven-membered Pd–PEPPSI-type N-heterocyclic carbene (NHC) complexes 3 and 4 is described. Complexes of... 
ACTIVATION | AMINATION | LIGANDS | STABILIZATION | NHC | REACTIVITY | CHEMISTRY | CHEMISTRY, ORGANIC | PALLADIUM(II) | PRECATALYST | RHODIUM(I) | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organic Letters, ISSN 1523-7060, 12/2017, Volume 19, Issue 24, pp. 6510 - 6513
A general, highly selective method for the room temperature Suzuki–Miyaura cross-coupling of commonly encountered primary benzamides is reported. A combination... 
COOPERATIVE CATALYSIS | KETONE SYNTHESIS | C-N | BUCHWALD-HARTWIG | NICKEL CATALYSIS | N BOND ACTIVATION | HETEROCYCLIC CARBENE COMPLEXES | TWISTED AMIDES | CHEMISTRY, ORGANIC | PD-NHC PRECATALYST | DIARYL KETONE
Journal Article
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