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1. Full Text Catalytic C(sp3)−H Arylation of Free Primary Amines with an exo Directing Group Generated In Situ
by Xu, Yan and Young, Michael C and Wang, Chengpeng and Magness, David M and Dong, Guangbin
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2016, Volume 55, Issue 31, pp. 9084 - 9087
Herein, we report the palladium‐catalyzed direct arylation of unactivated aliphatic C−H bonds in free primary amines. This method takes advantage of an... 
palladium catalysis | C−H activation | directing groups | primary amines | arylation | ROOM-TEMPERATURE | C(SP)-H BONDS | PALLADIUM | NITROGEN-HETEROCYCLES | UNACTIVATED C(SP)-H | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | FUNCTIONALIZED MOLECULES | C-H activation | ALIPHATIC-AMINES | ETHER SYNTHESIS | Aniline | Palladium | Catalysis
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2. Full Text Palladium‐Catalyzed C(sp3)−H Arylation of Primary Amines Using a Catalytic Alkyl Acetal to Form a Transient Directing Group
by St John‐Campbell, Sahra and Ou, Alex K and Bull, James A
Chemistry – A European Journal, ISSN 0947-6539, 12/2018, Volume 24, Issue 67, pp. 17838 - 17843
C−H Functionalization of amines is a prominent challenge due to the strong complexation of amines to transition metal catalysts, and therefore typically... 
C−H functionalization | amines | palladium | reaction kinetics | homogeneous catalysis | OXIDATION | COMPLEX | STRATEGY | C-H functionalization | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | ALIPHATIC-AMINES | BOND ACTIVATION | C(SP)-H | Amines | Transition metal compounds | Chemical reaction, Rate of | Chemical tests and reagents | Metal catalysts | Palladium | Salicylates | Catalysis | Transition metals | Iodides | Catalysts | Aromatic compounds | Benzene | Reagents | Acetals | Carbonyls | Full Paper | Full Papers
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3. Full Text A Hydrazone‐Based exo‐Directing‐Group Strategy for β C−H Oxidation of Aliphatic Amines
by Huang, Zhongxing and Wang, Chengpeng and Dong, Guangbin
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2016, Volume 55, Issue 17, pp. 5299 - 5303
Described is a new hydrazone‐based exo‐directing group (DG) strategy developed for the functionalization of unactivated primary β C−H bonds of aliphatic... 
amines | oxidation | palladium | C−H activation | hydrazones | Hydrazones | Oxidation | Palladium | Amines | C-H activation
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4. Full Text Stability of Second Generation Grubbs’ Alkylidenes to Primary Amines: Formation of Novel Ruthenium‐Amine Complexes
by Wilson, Gerald O and Porter, Keith A and Weissman, Haim and White, Scott R and Sottos, Nancy R and Moore, Jeffrey S
Advanced Synthesis & Catalysis, ISSN 1615-4150, 08/2009, Volume 351, Issue 11‐12, pp. 1817 - 1825
The stability of second generation Grubbs’ alkylidenes to primary amines relative to the first generation derivatives is investigated. For both Grubbs’... 
ruthenium | self‐healing polymers | ring‐opening metathesis (ROMP) | ring‐closing metathesis (RCM) | primary amines | Grubbs’ catalyst stability | Self-healing polymers | Grubbs' catalyst stability | Primary amines | Ruthenium | Ring-opening metathesis (ROMP) | Ring-closing metathesis (RCM) | OLEFIN METATHESIS CATALYSTS | MECHANISM | self-healing polymers | DECOMPOSITION | CHEMISTRY, ORGANIC | POLYMERIZATION | ring-opening metathesis (ROMP) | PRIMARY ALCOHOLS | ring-closing metathesis (RCM) | KINETICS | DEGRADATION | CHEMISTRY, APPLIED | INITIATORS
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5. Full Text Azobisisobutyronitrile Initiated Aerobic Oxidative Transformation of Amines: Coupling of Primary Amines and Cyanation of Tertiary Amines
by Liu, Lianghui and Wang, Zikuan and Fu, Xuefeng and Yan, Chun-Hua
Organic Letters, ISSN 1523-7060, 11/2012, Volume 14, Issue 22, pp. 5692 - 5695
In the presence of a catalytic amount of radical initiator AIBN, primary amines are oxidatively coupled to imines and tertiary amines are cyanated to... 
CARBON BOND FORMATION | PRIMARY ALIPHATIC-AMINES | N-HYDROXYPHTHALIMIDE NHPI | ONE-POT SYNTHESIS | CATALYTIC-SYSTEM | SODIUM-CYANIDE | BAEYER-VILLIGER OXIDATION | CHEMISTRY, ORGANIC | HYDROGEN-PEROXIDE | METAL-FREE | MOLECULAR-OXYGEN | Amines - chemistry | Combinatorial Chemistry Techniques | Oxidation-Reduction | Imines - chemistry | Nitriles - chemistry | Molecular Structure | Catalysis
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6. Full Text Photoredox‐Catalyzed Site‐Selective α‐C(sp3)−H Alkylation of Primary Amine Derivatives
by Ashley, Melissa A and Yamauchi, Chiaki and Chu, John C. K and Otsuka, Shinya and Yorimitsu, Hideki and Rovis, Tomislav
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2019, Volume 58, Issue 12, pp. 4002 - 4006
The synthetic utility of tertiary amines to oxidatively generate α‐amino radicals is well established, however, primary amines remain challenging because of... 
amines | reaction mechanisms | radicals | photochemistry | synthetic methods | ACIDS | ALPHA-AMINOALKYL RADICALS | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | ATOM | FUNCTIONALIZATION | ABSTRACTION | ADDITION-REACTIONS | ARENECARBONITRILES | ALIPHATIC-AMINES | PHOTOCHEMICAL-REACTIONS | Side reactions | Divergence | Amines | Alkenes | Sulfonamides | Selectivity | Catalysis | Derivatives | Amino radical | Alkylation | Intermediates
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7. Full Text Vicinal α,β‐Functionalizations of Amines: Cyclization Versus Dehydrogenative Hydrolysis
by Jiang, Fan and Achard, Mathieu and Bruneau, Christian
Chemistry – A European Journal, ISSN 0947-6539, 10/2015, Volume 21, Issue 41, pp. 14319 - 14323
Direct vicinal α,β‐difunctionalization of tertiary cyclic amines is achieved in the presence of ruthenium or iridium transition‐metal complexes featuring... 
alkylation | dehydrogenative hydrolysis | hydrogen | chelate | cyclization | TERTIARY-AMINES | BORROWING HYDROGEN | TRANSFER HYDROGENATION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | PRIMARY ALCOHOLS | IRIDIUM CATALYSTS | SECONDARY ALCOHOLS | SELECTIVE SYNTHESIS | CATALYZED N-ALKYLATION | CYCLIC AMINES | Hydrolysis | Hydrogen storage | Ruthenium | Amines | Dehydrogenation | Amides | Iridium | Chelates | Chemical Sciences
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8. Full Text Cyclopentadiene–Phosphine/Palladium-Catalyzed Cleavage of C–N Bonds in Secondary Amines: Synthesis of Pyrrole and Indole Derivatives from Secondary Amines and Alkenyl or Aryl Dibromides
by Geng, Weizhi and Zhang, Wen-Xiong and Hao, Wei and Xi, Zhenfeng
Journal of the American Chemical Society, ISSN 0002-7863, 12/2012, Volume 134, Issue 50, pp. 20230 - 20233
An efficient Pd-catalyzed cleavage of C(sp3)–N bonds in secondary amines and a consequent C(sp2)–N and C(sp3)–N coupling process was developed. Various... 
REDUCTIVE-ELIMINATION | PRIMARY ALLYLIC AMINES | HETEROCYCLIC CARBENE | HYDRODENITROGENATION CATALYSIS | CARBONYLATIVE RING EXPANSION | ARYLTRIMETHYLAMMONIUM SALTS | OXIDATIVE-ADDITION | ETA(N,C)-PYRIDINE COMPLEX | MECHANISTIC INSIGHT | CARBON-NITROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | Palladium catalysts | Catalysis | Chemical properties | Cyclopentadiene | Analysis | Pyrrole
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9. Full Text Polynuclear Gold [AuI]4, [AuI]8, and Bimetallic [AuI4AgI] Complexes: C−H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines
by Smirnova, Ekaterina S and Muñoz Molina, José M and Johnson, Alice and Bandeira, Nuno A. G and Bo, Carles and Echavarren, Antonio M
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2016, Volume 55, Issue 26, pp. 7487 - 7491
The synthesis of tetranuclear gold complexes, a structurally unprecedented octanuclear complex with a planar [AuI8] core, and pentanuclear [AuI4MI] (M=Cu, Ag)... 
gold | heterometallic complexes | structure elucidation | homogeneous catalysis | carbonylation | Amines | Catalysis | Nanoparticles | Gold | Carbonyl compounds | Bimetals | Ureas | Carbonyls | Communications | Communication
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10. Full Text Direct Aryl C−H Amination with Primary Amines Using Organic Photoredox Catalysis
by Margrey, Kaila A and Levens, Alison and Nicewicz, David A
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 49, pp. 15644 - 15648
The direct catalytic C−H amination of arenes is a powerful synthetic strategy with useful applications in pharmaceuticals, agrochemicals, and materials... 
organocatalysis | amines | arenes | photochemistry | synthetic methods | DRUG | ACIDS | FUNCTIONAL MOLECULES | ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | ARENE | HETEROCYCLES | CHEMISTRY | IMIDATION | Usage | Amines | Catalysis | Drugs | Agricultural chemicals | Catalysts | Toluene | Amino acids | Biological activity | Aliphatic compounds | Aromatics | Agrochemicals | Amination | Aromatic compounds | Benzene | Chemical bonds | Coupling | Scaffolds
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11. Full Text Synthesis of Symmetric and Unsymmetric Secondary Amines from the Ligand-Promoted Ruthenium-Catalyzed Deaminative Coupling Reaction of Primary Amines
by Arachchige, Pandula T. Kirinde and Lee, Hanbin and Yi, Chae S
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2018, Volume 83, Issue 9, pp. 4932 - 4947
The catalytic system generated in situ from the tetranuclear Ru–H complex with a catechol ligand (1/L1) was found to be effective for the direct deaminative... 
TRANSITION-METAL CATALYSIS | ROOM-TEMPERATURE | DIRECT REDUCTIVE AMINATION | CHEMOSELECTIVE REDUCTION | PRIMARY ALLYLIC AMINES | HETEROCYCLIC CARBENE | ANILINE DERIVATIVES | CARBON-NITROGEN BOND | CHEMISTRY, ORGANIC | C-N BOND | HECK REACTION | ruthenium catalyst | deamination | secondary amine
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12. Full Text Mild N‐Alkylation of Amines with Alcohols Catalyzed by the Acetate Ru(OAc)2(CO)(DiPPF) Complex
by Figliolia, Rosario and Baldino, Salvatore and Nedden, Hans G and Zanotti‐Gerosa, Antonio and Baratta, Walter
Chemistry – A European Journal, ISSN 0947-6539, 10/2017, Volume 23, Issue 58, pp. 14416 - 14419
The acetate complex Ru(OAc)2(DiPPF) (2) obtained from Ru(OAc)2(PPh3)2 (1) and 1,1′‐bis(diisopropylphosphino)ferrocene (DiPPF) reacts cleanly with formaldehyde... 
borrowing hydrogen | amines | ruthenium | alcohols | N-alkylation | Alcohol | Amines | Acetic acid | Dipping | Alkylation | Alcohols
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