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pronucleophiles (134) 134
chemistry, organic (103) 103
palladium (46) 46
chemistry, multidisciplinary (39) 39
allylation (34) 34
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cyclization (26) 26
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pyridines (6) 6
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umpolung addition (6) 6
[ chim.orga ] chemical sciences/organic chemistry (5) 5
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1,3-dicarbonyl compounds (4) 4
3,4-disubstituted isoquinolines (4) 4
<3+2>-cycloaddition (4) 4
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Accounts of Chemical Research, ISSN 0001-4842, 08/2016, Volume 49, Issue 8, pp. 1524 - 1536
We present a new and efficient strategy for the atom-economic transformation of both alkynes and allenes to allylic functionalized structures via a... 
ASYMMETRIC-SYNTHESIS | 1,3-DICARBONYL COMPOUNDS | CARBON PRONUCLEOPHILES | REVERSE PRENYLATION | INTRAMOLECULAR HYDROAMINATION | TERMINAL ALKYNES | ENANTIOSELECTIVE HYDROAMINATION | REGIOSELECTIVE DECARBOXYLATIVE ADDITION | ALLYLIC ALKYLATIONS | CHEMISTRY, MULTIDISCIPLINARY | CARBOXYLIC-ACIDS
Journal Article
Organic Letters, ISSN 1523-7060, 08/2016, Volume 18, Issue 15, pp. 3906 - 3909
A palladium-catalyzed dearomative allylic alkylation of indoles with alkynes to construct indolenines with C3-quarternary centers was reported. The in situ... 
KOUMINE | REARRANGEMENT | N-ALLOC | ACTIVATION | ALLYLATION | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | HYDROAMINATION | ALLENAMIDES | PRONUCLEOPHILES | ALKALOIDS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2010, Volume 132, Issue 13, pp. 4568 - 4569
A method for catalytic asymmetric γ sulfenylation of carbonyl compounds has been developed. In the presence of an appropriate catalyst, thiols not only add to... 
NUCLEOPHILES | ADDITION-REACTION | ENANTIOSELECTIVE SYNTHESIS | HETEROCYCLES | 2-ALKYNOATES | ORGANOCATALYSIS | ALDEHYDES | UMPOLUNG ADDITION | CHEMISTRY, MULTIDISCIPLINARY | PRONUCLEOPHILES | CONJUGATE ADDITION
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2016, Volume 14, Issue 46, pp. 10833 - 10839
A novel method for the construction of allyl arylsulfone derivatives was developed by palladium catalyzed allylation of sulfonyl hydrazides with alkynes. A... 
Journal Article
Organic Letters, ISSN 1523-7060, 11/2018, Volume 20, Issue 21, pp. 6891 - 6895
An unprecedented efficient palladium(0)-catalyzed reaction of vinyl oxiranes with N-tosylhydrazones, affording “skipped” allylic alcohols in total... 
NUCLEOPHILES | ORGANIC-SYNTHESIS | EPOXIDES | NATURAL-PRODUCTS | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | SUBSTITUTION-REACTIONS | VERSATILE REAGENTS | HECK REACTION | ELECTROPHILES | PRONUCLEOPHILES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2018, Volume 140, Issue 37, pp. 11627 - 11630
We developed a highly regioselective addition of 1,3-dienes with simple ketones by nickel-hydride catalyst bearing DTBM-SegPhos ligand. A wide range of... 
PALLADIUM-CATALYZED ADDITION | ACTIVE METHYLENE | DIENES | ALLYLATION | ALPHA-ALKYLATION | CARBONYL-COMPOUNDS | ALKYNES | ALLENES | ALLYLIC ALKYLATIONS | CHEMISTRY, MULTIDISCIPLINARY | PRONUCLEOPHILES
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 14, pp. 4002 - 4005
Journal Article
Organic Letters, ISSN 1523-7060, 12/2002, Volume 4, Issue 26, pp. 4677 - 4679
A highly efficient method for constructing heterocycles was achieved by phosphine-catalyzed tandem umpolung addition and intramolecular conjugate addition.... 
NUCLEOPHILES | POTENT | CPP | ANTAGONIST | ACID | CHEMISTRY, ORGANIC | PRONUCLEOPHILES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2017, Volume 139, Issue 10, pp. 3631 - 3634
We herein describe a synergistic chiral primary amine/achiral palladium catalyzed enantioselective terminal addition to allenes with α-branched β-ketocarbonyls... 
PALLADIUM | BETA-KETOESTERS | INTERMOLECULAR HYDROALKOXYLATION | ASYMMETRIC ALLYLIC ALKYLATION | SYNERGISTIC CATALYSIS | ALPHA-ALLYLATION | BRANCHED ALDEHYDES | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | PRONUCLEOPHILES | CARBOXYLIC-ACIDS | Palladium catalysts | Carbonyl compounds | Chemical properties | Aldehydes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2005, Volume 44, Issue 34, pp. 5526 - 5528
A variety of 1,2‐dihydroisoquinoline derivatives 3 have been prepared in good to high yields by the AgOTf‐catalyzed reaction of ortho‐alkynylaryl aldimines 1... 
imines | Mannich reaction | pronucleophiles | synthetic methods | nitrogen heterocycles | Pronucleophiles | Synthetic methods | Imines | Nitrogen heterocycles | ACETYLENES | ALPHA-AMINO | ASYMMETRIC-SYNTHESIS | ALDEHYDE | PROPARGYLAMINES | TERMINAL ALKYNES | COPPER | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | HIGHLY ENANTIOSELECTIVE ROUTE | 3-COMPONENT
Journal Article
Nature Communications, ISSN 2041-1723, 12/2018, Volume 9, Issue 1, pp. 3365 - 8
Amines are fundamental motifs in bioactive natural products and pharmaceuticals. Using simple toluene derivatives, a one-pot aminobenzylation of aldehydes is... 
C(SP)-H BONDS | ACTIVATION | ACIDS | MULTIDISCIPLINARY SCIENCES | AROMATIC HETEROCYCLES | ARYLATION | COMPLEXES | DIARYLMETHANE PRONUCLEOPHILES | DIMETHYL-SULFOXIDE | C-H BONDS | TRANSIENT DIRECTING GROUP | Amines | Amination | Natural products | Aromatic compounds | Toluene | Acidification | Cations | Derivatives | Aldehydes
Journal Article
by Lu, CJ and Yu, X and Chen, DK and Wang, H and Song, QB and Gao, JR
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 04/2019, Volume 17, Issue 14, pp. 3545 - 3551
A method for the allylic alkylation of aminophenol with alkynes was developed using a palladium-catalysed allylation reaction with 100% atom economy. A series... 
ALCOHOLS | INTRAMOLECULAR ASYMMETRIC HYDROAMINATION | ACID | RH | ALLYLIC ALKYLATION | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | REGIOSELECTIVE DECARBOXYLATIVE ADDITION | BETA-KETOACIDS | SULFONES | PRONUCLEOPHILES
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 10/2016, Volume 14, Issue 41, pp. 9896 - 9906
A novel approach for the synthesis of functionalized 1,2-dihydroisoquinolines from o-alkynylarylaldimines via the Reformatsky reaction without the aid of an... 
Journal Article
Dalton transactions, ISSN 1477-9226, 2015, Volume 44, Issue 14, pp. 6416 - 6422
The complexation of representative lanthanides with three calix[4]arenes functionalized with four pyrazine pendent arms containing different substituents such... 
METIS-314669 | IR-99644
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2018, Volume 57, Issue 30, pp. 9465 - 9469
The palladium‐catalyzed asymmetric side‐chain C(α)‐allylation of 2‐alkylpyridines, without using an external base, was developed. The high linear selectivities... 
ligand design | palladium | asymmetric catalysis | C−H activation | allylation | DIAMIDOPHOSPHITE LIGANDS | COMPLEXES | TERMINAL ALKYNES | ALKYLATIONS | CHEMISTRY, MULTIDISCIPLINARY | 3+2 CYCLOADDITION | NUCLEOPHILES | C-H activation | HETEROCYCLES | CHEMISTRY | DIARYLMETHANE PRONUCLEOPHILES | ALLYLIC SUBSTITUTION | Palladium | Catalysis | Chemical reactions | Allyl compounds | Carbonyls
Journal Article
Organic Letters, ISSN 1523-7060, 05/2013, Volume 15, Issue 9, pp. 2172 - 2175
The first organocatalytic diastereo- and enantioselective domino Michael/aldol reaction of 3-halogeno-1,2-diones to α,β-unsaturated aldehydes has been... 
CATALYSIS | BUILDING-BLOCKS | CHEMISTRY, ORGANIC | AMINOCATALYSIS | HENRY REACTION | 1,2-DICARBONYL COMPOUNDS | ASYMMETRIC TRANSFORMATIONS | CYCLIC 1,2-DIKETONES | PRONUCLEOPHILES | NITROALKENES | ECONOMY
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2008, Volume 49, Issue 38, pp. 5531 - 5533
Reaction of 2-alkynylbenzaldoximes 1 with 5 equiv of iodine in EtOH at room temperature gives the corresponding iodoisoquinoline N-oxides 2 in good to... 
Iodonium ion | Isoquinoline | 2-Alkynylbenzaldoxime | Electrophilic cyclization | Isoquinoline N-oxide | Iodine | iodonium ion | CHEMISTRY, ORGANIC | BENZODIAZEPINE-RECEPTOR | PAUSON-KHAND REACTIONS | PRONUCLEOPHILES | 2-alkynylbenzaldoxime | KETONES | POTENT | isoquinoline N-oxide | isoquinoline | LIGANDS | REDUCTION | iodine | electrophilic cyclization | DERIVATIVES
Journal Article
Organic Letters, ISSN 1523-7060, 05/2011, Volume 13, Issue 10, pp. 2586 - 2589
Highly functionalized alkenes can be prepared through phosphine-catalyzed β′-umpolung additions of nucleophiles (carbon-, oxygen-, nitrogen-, and... 
GAMMA | ORGANIC-SYNTHESIS | 4+2 ANNULATION | PEPTIDES | HETEROCYCLES | HIGHLY FUNCTIONALIZED TETRAHYDROPYRIDINES | CHEMISTRY, ORGANIC | CARBON-CARBON | SYNTHETIC APPLICATION | COUMARINS | PRONUCLEOPHILES
Journal Article
Synlett, ISSN 0936-5214, 09/2016, Volume 27, Issue 15, pp. 2213 - 2216
Abstract An efficient organocatalytic route for the activation of amide derivatives is reported. In this transformation, amide derivatives were employed as a... 
letter | tetrabutylphosphonium acetate | 1,2-dihydroisoquinoline | amide | multicomponent reaction | propiolate | ONE-POT SYNTHESIS | 3-COMPONENT REACTION | 1,2-DIHYDROISOQUINOLINES | CHEMISTRY, ORGANIC | PRONUCLEOPHILES | 2-dihydroisoquinoline | ISOQUINOLINE | AMINES | TANDEM NUCLEOPHILIC-ADDITION | DERIVATIVES | CYCLIZATION
Journal Article
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