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European Journal of Organic Chemistry, ISSN 1434-193X, 06/2018, Volume 2018, Issue 23, pp. 2984 - 2994
The racemization tendency of acyclic P‐chirogenic phosphanes is investigated experimentally and theoretically. Results of these investigations are important... 
Inversion barrier | Chirality | Isomerization | Racemization | P ligands | Phosphanes | Chiral resolution | PHOSPHORUS | RHODIUM | STABILITY | CHEMISTRY, ORGANIC | PYRAMIDAL INVERSION | LIGANDS | DIPHOSPHINES | REDUCTION | PHOSPHINES | NITROGEN | ASYMMETRIC HYDROGENATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2017, Volume 56, Issue 27, pp. 7858 - 7862
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2008, Volume 130, Issue 20, pp. 6362 - 6366
Amine nitrogen inversion, difficult to observe in aqueous solution, is followed in a chiral, supramolecular host molecule with purely rotational T-symmetry... 
BASIC SOLUTION | SLOW CHEMICAL-EXCHANGE | NMR | TERTIARY-AMINES | NUCLEAR-MAGNETIC-RESONANCE | GUEST EXCHANGE | HOST | AMINE INVERSION | CHEMISTRY, MULTIDISCIPLINARY | CROWDED PIPERIDINES | PYRAMIDAL INVERSION | Amines | Solvation | Chemical properties | Hydrogen bonding | Chirality | Analysis
Journal Article
Journal of Structural Chemistry, ISSN 0022-4766, 11/2018, Volume 59, Issue 6, pp. 1374 - 1380
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 11/2013, Volume 78, Issue 22, pp. 11623 - 11626
The nitrogen inversion of a N-phenyl aziridine fused to a succinimide ring is influenced by the presence of a phenyl ring in the succinimide moiety. The endo... 
RATES | ENERGY | STEREODYNAMICS | SPECTROSCOPY | RING | NUCLEAR-MAGNETIC-RESONANCE | SUBSTITUENTS | CHEMISTRY, ORGANIC | STEREOSELECTIVE-SYNTHESIS | SPECTRA | PYRAMIDAL INVERSION | Usage | Aziridines | Chemical properties | Research | Nuclear magnetic resonance | Cyclic compounds
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2007, Volume 46, Issue 39, pp. 7412 - 7416
Journal Article
Organometallics, ISSN 0276-7333, 11/1999, Volume 18, Issue 24, pp. 5141 - 5151
The chiral Pt(II) phosphido complex Pt(dppe)(Me)[P(Mes)(Men)] (dppe = Ph2PCH2CH2PPh2, Mes = 2,4,6-Me3C6H2, Men = (−)menthyl, 1) was prepared by proton transfer... 
COORDINATED SECONDARY | LIGANDS | MOLECULAR-STRUCTURE | STABILITY | ISOMERIZATION | CHEMISTRY | CHEMISTRY, ORGANIC | CRYSTAL | METAL-SUBSTITUTED PHOSPHANES | DYNAMIC KINETIC RESOLUTION | PYRAMIDAL INVERSION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of Crystal Growth, ISSN 0022-0248, 2004, Volume 269, Issue 2, pp. 249 - 256
Journal Article
Organometallics, ISSN 0276-7333, 07/2002, Volume 21, Issue 15, pp. 3208 - 3214
The cyclometalated cationic Pd(II) and Pt(II) complexes [M(diphos)(CH2C6H2Me2P(Mes)(H))][X] (5−8:  M = Pd, Pt; diphos = dppe (Ph2PCH2CH2PPh2), dppen... 
PHOSPHANES | ACTIVATION | LIGANDS | OLEFIN INSERTION | PLATINUM(II) | CHEMISTRY, ORGANIC | CATALYZED ACRYLONITRILE HYDROPHOSPHINATION | PT-P BOND | PYRAMIDAL INVERSION | HYDRIDE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2018, Volume 140, Issue 35, pp. 11091 - 11100
In this study, we report the preparation, conformational dynamics, and recognition characteristics of novel molecular capsule 1 comprising a bowl-shaped... 
(FE4L4)-L-II CAGE | CHIROPTICAL SWITCHES | HYDROGEN-BOND | PI INTERACTIONS | HELICITY INVERSION | SYSTEMS CHEMISTRY | HOST-GUEST INTERACTIONS | SUPRAMOLECULAR CHEMISTRY | CHEMISTRY, MULTIDISCIPLINARY | PYRAMIDAL INVERSION | ANION-BINDING
Journal Article
Organic Letters, ISSN 1523-7060, 06/2004, Volume 6, Issue 13, pp. 2197 - 2200
A theoretical study on the pyramidal inversion of the chiral sulfur compounds SO(X)(Me) (X = Cl, OMe, p-MePh) has been carried out by means of the... 
NITROGEN INVERSION | THERMAL RACEMIZATION | ASYMMETRIC-SYNTHESIS | BARRIER | STEREOCHEMISTRY | CHEMISTRY, ORGANIC | BIS-SULFOXIDES | INTERCONVERSION | SULFINYL CHLORIDES | DYNAMIC KINETIC RESOLUTION | PYRAMIDAL INVERSION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2014, Volume 136, Issue 50, pp. 17634 - 17644
Journal Article
Synlett, ISSN 0936-5214, 10/2007, Volume 2007, Issue 17, pp. 2627 - 2634
Journal Article
Tetrahedron: Asymmetry, ISSN 0957-4166, 2006, Volume 17, Issue 9, pp. 1355 - 1369
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 05/2019, Volume 55, Issue 34, pp. 4909 - 4912
Dibenzo[b, e] phosphindolizines 1 were successfully synthesized by a ring-closing metathesis of benzo[b] phosphole chalcogenides 2a-2c with two vinyl tethers... 
PHOSPHORUS | AROMATICITY | OXIDE | BEHAVIOR | BARRIERS | DEVICES | CHEMISTRY, MULTIDISCIPLINARY | PYRAMIDAL INVERSION
Journal Article
The Journal of Physical Chemistry A, ISSN 1089-5639, 04/1998, Volume 102, Issue 18, pp. 3193 - 3201
The chemistry of a series of aziridines and diaziridines, including the parent compounds aziridine and diaziridine and several methyl-substituted analogues, is... 
CYCLOPROPANE | PERTURBATION-THEORY | MOLECULAR CALCULATIONS | ETHYLENE-OXIDE | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | IMPLEMENTATION | CHEMISTRY, PHYSICAL | BASIS-SETS | COUPLED CLUSTER SINGLE | ELECTRON CORRELATION | PYRAMIDAL INVERSION | FIRST-ROW | Electronic structure | Nitrogen | Heterocyclic compounds | Analysis
Journal Article
Chemical Science, ISSN 2041-6520, 2016, Volume 7, Issue 12, pp. 6981 - 6987
The room temperature reaction of a 1 : 1 mixture of phosphorus tribromide (PBr3) and the N-heterocyclic carbene... 
CATALYSIS | CRYSTALLINE CARBENE | COVALENT RADII | COMPLEXES | COMPOUND | CHEMISTRY, MULTIDISCIPLINARY | PYRAMIDAL INVERSION
Journal Article
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