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rhodium (339) 339
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European Journal of Inorganic Chemistry, ISSN 1434-1948, 12/2019, Volume 2019, Issue 45, pp. 4846 - 4854
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2019, Volume 58, Issue 40, pp. 14110 - 14114
We report the C−H alkylation of biarylphosphines at the ortho′ position(s) with alkenes by using rhodium(I) catalysis, which provides straightforward access to... 
C−H functionalization | carbon dioxide | alkylation | phosphine ligands | rhodium | Alkenes | Rhodium | Catalysts | Aromatic compounds | Carbon dioxide | Bromides | Carboxylation | Catalysis | Alkylation | Phosphines
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 09/2019, Volume 361, Issue 18, pp. 4201 - 4207
The synthesis of β2,2‐amino esters was successfully achieved via Rh‐catalysed regioselective hydroaminomethylation of methyl methacrylate with secondary amines... 
hydroformylation | Hydroaminomethylation | β-amino acids | hydrogenation | tandem | Chemical industry | Amines | Regioselectivity | Aniline | Precursors | Toluene | Esters | Chemical synthesis | Molecular sieves | Polymethyl methacrylate
Journal Article
Angewandte Chemie, ISSN 0044-8249, 09/2019, Volume 131, Issue 36, pp. 12659 - 12663
A rhodium‐catalyzed system is introduced for in situ modification of biaryl‐type monophosphines with hydrosilanes through a PIII‐chelation‐assisted... 
Ligandendesign | Rhodium | Phosphane | Silylierungen | C-H-Aktivierung | Dehydrogenation | Chelation | Ligands | Chemical reactions | Phosphines | Substrates
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2019, Volume 58, Issue 36, pp. 12529 - 12533
A rhodium‐catalyzed system is introduced for in situ modification of biaryl‐type monophosphines with hydrosilanes through a PIII‐chelation‐assisted... 
ligand design | phosphine | C−H activation | silylation | rhodium | O BOND | SILICON | C-H SILYLATION | CHEMISTRY, MULTIDISCIPLINARY | C-H activation | LIGANDS | PHENOLS | BOND ACTIVATION | ORTHO-ARYLATION | CATALYSTS | Rhodium | Dehydrogenation | Chelation | Ligands | Chemical reactions | Phosphines | Substrates
Journal Article
Petroleum Chemistry, ISSN 0965-5441, 9/2019, Volume 59, Issue 9, pp. 1009 - 1016
The feature of hydroformylation of model gas mixtures with different ethylene, hydrogen, and methane concentrations in the presence of rhodium catalysts have... 
oxygenates | oxygen-containing products | propanal | catalyst recycling | Chemistry | methane | cracked gases | hydroformylation | Industrial Chemistry/Chemical Engineering | phosphine ligands | ethylene | fuel additives
Journal Article
Catalysis Communications, ISSN 1566-7367, 09/2019, Volume 129, p. 105721
The hydroformylation of 1-decene was conducted in a gas-liquid-liquid system featuring a deep eutectic solvent to enable recycling of the noble metal catalyst.... 
Phosphine ligands | Catalyst recycling | Biphasic catalysis | Deep eutectic solvent | Hydroformylation | LEAN AQUEOUS HYDROFORMYLATION | CATALYZED HYDROFORMYLATION | LIGANDS | CHEMISTRY, PHYSICAL | TANDEM REACTION
Journal Article
by Jin, X and Feng, JY and Song, HB and Yao, JJ and Ma, QQ and Zhang, M and Yu, C and Li, SM and Yu, ST
GREEN CHEMISTRY, ISSN 1463-9262, 07/2019, Volume 21, Issue 13, pp. 3583 - 3596
The major limitation of classic biphasic ionic liquid (IL) catalysis is the heavy use of solvent ILs, which not only violates green chemistry principles but... 
ALKENES | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | BIPHASIC HYDROFORMYLATION | SOLVENTS | DIPHOSPHINE | ACETALIZATION | XANTPHOS-TYPE LIGAND | RHODIUM COMPLEXES | CARBON-DIOXIDE | SALTS | MOIETIES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2019, Volume 58, Issue 27, pp. 9194 - 9198
Journal Article
by Jin, X and Feng, JY and Ma, QQ and Song, HB and Liu, QQ and Xu, BY and Zhang, M and Li, SM and Yu, ST
GREEN CHEMISTRY, ISSN 1463-9262, 06/2019, Volume 21, Issue 12, pp. 3267 - 3275
In classical biphasic ionic liquid (IL) catalysis, the use of a large amount of solvent IL is a major limitation, and usually leads to a waste of resources and... 
ALKENES | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | RHODIUM | SOLVENTS | VERSATILE | FLOW HOMOGENEOUS HYDROFORMYLATION | COMPLEXES | ACETALIZATION | XANTPHOS-TYPE LIGAND | SEPARATION | CHEMISTRY, MULTIDISCIPLINARY | HALOGEN-FREE
Journal Article
Zeitschrift für Naturforschung B, ISSN 0932-0776, 05/2019, Volume 74, Issue 5, pp. 455 - 457
The synthesis and structural characterization of the new olefinic complex [Rh( -C )(coe)(P Bu H)] ( , coe =  -cyclooctene) is reported. The title compound was... 
rhodium(I) | crystal structure | olefine complex | phosphane complex | CHEMISTRY, ORGANIC | DISPLACEMENT | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ChemSusChem, ISSN 1864-5631, 05/2019, Volume 12, Issue 10, pp. 2195 - 2201
The iron complex of tetradentate tris[2‐(diphenylphosphino) ethyl]phosphine (PP3), [Fe(PP3)(MeCN)2](BF4)2, was able to electrocatalytically reduce CO2 to... 
amidation | methanol | carbon dioxide | iron | electrocatalysis | DIHYDRIDE | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | RHODIUM | BICARBONATES | CATALYTIC-HYDROGENATION | ELECTROCHEMICAL REDUCTION | AMINE | CHEMISTRY, MULTIDISCIPLINARY | ALKYL FORMATES | HOMOGENEOUS CATALYSIS | CARBON-DIOXIDE | CAPTURE | Carbamates | Acetonitrile | Methanol | Chemical reduction | Iron | Carbon dioxide
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2019, Volume 58, Issue 19, pp. 6220 - 6224
Species with 2‐center, 3‐electron (2c/3e−) σ bonds are of interest owing to their fascinating electronic structures and potential for interesting reactivity... 
iridium | metalloradicals | structure elucidation | electronic structure | rhodium | Wave diffraction | Orbitals | Phosphine | Metals | X-ray diffraction | Continuous radiation | Covalent bonds | Partial stabilization | Rhodium | Ligands | Electron paramagnetic resonance | Iridium | Destabilization | Electrons
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2019, Volume 25, Issue 25, pp. 6317 - 6319
Journal Article
Journal of Catalysis, ISSN 0021-9517, 05/2019, Volume 373, pp. 215 - 221
IrCl3⋅3H2O with the involvement of the electron-deficient phosphines (L1-L6) was able to serve as a bi-functional catalyst with dual functions of transition... 
Electron-deficient phosphine | Bi-functional catalyst | Hydroformylation | Iridium complex | Acetalization | Co-catalysis | Tandem reaction | RHODIUM | COMPLEXES | CHEMISTRY, PHYSICAL | ALCOHOLS | ENGINEERING, CHEMICAL | LIGANDS | BIFUNCTIONAL CATALYST | N-ALKYLATION | OLEFINS | ARYL ALKENES | EFFICIENT | Green chemistry | Catalysis | Structure | Crystals | Green technology
Journal Article