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Chemical Science, ISSN 2041-6520, 2017, Volume 8, Issue 2, pp. 846 - 863
The empty pz-orbital of a three-coordinate organoboron compound leads to its electron-deficient properties, which make it an excellent π-acceptor in conjugated... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2012, Volume 134, Issue 10, pp. 4529 - 4532
Triphenylborane and 9,10-diphenyl-9,10-dihydro-9,10-diboraanthracene, constrained to a planar arrangement with methylene tethers, were synthesized by... 
ORGANOBORON COMPOUNDS | POLYMERS | PI-ELECTRON MATERIALS | BORON | SUBSTITUENTS | OPTICAL-PROPERTIES | DIBENZOBOROLE | SYSTEMS | CONFORMATIONAL-ANALYSIS | CHEMISTRY, MULTIDISCIPLINARY | FLUORIDE | Friedel-Crafts reactions | Borane | Chemical properties | Ring formation (Chemistry) | Analysis
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2006, Volume 71, Issue 3, pp. 883 - 893
Nucleus-independent chemical shifts (NICS) have been used extensively for the identification of aromaticity properties of molecules, ions, intermediates, and... 
PI-ELECTRON DELOCALIZATION | CHEMISTRY, ORGANIC | LOCAL AROMATICITY | RING CURRENTS | Chemical properties | Research | Transition state (Chemistry) | Polycyclic compounds
Journal Article
Nature Communications, ISSN 2041-1723, 2013, Volume 4, Issue 1, p. 1344
Purely organic materials are generally insulating. Some charge-carrier generation, however, can provide them with electrical conductivity. In multi-component... 
DESIGN | COMPLEX | TETRATHIAFULVALENE | SUPERCONDUCTIVITY | ACID | MOLECULAR CONDUCTORS | GROUND-STATE | MULTIDISCIPLINARY SCIENCES | PI-ELECTRON DONORS | RADICALS | DERIVATIVES
Journal Article
Dalton Transactions, ISSN 1477-9226, 9/2016, Volume 45, Issue 36, pp. 13996 - 147
This perspective highlights recent progress on the design, synthesis and applications of thienylboranes as building blocks for new functional materials.... 
POLYMER SOLAR-CELLS | FLUORESCENCE RESPONSE | PI-ELECTRON MATERIALS | HYDROBORATION POLYMERIZATION | NONLINEAR-OPTICAL PROPERTIES | MOLECULAR-STRUCTURES | C-H BORYLATION | 3-COORDINATE ORGANOBORON COMPOUNDS | FIELD-EFFECT TRANSISTORS | BAND-GAP | CHEMISTRY, INORGANIC & NUCLEAR | Exchange | Boron | Merging | Switches | Electronics | Boranes | Robustness | Assembly
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 05/2019, Volume 55, Issue 43, pp. 6022 - 6025
We introduce the first series of enantiopure twistacene radical cations, which form reversibly upon chemical or electrochemical oxidation. Their vis-NIR... 
PI-ELECTRON DELOCALIZATION | ANTHRACENE | ABSORPTION-SPECTRA | X-RAY CRYSTALLOGRAPHY | RESONANCE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 10/2009, Volume 42, Issue 10, pp. 1584 - 1596
Journal Article
Chemical Society reviews, ISSN 0306-0012, 09/2015, Volume 44, Issue 18, pp. 6494 - 6518
Cyclophanes have been firmly entrenched as a distinct class of compounds for well over half a century. The two main factors that have kept this field of... 
Journal Article
Chemical Communications, ISSN 1359-7345, 2015, Volume 51, Issue 87, pp. 15808 - 15810
The high-yield synthesis of a boron-doped [4] helicene was achieved through a Ni-mediated Yamamoto C-C-coupling reaction; the moderate distortion of the... 
NICKEL-COMPLEXES | POLYMERS | PI-ELECTRON MATERIALS | MECHANISM | BUILDING-BLOCKS | CHEMISTRY | 9,10-DIHYDRO-9,10-DIBORAANTHRACENES | FUSED POLYCYCLIC AROMATICS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 11/2018, Volume 20, Issue 21, pp. 6868 - 6871
New types of [2.2]­paracyclophane derivatives, g-BNMe2-Cp and m-BNMe2-Cp, in which electron-donating NMe2 and the electron-accepting BMes2 are introduced at... 
LIGHT-EMITTING-DIODES | SPACE CHARGE-TRANSFER | ORGANIC-SOLIDS | BORON | ASSEMBLIES | PI-ELECTRON SYSTEMS | OPTICAL-PROPERTIES | DELOCALIZATION | CHEMISTRY, ORGANIC | ELECTROLUMINESCENCE | MOLECULES
Journal Article
Nature Communications, ISSN 2041-1723, 11/2016, Volume 7, Issue 1, p. 13620
Aromaticity is a key concept in organic chemistry. Even though this concept has already been theoretically extrapolated to three dimensions, it usually still... 
CORE | NORCORROLE | PI-ELECTRON SYSTEMS | NONLINEAR-OPTICAL PROPERTIES | MULTIDISCIPLINARY SCIENCES | EXPANDED PORPHYRINS | PERIMETER MODEL | AROMATIC RINGS | 4N-ELECTRON | BIOLOGICAL RECOGNITION | MCD
Journal Article
Organic Letters, ISSN 1523-7060, 02/2016, Volume 18, Issue 4, pp. 720 - 723
We report the first examples of straightforward trans-hydroboration of internal alkynes at room temperature with 9-BBN, producing five-membered... 
SELECTIVE HYDROBORATION | POLYMERS | QUADRUPOLAR | PI-ELECTRON MATERIALS | BORON | N,C-CHELATE | COMPLEXES | REACTIVITY | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | AMINE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2013, Volume 135, Issue 34, pp. 12892 - 12907
9,10-Dihydro-9,10-diboraanthracene (DBA) provides a versatile scaffold for the development of boron-doped organic luminophores. Symmetrically C-halogenated... 
BIDENTATE LEWIS-ACIDS | ORGANOBORON POLYMERS | DIELS-ALDER | PI-ELECTRON MATERIALS | BORON | CONJUGATED POLYMERS | CHEMICAL-SHIFTS | OPTICAL-PROPERTIES | VERSATILE BUILDING-BLOCKS | AROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article