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pinacol rearrangement (132) 132
chemistry, organic (126) 126
chemistry, multidisciplinary (95) 95
catalysis (48) 48
ketones (46) 46
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Chemical Communications, ISSN 1359-7345, 2017, Volume 54, Issue 2, pp. 196 - 199
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2018, Volume 16, Issue 30, pp. 5441 - 5445
A straightforward two-step entry to -oxgenated ,-unsaturated ketones from readily available ,-unsaturated ketones is disclosed. It was found that bis(allylic)... 
MIGRATION | ALCOHOLS | INITIATED PINACOL REARRANGEMENT | RING EXPANSION | STEREOSELECTIVE CONSTRUCTION | ACID CATALYSIS | STEREOCHEMISTRY | SEMIPINACOL REARRANGEMENT | CHEMISTRY, ORGANIC | WAGNER-MEERWEIN SHIFT | DERIVATIVES
Journal Article
Zeitschrift für anorganische und allgemeine Chemie, ISSN 0044-2313, 01/2019, Volume 645, Issue 1, pp. 22 - 26
Using 1,1,2‐triphenylethane‐1,2‐diol, AgSbF6, and NOSbF6, two different carbonyl products of rearrangement were synthesized: neutral ketone compound... 
Silver | Wagner–Meerwein shift | Migratory aptitude | Pinacol rearrangement | MIGRATION | EPOXIDES | ELECTRON-TRANSFER | MEERWEIN REARRANGEMENT | SALTS | Wagner-Meerwein shift | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of Catalysis, ISSN 0021-9517, 2010, Volume 270, Issue 1, pp. 196 - 205
One-pot synthesized Zr–SBA-15 materials containing superficial zirconia clusters were the most efficient catalyst in pinacol-type rearrangement, in comparison... 
One-pot synthesis | Zirconium | Pinanediol | Mesoporous materials | Pinacol rearrangement | SBA-15 | POSTSYNTHESIS | GENERATED ACIDIC ENVIRONMENT | MESOPOROUS MOLECULAR-SIEVES | CHEMISTRY, PHYSICAL | INORGANIC SALTS | COPOLYMER SYNTHESIS | ENGINEERING, CHEMICAL | SILICA FILMS | AID | CHLORIDE | Small business | Analysis
Journal Article
Organic & Biomolecular Chemistry, ISSN 1477-0520, 01/2018, Volume 16, Issue 30, pp. 5441 - 5445
A straightforward two-step entry to α-oxgenated β,γ-unsaturated ketones from readily available α,β-unsaturated ketones is disclosed. It was found that... 
Acidity | Catalysis | Ketones | Chemical synthesis | Computer applications | Alcohols
Journal Article
Tetrahedron, ISSN 0040-4020, 11/2018, Volume 74, Issue 48, pp. 6939 - 6945
A BINOL-phosphoric acid-catalyzed furylogous Pinacol rearrangement is developed. This reaction produces spiro cyclopentanone in good yields under mild... 
Cyclopentanones | Ring-expansion | Furans | Pinacol rearrangement | FURAN RING | STRATEGY | CHEMISTRY, ORGANIC | CLEAVAGE | INDOLES | TONGHAOSU | FURFURAL TOSYLHYDRAZONES | SPIROACETAL-ENOL ETHERS | CONSTRUCTION | ACCESS | DEAROMATIZATION | Phosphates | Phosphoric acid | Enantiomers
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 01/2018, Volume 59, Issue 3, pp. 243 - 246
[Display omitted] •The synthesis of 3,4-dihetarylcyclopent-3-en-1,2-diols is proposed.•The pinacol rearrangement of 3,4-dihetarylcyclopent-3-en-1,2-diols is... 
Interrupted reaction | Cyclopentenone | Diarylethene | Pinacol rearrangement | Cyclopentenyl cation | Dimerization | CARBON | MECHANISM | DOUBLE-BOND MIGRATION | NAZAROV CYCLIZATION | CHEMISTRY, ORGANIC | DIARYLETHENES | 2,3-DIARYLCYCLOPENT-2-EN-1-ONES | KETONES | EXPLORATION | Glycols | Resveratrol | Catalysis
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 11/2016, Volume 22, Issue 45, pp. 16072 - 16077
Journal Article
Organic Letters, ISSN 1523-7060, 02/2015, Volume 17, Issue 4, pp. 1014 - 1017
A novel carbon electrophile induced intermolecular oxa-Diels–Alder/semipinacol rearrangement/aldol cascade reaction of allylic silyl ether with β,γ-unsaturated... 
INVERSE-ELECTRON-DEMAND | ASYMMETRIC-SYNTHESIS | MARASMIUS-ALLIACEUS | ALDER REACTIONS | SEMIPINACOL REARRANGEMENT | CATALYZED TRIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | STEREOSELECTIVE TOTAL-SYNTHESIS | ENANTIOSELECTIVE TOTAL-SYNTHESIS | PRINS-PINACOL SYNTHESIS | ALPHA-HYDROXY EPOXIDES
Journal Article
Nature Communications, ISSN 2041-1723, 06/2015, Volume 6, Issue 1, p. 7332
Natural products are a vital source of lead compounds in drug discovery. Development of efficient tandem reactions to build useful compounds and apply them to... 
STEREOCONTROLLED PREPARATION | ETHERS | TETRAHYDROFURANS | RING | MULTIDISCIPLINARY SCIENCES | OXIDATIVE ACTIVATION | COUPLING REACTION | SEMIPINACOL REARRANGEMENT | EFFICIENT CONSTRUCTION | PRINS-PINACOL SYNTHESIS | CYCLIZATION | Diterpenes - chemical synthesis | Indium - chemistry | Benzoquinones - chemistry
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2018, Volume 140, Issue 36, pp. 11184 - 11188
Chiral Lewis acid catalyzed asymmetric formation of cyclobutanones from α-silyloxyacroleins and α-alkyl or α-aryl diazoesters has been developed. In the... 
ORGANIC-SYNTHESIS | DONOR-ACCEPTOR CYCLOPROPANES | NATURAL-PRODUCT SYNTHESIS | C-H BOND | RING EXPANSION | ENANTIOSELECTIVE SYNTHESIS | OXAZABOROLIDINIUM ION | QUATERNARY STEREOCENTERS | CHEMISTRY, MULTIDISCIPLINARY | PINACOL REARRANGEMENT | CONJUGATE ADDITION
Journal Article
by Liu, Y and Yeung, YY
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 08/2017, Volume 15, Issue 31, pp. 6478 - 6482
We have developed ring-strain dictated divergent diastereo-selective fluorinating Prins cyclization reactions or semipinacol rearrangement reactions to access... 
BROMOLACTONIZATION | KETONES | SCOPE | CONSTRUCTION | CHEMISTRY, ORGANIC | PRINS/PINACOL REACTION | CASCADE | STEREOSELECTIVE-SYNTHESIS | CATALYST | DERIVATIVES | PINACOL TANDEM PROCESS
Journal Article
ACS Catalysis, ISSN 2155-5435, 07/2017, Volume 7, Issue 7, pp. 4435 - 4440
Journal Article
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, ISSN 1860-5397, 01/2020, Volume 16, Issue 1, pp. 88 - 105
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 02/2013, Volume 54, Issue 6, pp. 526 - 529
In this Letter we report on the reaction of 4H-cyclopenta[2,1-b:3,4-b′]dithiophen-4-one with various trivalent organophosphorus derivatives, with an emphasis... 
X-ray diffraction | 4H-Cyclopenta[2,1-b:3,4-b′]dithiophene | Chemical shift calculations | Pinacol rearrangement | Trivalent organophosphorus reagents | DEFECTS | CYCLOPENTADITHIOPHENE | 4H-Cyclopenta[2,1-b:3,4-b ']dithiophene | DONOR | PERFORMANCE | CHEMISTRY, ORGANIC | Chemical tests and reagents
Journal Article
Chemical Communications, ISSN 1359-7345, 02/2013, Volume 49, Issue 16, pp. 1648 - 1650
A catalytic intermolecular carbon electrophile induced semipinacol rearrangement was realized and the asymmetric version was also preliminarily accomplished... 
PRINS-CYCLIZATION | NATURAL-PRODUCT SYNTHESIS | RING EXPANSION | FORMAL SYNTHESIS | CONSTRUCTION | COMPLEXES | EFFICIENT SYNTHESIS | ACETALS | ENE REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | PINACOL TANDEM PROCESS | Models, Molecular | Molecular Structure | Catalysis | Stereoisomerism | Cyclohexenes - chemistry | Carbon - chemistry | Architecture | Asymmetry | Catalysts | Carbon
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 03/2013, Volume 11, Issue 9, pp. 1460 - 1462
Journal Article
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