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European journal of organic chemistry, ISSN 1434-193X, 08/2010, Volume 2010, Issue 24, pp. 4588 - 4616
The reactions of enantiopure S‐tert‐butyl sulfones of the type R1CH(R2)SO2tBu (≥99 % ee) with lithiumorganyl compounds gave the corresponding chiral α‐sulfonyl... 
Racemi­zation | Carbanions | Enantioselectivity | Chirality | Alkylation | Racemization
Journal Article
Synthesis, ISSN 0039-7881, 03/2019, Volume 51, Issue 5, pp. 1263 - 1272
Abstract Highly enantioselective desymmetrisation of Fittig’s lactones with alcohols is promoted by bifunctional cinchona squaramides. The reactions were... 
paper | bislactone acylal | Fittig's lactone | bifunctional organocatalysis | desymmetrization | racemization
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 08/2018, Volume 57, Issue 34, pp. 11040 - 11044
Atropo‐enantioselective C−H functionalization reactions are largely limited to the dynamic kinetic resolution of biaryl substrates through the introduction of... 
axial chirality | palladium | asymmetric catalysis | C−H activation | atropisomer | Enantiomers | Palladium | Catalysis | Racemization | Chirality | Substrates | Computer applications
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 05/2018, Volume 24, Issue 30, pp. 7601 - 7604
Diquats with extremely high racemization barriers with ΔG≠theor of 233 kJ mol−1 at 180 °C are described. Reported configurational robustness is due to a... 
racemization barrier | chiral selector | helical chirality | N-heterocyclic cations | capillary electrophoresis | Dyes | Synthesis | Chirality | Racemization | Nitrogen atoms | Diquat | Atomic structure | Selectors | Molecular chains
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 08/2018, Volume 57, Issue 32, pp. 10278 - 10282
We have discovered that the racemization of configurationally stable, axially chiral 2,2′‐dihydroxy‐1,1′‐biaryls proceeds with a catalytic amount of a... 
ruthenium | biaryl compounds | racemization | dynamic kinetic resolution | lipase | Lipase | Synthesis | Organic compounds | Racemization | Catalysis | Asymmetric synthesis | Diols
Journal Article
Tetrahedron: asymmetry, ISSN 0957-4166, 2006, Volume 17, Issue 14, pp. 2133 - 2142
( S)-Perillyl alcohol was converted to ( R)-cryptone (91.5–93% ee) in six steps, which was then treated with methyllithium to give (1 S,4... 
Racemization
Journal Article
Synlett, ISSN 0936-5214, 03/2016, Volume 27, Issue 4, pp. 551 - 554
Abstract A simple and reliable protocol for determining the enantiopurity of 3,3′-substituted BINOL- and H8-BINOL-based chiral phosphoric acids (CPA) using 31... 
cluster | P NMR | chiral phosphoric acid | racemization | enantiopurity
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 01/2014, Volume 53, Issue 5, pp. 1218 - 1250
Journal Article