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1. Full Text Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise
by Soleilhavoup, Michèle and Bertrand, Guy
Accounts of Chemical Research, ISSN 0001-4842, 02/2015, Volume 48, Issue 2, pp. 256 - 266
Conspectus Carbenes are compounds that feature a divalent carbon atom with only six electrons in its valence shell. In the singlet state, they possess a lone... 
CRYSTALLINE CARBENE | TRANSITION-METAL-COMPLEXES | INTRAMOLECULAR HYDROIMINIUMATION | RADICAL-CATION | ALKYL AMINO CARBENES | N-HETEROCYCLIC CARBENES | SINGLET CARBENES | CATALYTIC-ACTIVITY | LIGAND PROPERTIES | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY
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2. Full Text Design of aqueous redox-enhanced electrochemical capacitors with high specific energies and slow self-discharge
by Chun, Sang-Eun and Evanko, Brian and Wang, Xingfeng and Vonlanthen, David and Ji, Xiulei and Stucky, Galen D and Boettcher, Shannon W
Nature Communications, ISSN 2041-1723, 08/2015, Volume 6, Issue 1, p. 7818
Electrochemical double-layer capacitors exhibit high power and long cycle life but have low specific energy compared with batteries, limiting applications.... 
STORAGE | CARBON ELECTRODES | REDUCTION | BROMINE | METHYL VIOLOGEN | PERFORMANCE | MULTIDISCIPLINARY SCIENCES | RADICAL CATION | GRAPHENE | SUPERCAPACITOR | ACTIVE ELECTROLYTE
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3. Full Text A Consecutive C−H Functionalization Triggered by Oxidation of Active sp 3 C−H Bonds: Construction of 3,4-Dihydroquinoline-3-one Derivatives
by Jia, Xiaodong and Hou, Wentao and Shao, Yu and Yuan, Yu and Chen, Qian and Li, Pengfei and Liu, Xiaofei and Ji, Honghe
Chemistry - A European Journal, ISSN 0947-6539, 2017, Volume 23, Issue 53, pp. 12980 - 12984
We report a consecutive C-H functionalization that constructs 3,4-dihydroquinoline-3-one derivatives in high yields. This reaction is triggered by oxidation of... 
C−H functionalization | quaternary center | 3,4-dihydroquinoline-3-one | aerobic oxidation | radical cation
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4. Full Text Tetrathiafulvalene: the advent of organic metals
by Martn, Nazario
Chemical Communications, ISSN 1359-7345, 7/2013, Volume 49, Issue 63, pp. 725 - 727
Tetrathiafulvalene (TTF) is among the most versatile and well-known molecules which exhibits outstanding redox properties and a remarkable electron donor... 
RADICAL-CATION | TTF | CHEMISTRY | SYSTEMS | NLO PROPERTIES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
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5. Full Text Electrogenerated Cationic Reactive Intermediates: The Pool Method and Further Advances
by Yoshida, Jun-ichi and Shimizu, Akihiro and Hayashi, Ryutaro
Chemical Reviews, ISSN 0009-2665, 05/2018, Volume 118, Issue 9, pp. 4702 - 4730
Electrochemistry serves as a powerful method for generating reactive intermediates, such as organic cations. In general, there are two ways to use reactive... 
CARBON BOND FORMATION | RADICAL-CATION | ONE-STEP PREPARATION | DIARYLCARBENIUM ION POOLS | AROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | C-H AMINATION | ASSISTED SEQUENTIAL INTRODUCTION | ELECTROCHEMICAL OXIDATION | ENOL SILYL ETHERS | ANODIC-OXIDATION
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6. Full Text Stabilization of reactive species by supramolecular encapsulation
by Galan, Albano and Ballester, Pablo
Chemical Society Reviews, ISSN 0306-0012, 03/2016, Volume 45, Issue 6, pp. 1720 - 1737
Molecular containers have attracted the interest of supramolecular chemists since the early beginnings of the field. Cavitands' inner cavities were quickly... 
O-BENZYNE | ASSEMBLED COORDINATION CAGE | INNER PHASE | CAPSULE | RADICAL-CATION STABILIZATION | HOST | N-OXIDES | CHEMISTRY, MULTIDISCIPLINARY | ROOM-TEMPERATURE STABILIZATION | MOLECULAR CONTAINERS | CARBOXYLIC-ACIDS
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7. Full Text Structures and Electronic Properties of Diisopropylaminoborane Substituted with Highly Electron-Rich pi-Conjugated Systems and Their Oxidized States
by Yoshida, K and Suzuki, S and Kozaki, M and Okada, K
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, ISSN 0009-2673, 11/2019, Volume 92, Issue 11, pp. 1902 - 1909
We have designed and synthesized three kinds of diisopro-pylaminoboranes substituted with two electron-donating pi-conjugated systems, 2a: bis(phenothiazinyl)... 
Main group elements | Radical cation | Trimethylenemethane | RADICALS | CHEMISTRY, MULTIDISCIPLINARY
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8. Full Text Electrical magnetochiral anisotropy in a bulk chiral molecular conductor
by Pop, F and Auban-Senzier, P and Canadell, E and Rikken, GLJA and Avarvari, N
NATURE COMMUNICATIONS, ISSN 2041-1723, 05/2014, Volume 5
So far, no effect of chirality on the electrical properties of bulk chiral conductors has been observed. Introduction of chiral information in... 
TRANSPORT | COMPLETE SERIES | TETRATHIAFULVALENE | METALS | RADICAL-CATION SALTS | DICHROISM | BEHAVIOR | MULTIDISCIPLINARY SCIENCES | TTF | ORGANIC CONDUCTORS | CRYSTAL
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9. Full Text Ultrafast chemistry of water radical cation, H 2 O •+ , in aqueous solutions
by Ma, Jun and Wang, Furong and Mostafavi, Mehran
Molecules, 2018, Volume 23, Issue 2
Electron transfer | Radiation chemistry | Water radical cation | Oxidizing radicals
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10. Full Text Formation of polypseudorotaxane networks by cross-linking the quadruple hydrogen bonded linear supramolecular polymers via bisparaquat molecules
by Li, Shao-Lu and Xiao, Tangxin and Hu, Bingjie and Zhang, Yajie and Zhao, Feng and Ji, Ya and Yu, Yihua and Lin, Chen and Wang, Leyong
Chemical Communications, ISSN 1359-7345, 10/2011, Volume 47, Issue 38, pp. 10755 - 10757
The creation of novel crown ether-paraquat polypseudorotaxane networks, constructed by bisparaquat monomers threading into the cavity of the crown ether units... 
MONOMERS | POLYMERIZATIONS | ORTHOGONAL BINDING INTERACTIONS | RADICAL-CATION | CYCLODEXTRIN | STABILIZATION | CONSTRUCTION | POLYROTAXANE | DRIVEN | CHEMISTRY, MULTIDISCIPLINARY | ARCHITECTURES
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11. Full Text Excited-State Conformational/Electronic Responses of Saddle-Shaped N,N′‑Disubstituted-Dihydrodibenzo[a,c]phenazines: Wide-Tuning Emission from Red to Deep Blue and White Light Combination
by Zhang, Zhiyun and Wu, Yu-Sin and Tang, Kuo-Chun and Chen, Chi-Lin and Ho, Jr-Wei and Su, Jianhua and Tian, He and Chou, Pi-Tai
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 26, pp. 8509 - 8520
A tailored strategy is utilized to modify 5,10-dimethylphenazine (DMP) to donor–acceptor type N,N′-disubstituted-dihydrodibenzo­[a,c]­phenazines. The... 
SUBSTITUTED RADICAL-CATION | FLUORESCENCE | LUMINESCENCE | ISOMERIZATION | LARGE STOKES SHIFT | PHOTOPHYSICS | SYSTEMS | MODEL | CHEMISTRY, MULTIDISCIPLINARY | GEOMETRY | Chemical properties | Research | Charge transfer | Heterocyclic compounds | Analysis | Excited state chemistry
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12. QP Partitioning for Radiationless Transitions
by Lavigne, Cyrille
03/2014
This work presents a new implementation of the QP algorithm, a computer method to diagonalize the extremely large matrices arising in multimode vibronic... 
pyrazine | vibronic | coherent control | benzene radical cation | Wavepacket | Radiationless | matrix diagonalization | 0494 | overlapping resonances | Intramolecular | conical intersection
Dissertation
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13. Full Text Spectroscopic properties and electronic structures of 17-electron half-sandwich ruthenium acetylide complexes, [Ru(CCAr)(L2)Cp']+ (Ar = phenyl, p-tolyl, 1-naphthyl, 9-anthryl; L2 = (PPh3)2, Cp'= Cp; L2 = dppe; Cp' = Cp)
by Fox, M.A and Roberts, R.L and Khairul, W.M and Hartl, F and Low, P.J
Journal of Organometallic Chemistry, ISSN 0022-328X, 2007, Volume 692, Issue 15, pp. 3277 - 3290
A series of half-sandwich bis(phosphine) ruthenium acetylide complexes [Ru(C{triple bond, long}CAr)(L )Cp′] (Ar = phenyl, p-tolyl, 1-naphthyl, 9-anthryl; L =... 
Acetylide | Radical cation | Ruthenium | Spectroelectrochemistry | TD DFT
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14. Full Text Multifunctional pi-expanded oligothiophene macrocycles
by Iyoda, M and Shimizu, H
CHEMICAL SOCIETY REVIEWS, ISSN 0306-0012, 2015, Volume 44, Issue 18, pp. 6411 - 6424
This tutorial review summarizes recent progress in the design, synthesis, and multifunctional properties of fully conjugated macrocyclic pi-systems. We focus... 
ACETYLENES | BUCKMINSTERFULLERENE | CONJUGATED MACROCYCLES | CYCLOPARAPHENYLENE RADICAL-CATION | ELIMINATION | PHOTOPHYSICAL PROPERTIES | THIOPHENE | COMPLEXATION | CHEMISTRY, MULTIDISCIPLINARY | CARBON NANOTUBES | GIANT
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15. Full Text Synthesis and Physical Properties of Polyfluorinated Cycloparaphenylenes
by Hashimoto, Sigma and Kayahara, Eiichi and Mizuhata, Yoshiyuki and Tokitoh, Norihiro and Takeuchi, Katsuhiko and Ozawa, Fumiyuki and Yamago, Shigeru
Organic Letters, ISSN 1523-7060, 09/2018, Volume 20, Issue 18, pp. 5973 - 5976
Fluorinated [6]- and [9]­cycloparaphenylene (CPP) derivatives, 8F-[6]­CPP and 12F-[9]­CPP, were synthesized based on the previous synthesis of the parent CPPs.... 
BEARING 3 | SIZE DEPENDENCE | RADICAL-CATION | DONOR | N=5 | CHEMISTRY, ORGANIC | N=8-13 | DICATIONS
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16. Full Text An Unexpected Construction of 2-Arylquinolines from N-Cinnamylanilines through sp3 Ci-H Aerobic Oxidation Induced by a Catalytic Radical Cation Salt
by Liu, Fang and Yu, Liangliang and Lv, Shiwei and Yao, Junjun and Liu, Jing and Jia, Xiaodong
Advanced Synthesis and Catalysis, ISSN 1615-4150, 02/2016, Volume 358, Issue 3, pp. 459 - 465
radical cation salts | 2-arylquinolines | N-cinnamylaniline | aerobic oxidation
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17. Full Text Construction of quinoline-fused lactones and 2,3-disubstituted quinolines via catalytic aerobic sp3C-H oxidation: Application of fragment-reassembly strategy
by Ma, Xingge and Zhu, Yingzu and Lü, Shiwei and Zhang, Liang and Luo, Liangliang and Jia, Xiaodong
Tetrahedron Letters, ISSN 0040-4039, 2016, Volume 57, Issue 14, pp. 1528 - 1531
Designed by fragment-reassembly strategy, the reaction between glycine esters and cyclic enol ethers was achieved in the catalysis of TBPA /O , yielding a... 
C-H oxidation | Heterocycles | Radical cation salt | Quinoline | Lactone
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18. Full Text Halogen bonding: A powerful, emerging tool for constructing high-dimensional metal-containing supramolecular networks
by Li, Bo and Zang, Shuang-Quan and Wang, Li-Ya and Mak, Thomas C.W
Coordination Chemistry Reviews, ISSN 0010-8545, 02/2016, Volume 308, pp. 1 - 21
Halogen bonding (XB), an attractive and valuable noncovalent interaction, has recently been exploited as an important tool in crystal engineering. The recent... 
Supramolecular networks | Crystal engineering | Halogen bonding | High dimensionality | Metal-containing complexes | SPIN-CROSSOVER | RADICAL-CATION SALTS | CRYSTAL-STRUCTURE | BONDED ORGANIC FRAMEWORK | HYDROGEN-BONDS | CHEMISTRY, INORGANIC & NUCLEAR | MOLECULAR HOST FRAMEWORKS | PI INTERACTIONS | MAGNETIC-PROPERTIES | ANION RECOGNITION | COORDINATION POLYMERS
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19. Full Text Intense Chiroptical Switching in a Dicationic Helicene-Like Derivative: Exploration of a Viologen-Type Redox Manifold of a Non-Racemic Helquat
by Pospíšil, Lubomír and Bednárová, Lucie and Štěpánek, Petr and Slavíček, Petr and Vávra, Jan and Hromadová, Magdaléna and Dlouhá, Helena and Tarábek, Ján and Teplý, Filip
Journal of the American Chemical Society, ISSN 0002-7863, 08/2014, Volume 136, Issue 31, pp. 10826 - 10829
Two-step redox switching in enantiopure helquat system [P-1]2+ ⇌ [P-1]•+ ⇌ [P-1]0 is demonstrated. The viologen-type electroactive unit embedded directly in... 
ASYMMETRIC-SYNTHESIS | RADICAL-CATION | BEHAVIOR | ENHANCEMENT | OPTICAL-PROPERTIES | CHIRALITY | FACILE | CHEMISTRY, MULTIDISCIPLINARY | MOLECULES | Redox potential | Enantiomers | Analysis | Chirality
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20. Full Text [3+2] Photooxygenation of aryl cylopropanes via visible light photocatalysis
by Lu, Zhan and Parrish, Jonathan D and Yoon, Tehshik P
Tetrahedron, ISSN 0040-4020, 07/2014, Volume 70, Issue 27-28, pp. 4270 - 4278
We report that Ru(bpz) is an excellent sensitizer for the photooxygenation of aryl cyclopropanes upon irradiation with visible light. The effectiveness of this... 
Endoperoxide | Cyclopropanes | Radical cation | Photooxygenation | Photocatalysis
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