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Accounts of Chemical Research, ISSN 0001-4842, 02/2015, Volume 48, Issue 2, pp. 256 - 266
Conspectus Carbenes are compounds that feature a divalent carbon atom with only six electrons in its valence shell. In the singlet state, they possess a lone... 
CRYSTALLINE CARBENE | TRANSITION-METAL-COMPLEXES | INTRAMOLECULAR HYDROIMINIUMATION | RADICAL-CATION | ALKYL AMINO CARBENES | N-HETEROCYCLIC CARBENES | SINGLET CARBENES | CATALYTIC-ACTIVITY | LIGAND PROPERTIES | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Nature Communications, ISSN 2041-1723, 08/2015, Volume 6, Issue 1, p. 7818
Electrochemical double-layer capacitors exhibit high power and long cycle life but have low specific energy compared with batteries, limiting applications.... 
STORAGE | CARBON ELECTRODES | REDUCTION | BROMINE | METHYL VIOLOGEN | PERFORMANCE | MULTIDISCIPLINARY SCIENCES | RADICAL CATION | GRAPHENE | SUPERCAPACITOR | ACTIVE ELECTROLYTE
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 2017, Volume 23, Issue 53, pp. 12980 - 12984
We report a consecutive C-H functionalization that constructs 3,4-dihydroquinoline-3-one derivatives in high yields. This reaction is triggered by oxidation of... 
C−H functionalization | quaternary center | 3,4-dihydroquinoline-3-one | aerobic oxidation | radical cation
Journal Article
Chemical Communications, ISSN 1359-7345, 7/2013, Volume 49, Issue 63, pp. 725 - 727
Tetrathiafulvalene (TTF) is among the most versatile and well-known molecules which exhibits outstanding redox properties and a remarkable electron donor... 
RADICAL-CATION | TTF | CHEMISTRY | SYSTEMS | NLO PROPERTIES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Reviews, ISSN 0009-2665, 05/2018, Volume 118, Issue 9, pp. 4702 - 4730
Electrochemistry serves as a powerful method for generating reactive intermediates, such as organic cations. In general, there are two ways to use reactive... 
CARBON BOND FORMATION | RADICAL-CATION | ONE-STEP PREPARATION | DIARYLCARBENIUM ION POOLS | AROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | C-H AMINATION | ASSISTED SEQUENTIAL INTRODUCTION | ELECTROCHEMICAL OXIDATION | ENOL SILYL ETHERS | ANODIC-OXIDATION
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 03/2016, Volume 45, Issue 6, pp. 1720 - 1737
Molecular containers have attracted the interest of supramolecular chemists since the early beginnings of the field. Cavitands' inner cavities were quickly... 
O-BENZYNE | ASSEMBLED COORDINATION CAGE | INNER PHASE | CAPSULE | RADICAL-CATION STABILIZATION | HOST | N-OXIDES | CHEMISTRY, MULTIDISCIPLINARY | ROOM-TEMPERATURE STABILIZATION | MOLECULAR CONTAINERS | CARBOXYLIC-ACIDS
Journal Article
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, ISSN 0009-2673, 11/2019, Volume 92, Issue 11, pp. 1902 - 1909
We have designed and synthesized three kinds of diisopro-pylaminoboranes substituted with two electron-donating pi-conjugated systems, 2a: bis(phenothiazinyl)... 
Main group elements | Radical cation | Trimethylenemethane | RADICALS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
NATURE COMMUNICATIONS, ISSN 2041-1723, 05/2014, Volume 5
So far, no effect of chirality on the electrical properties of bulk chiral conductors has been observed. Introduction of chiral information in... 
TRANSPORT | COMPLETE SERIES | TETRATHIAFULVALENE | METALS | RADICAL-CATION SALTS | DICHROISM | BEHAVIOR | MULTIDISCIPLINARY SCIENCES | TTF | ORGANIC CONDUCTORS | CRYSTAL
Journal Article
Chemical Communications, ISSN 1359-7345, 10/2011, Volume 47, Issue 38, pp. 10755 - 10757
The creation of novel crown ether-paraquat polypseudorotaxane networks, constructed by bisparaquat monomers threading into the cavity of the crown ether units... 
MONOMERS | POLYMERIZATIONS | ORTHOGONAL BINDING INTERACTIONS | RADICAL-CATION | CYCLODEXTRIN | STABILIZATION | CONSTRUCTION | POLYROTAXANE | DRIVEN | CHEMISTRY, MULTIDISCIPLINARY | ARCHITECTURES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 26, pp. 8509 - 8520
A tailored strategy is utilized to modify 5,10-dimethylphenazine (DMP) to donor–acceptor type N,N′-disubstituted-dihydrodibenzo­[a,c]­phenazines. The... 
SUBSTITUTED RADICAL-CATION | FLUORESCENCE | LUMINESCENCE | ISOMERIZATION | LARGE STOKES SHIFT | PHOTOPHYSICS | SYSTEMS | MODEL | CHEMISTRY, MULTIDISCIPLINARY | GEOMETRY | Chemical properties | Research | Charge transfer | Heterocyclic compounds | Analysis | Excited state chemistry
Journal Article
03/2014
This work presents a new implementation of the QP algorithm, a computer method to diagonalize the extremely large matrices arising in multimode vibronic... 
pyrazine | vibronic | coherent control | benzene radical cation | Wavepacket | Radiationless | matrix diagonalization | 0494 | overlapping resonances | Intramolecular | conical intersection
Dissertation
Journal of Organometallic Chemistry, ISSN 0022-328X, 2007, Volume 692, Issue 15, pp. 3277 - 3290
A series of half-sandwich bis(phosphine) ruthenium acetylide complexes [Ru(C{triple bond, long}CAr)(L )Cp′] (Ar = phenyl, p-tolyl, 1-naphthyl, 9-anthryl; L =... 
Acetylide | Radical cation | Ruthenium | Spectroelectrochemistry | TD DFT
Journal Article
CHEMICAL SOCIETY REVIEWS, ISSN 0306-0012, 2015, Volume 44, Issue 18, pp. 6411 - 6424
This tutorial review summarizes recent progress in the design, synthesis, and multifunctional properties of fully conjugated macrocyclic pi-systems. We focus... 
ACETYLENES | BUCKMINSTERFULLERENE | CONJUGATED MACROCYCLES | CYCLOPARAPHENYLENE RADICAL-CATION | ELIMINATION | PHOTOPHYSICAL PROPERTIES | THIOPHENE | COMPLEXATION | CHEMISTRY, MULTIDISCIPLINARY | CARBON NANOTUBES | GIANT
Journal Article
Organic Letters, ISSN 1523-7060, 09/2018, Volume 20, Issue 18, pp. 5973 - 5976
Fluorinated [6]- and [9]­cycloparaphenylene (CPP) derivatives, 8F-[6]­CPP and 12F-[9]­CPP, were synthesized based on the previous synthesis of the parent CPPs.... 
BEARING 3 | SIZE DEPENDENCE | RADICAL-CATION | DONOR | N=5 | CHEMISTRY, ORGANIC | N=8-13 | DICATIONS
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2016, Volume 57, Issue 14, pp. 1528 - 1531
Designed by fragment-reassembly strategy, the reaction between glycine esters and cyclic enol ethers was achieved in the catalysis of TBPA /O , yielding a... 
C-H oxidation | Heterocycles | Radical cation salt | Quinoline | Lactone
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 02/2016, Volume 308, pp. 1 - 21
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2014, Volume 136, Issue 31, pp. 10826 - 10829
Two-step redox switching in enantiopure helquat system [P-1]2+ ⇌ [P-1]•+ ⇌ [P-1]0 is demonstrated. The viologen-type electroactive unit embedded directly in... 
ASYMMETRIC-SYNTHESIS | RADICAL-CATION | BEHAVIOR | ENHANCEMENT | OPTICAL-PROPERTIES | CHIRALITY | FACILE | CHEMISTRY, MULTIDISCIPLINARY | MOLECULES | Redox potential | Enantiomers | Analysis | Chirality
Journal Article
Tetrahedron, ISSN 0040-4020, 07/2014, Volume 70, Issue 27-28, pp. 4270 - 4278
We report that Ru(bpz) is an excellent sensitizer for the photooxygenation of aryl cyclopropanes upon irradiation with visible light. The effectiveness of this... 
Endoperoxide | Cyclopropanes | Radical cation | Photooxygenation | Photocatalysis
Journal Article
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