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CHEMICAL SOCIETY REVIEWS, ISSN 0306-0012, 2016, Volume 45, Issue 19, pp. 5296 - 5310
This review serves as a brief introduction to phospholes and discusses their unique favorable properties for application in organic electronic materials. Over... 
LIGHT-EMITTING-DIODES | SENSITIZED SOLAR-CELLS | ELECTROLUMINESCENT DEVICES | POLYCYCLIC AROMATIC-HYDROCARBONS | ORGANOPHOSPHORUS DOPANTS | ELECTRICAL-CONDUCTIVITY | OPTICAL-PROPERTIES | REDUCED PYRAMIDAL CHARACTER | CHEMISTRY, MULTIDISCIPLINARY | ORGANIC PHOTOVOLTAICS | CATHODE BUFFER LAYERS | Devices | Electronic materials | Synthesis
Journal Article
Letters in Organic Chemistry, ISSN 1570-1786, 09/2015, Volume 12, Issue 8, pp. 549 - 559
A new aromaticity index is proposed based on the energy of pi orbitals D = {[pi(1)+Sigma(n)(2)(pi(1)-pi(n))](0)/[pi(1)+Sigma(n)(2)(pi(1)-pi(n))]} x a, where n... 
HOMA | Quantification of the aromatic character | ASE | DFT | Aromaticity | quantification of the aromatic character | CHEMISTRY, ORGANIC | REDUCED PYRAMIDAL CHARACTER | PHOSPHOLES | ELECTRON DELOCALIZATION
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2015, Volume 21, Issue 32, pp. 11545 - 11559
2,5‐Diferrocenyl‐1‐Ar‐1H‐phospholes 3 a–e (Ar=phenyl (a), ferrocenyl (b), mesityl (c), 2,4,6‐triphenylphenyl (d), and 2,4,6‐tri‐tert‐butylphenyl (e)) have been... 
structure elucidation | electrochemistry | electron transfer | heterocycles | phospholes | COMPLEXES | DELOCALIZATION | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | TRICOORDINATE PHOSPHORUS | AROMATICITY | NMR | DELTA-E-1/2 VALUES | REDUCED PYRAMIDAL CHARACTER | COMMUNICATION | Flattening | Aromaticity | Inversions | Electronics | Phosphorus | Activation | Cations | Three dimensional
Journal Article
Catalysis Science and Technology, ISSN 2044-4753, 8/2015, Volume 5, Issue 9, pp. 4289 - 4323
This review provides an overview of phosphole-based ligand families (monophospholes, multidentate hybrid phosphole ligands, diphospholes and... 
COORDINATION CHEMISTRY | TRANSITION-METAL-COMPLEXES | ASYMMETRIC HYDROFORMYLATION | RHODIUM-COMPLEXES | ONE-POT SYNTHESIS | RAY-CRYSTAL-STRUCTURE | X-RAY | CHEMISTRY, PHYSICAL | REDUCED PYRAMIDAL CHARACTER | TRANSFER HYDROGENATION | PI-CONJUGATED SYSTEMS | Chemical Sciences | Coordination chemistry
Journal Article
Mendeleev Communications, ISSN 0959-9436, 05/2013, Volume 23, Issue 3, pp. 117 - 130
Journal Article
Current Organic Chemistry, ISSN 1385-2728, 09/2004, Volume 8, Issue 13, pp. 1245 - 1261
beta-Oxophosphoranes/ylides. versatile intermediates in synthetic organic chemistry can be prepared by the novel reaction of P-aryl cyclic phosphine oxides,... 
ARYLPHOSPHINE OXIDES | ACETYLENIC ESTERS | FLASH VACUUM PYROLYSIS | RAY CRYSTALLOGRAPHIC ANALYSIS | CHEMISTRY, ORGANIC | REDUCED PYRAMIDAL CHARACTER | 2+2 CYCLOADDITION | 2,4,6-TRIALKYLPHENYLPHOSPHINE OXIDES | INVERSE WITTIG REACTION | 5-MEMBERED PHOSPHORUS-HETEROCYCLES | DIMETHYL ACETYLENEDICARBOXYLATE
Journal Article
Current Organic Chemistry, ISSN 1385-2728, 01/2006, Volume 10, Issue 1, pp. 43 - 78
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2002, Volume 67, Issue 4, pp. 1208 - 1213
Journal Article
Organometallics, ISSN 0276-7333, 03/2001, Volume 20, Issue 5, pp. 1014 - 1019
A novel chiral and enantiomerically pure phosphole with two (−)-menthyl groups at the 2- and 5-positions of the phosphole ring is prepared in two steps,... 
AROMATICITY | TRANSITION-METAL COMPLEXES | HETEROCYCLES | LIGANDS | DIPHOSPHINES | CHEMISTRY | CHEMISTRY, ORGANIC | REDUCED PYRAMIDAL CHARACTER | 1-(2,4-DI-TERT-BUTYL-6-METHYLPHENYL)-3-METHYLPHOSPHOLE | PHOSPHAFERROCENES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Tetrahedron, ISSN 0040-4020, 2002, Volume 58, Issue 49, pp. 9801 - 9808
Diels–Alder reaction of the title phospholes and N-phenylmaleimide afforded, surprisingly, a mixture of endo and exo fused cycloadducts with the P-aryl... 
stereochemistry | Diels–Alder reactions | theoretical studies | phospholes | Diels-Alder reactions | Stereochemistry | Phospholes | Theoretical studies | NMR | CHEMISTRY, ORGANIC | REDUCED PYRAMIDAL CHARACTER
Journal Article
Journal of Molecular Catalysis. A, Chemical, ISSN 1381-1169, 2003, Volume 200, Issue 1, pp. 131 - 136
P-arylphospholes of high aromaticity were used in rhodium-catalysed hydroformylation. The results obtained by the systematic variation of the aryl substituent... 
Aromaticity | Arylphospholes | Rhodium-complexes | DFT calculations | Hydroformylation | rhodium-complexes | RHODIUM SYSTEMS | ASYMMETRIC HYDROFORMYLATION | COMPLEXES | CHEMISTRY, PHYSICAL | PHOSPHOLES | NMR | LIGANDS | REDUCED PYRAMIDAL CHARACTER | hydroformylation | arylphospholes | ENANTIOSELECTIVE HYDROFORMYLATION | aromaticity
Journal Article
Tetrahedron, ISSN 0040-4020, 01/2000, Volume 56, Issue 1, pp. 79 - 84
Tricoordinate phosphorus can be planarized, and used as an excellent building block of aromatic compounds. The pyramidality can be reduced by (i) σ donor and π... 
Tricoordinate phosphorus | Aromaticity | Cyclic compounds | PI-DONATION | HETEROCYCLES | DOUBLE-BONDS | RING | CHEMISTRY | CHEMISTRY, ORGANIC | REDUCED PYRAMIDAL CHARACTER | 1-(2,4-DI-TERT-BUTYL-6-METHYLPHENYL)-3-METHYLPHOSPHOLE | DIBORYLPHOSPHINE | PHOSPHINOCARBENE | INVERSION BARRIERS | Nitrogen | Aromatic compounds
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2002, Volume 643, pp. 32 - 38
The reaction of 1-(tri- tert-butylphenyl)phosphole ( 1) with phosphorus tribromide gave the 3-dibromophosphino intermediate ( 2) selectively that was useful in... 
Phosphorylation | Selectivity | Arylphospholes | Hydroformylation | selectivity | NMR | C-PHOSPHORYLATION | CHEMISTRY, ORGANIC | REDUCED PYRAMIDAL CHARACTER | hydroformylation | arylphospholes | phosphorylation | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Heteroatom Chemistry, ISSN 1042-7163, 2005, Volume 16, Issue 2, pp. 104 - 110
A further member of 2,4,6‐trialkyl‐phenyl‐phos‐pholes, the ditertbutylmethylphenyl derivative (1c) was characterized by Bird index and by the sum of angles at... 
NMR | 2H-PHOSPHOLES | CHEMISTRY | REDUCED PYRAMIDAL CHARACTER | CRYSTAL | PHOSPHOLES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the Chemical Society, Perkin Transactions 1, ISSN 1470-4358, 2000, Issue 17, pp. 2895 - 2897
Two (trialkylphenyl)phospholes (1 and 4) with significant heteroaromatic character due to the flattened P-pyramid underwent Friedel-Crafts acylation with acyl... 
CHEMISTRY, ORGANIC | REDUCED PYRAMIDAL CHARACTER | NMR | PHOSPHOLES
Journal Article
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, ISSN 1434-193X, 12/2012, Volume 2012, Issue 34, pp. 6711 - 6721
Novel bis(azidophenyl)phosphole sulfide building block 8 has been developed to give access to a plethora of phosphole-containing p-conjugated systems in a... 
Phospholes | COMPLEXES | Fluorescence | CHEMISTRY, ORGANIC | X-RAY-DIFFRACTION | RISE | Molecular electronics | NMR | LIGANDS | METALLACYCLE TRANSFER | CHEMISTRY | REDUCED PYRAMIDAL CHARACTER | Conjugation | Click chemistry | PHOSPHOLE | DERIVATIVES
Journal Article
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