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Angewandte Chemie International Edition, ISSN 1433-7851, 10/2013, Volume 52, Issue 43, pp. 11303 - 11307
Aldehyde Termination: A novel copper‐catalyzed transformation from methyl ketones into aldehydes has been accomplished. This method is applicable to a wide... 
copper | aldehydes | ketones | oxygen | cleavage reactions | C-C-BOND | ACTIVATION | DIOXYGEN | LEWIS-ACID | TRIPLE BOND | CARBON-CARBON BONDS | CHEMISTRY, MULTIDISCIPLINARY | CYANO BONDS | REDUCTIVE CLEAVAGE | HOMOGENEOUS CATALYSIS | METAL-FREE | Ketones | Carbon dioxide | Byproducts | Cleavage | Transformations | Aldehydes | Aliphatic compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 21, pp. 6754 - 6757
A Ni-catalyzed ipso-borylation of aryl ethers via C­(sp2)–OMe and C­(sp3)–OMe cleavage is described. The transformation is characterized by its wide substrate... 
HALIDES | CROSS-COUPLING REACTIONS | ACTIVATION | REAGENTS | O BOND | REDUCTIVE CLEAVAGE | METHYL ETHERS | BORONIC ESTERS | METAL | LIGAND | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2017, Volume 56, Issue 8, pp. 2110 - 2114
Metallic palladium surfaces are highly selective in promoting the reductive hydrolysis of aromatic ethers in aqueous phase at relatively mild temperatures and... 
reductive hydrolysis | palladium | selective cleavage | hydrogenation | aryl ethers | HYDROGENOLYSIS | DEPOLYMERIZATION | LIGNIN MODEL COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | CHEMICALS | BIOMASS | CHEMISTRY | FUELS | WATER | Hydrolysis | Palladium | Hydrogenation | Analysis | Cyclohexanone | Beryllium | Phenols | Selectivity | Ethers | Aliphatic compounds
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 12/2014, Volume 43, Issue 23, pp. 8081 - 8097
In 1979, the seminal work of Wenkert set the standards for the utilization of aryl and vinyl ethers as coupling partners via C-O bond-cleavage. Although the... 
ORGANOBORON COMPOUNDS | ARYL GRIGNARD-REAGENTS | ORGANIC-SYNTHESIS | CROSS-COUPLING REACTIONS | CARBON-OXYGEN BONDS | REDUCTIVE CLEAVAGE | METHYL ETHERS | N-HETEROCYCLIC CARBENES | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | PHENOL DERIVATIVES
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 10/2014, Volume 12, Issue 38, pp. 7433 - 7444
RANEY® cobalt, which was first prepared in the 1930s, is known to function effectively as a catalyst for certain chemoselective reductions. However, its... 
Journal Article
by Yang, L and Zhang, JY and Duan, XH and Gao, P and Jiao, J and Guo, LN
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 07/2019, Volume 84, Issue 13, pp. 8615 - 8629
The efficient copper-catalyzed cyanoalkylation of amines via C-C bond cleavage has been demonstrated. Distinctive features of this procedure involves mild... 
TRANSFORMATION | H CYANOALKYLATION | PHOTOREDOX | CYCLOBUTANONE O-BENZOYLOXIMES | CHEMISTRY | SECONDARY | CHEMISTRY, ORGANIC | RADICALS | COUPLINGS | REDUCTIVE AMINATION | ALKYL-HALIDES
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 05/2012, Volume 2012, Issue 14, pp. 2683 - 2706
The activation and cleavage of C–C single bonds mediated by transition metal complexes is one of the most challenging reactions, both practically and in terms... 
Reaction mechanisms | Transition metal complexes | Single bond activation | Agostic interactions | Homogeneous catalysis | HETEROAROMATIC CARBOXYLIC-ACIDS | CROSS-COUPLING REACTION | CARBON-CARBON BOND | CHEMISTRY, ORGANIC | OXIDATIVE ADDITION | REDUCTIVE ELIMINATION | BETA-METHYL ELIMINATION | RAY CRYSTAL-STRUCTURE | HOMOALLYL ALCOHOLS | RETRO-ALLYLATION
Journal Article