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Chemical Science, ISSN 2041-6520, 06/2015, Volume 6, Issue 10, pp. 5802 - 5814
The ability to establish switchable site-selectivity through catalyst control in the direct functionalization of molecules that contain distinct C-H bonds... 
ONE-POT SYNTHESIS | REGIOSELECTIVE SYNTHESIS | EFFICIENT SYNTHESIS | N BOND | (ELECTRON-DEFICIENT ETA-CYCLOPENTADIENYL)RHODIUM(III) CATALYST | RH(III)-CATALYZED OXIDATIVE ANNULATION | SITE-SELECTIVE SP | INTERNAL ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | ORTHO-ALKENYLATION | RHODIUM CATALYSIS
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 02/2016, Volume 138, Issue 7, pp. 2327 - 2341
Dirhodium-catalyzed C-H amination is hypothesized to proceed via Rh-2-nitrene intermediates in either the Rh-2(II,II) or Rh-2(II,III) redox state. Herein, we... 
CHEMOSELECTIVE AMINATION | C(SP)-H BONDS | MANGANESE-PORPHYRINS | INTERMOLECULAR AMINATION | TRANSITION-METAL-COMPLEXES | SPIN-RESONANCE | CORRELATION-ENERGY | BASIS-SETS | CHEMISTRY, MULTIDISCIPLINARY | C-H AMINATION | RH-RH BOND
Journal Article
Organic Letters, ISSN 1523-7060, 05/2012, Volume 14, Issue 10, pp. 2520 - 2523
A novel water-soluble Au(III)-NHC complex has been synthesized and successfully applied in the intramolecular cyclization of γ-alkynoic acids into... 
GOLD(III) COMPLEXES | INTRAMOLECULAR CYCLIZATION | RH/M-TPPTC CATALYST | TRISUBSTITUTED ALKENES | ORGANIC-REACTIONS | HOMOGENEOUS GOLD CATALYSIS | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | N-HETEROCYCLIC CARBENES | ACETYLENIC CARBOXYLIC-ACIDS | SELECTIVE CYCLOISOMERIZATION
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 11/2017, Volume 50, Issue 11, pp. 2799 - 2808
Conspectus Transition-metal-catalyzed cross-coupling has emerged as an effective strategy for chemical synthesis. Within this area, direct C–H bond... 
DENSITY | QUINOLINE N-OXIDES | RH(III) CATALYST | ACTIVATION | AMINATION | NITROGEN-SOURCE | DUAL ROLE | BOND-CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | ATOM TRANSFER
Journal Article
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, ISSN 2168-0485, 01/2019, Volume 7, Issue 2, pp. 2648 - 2657
The development of supramolecular photocatalysts has been an important target in the field of artificial photosynthesis because of their efficient reduction of... 
FORMIC-ACID | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | STORAGE MATERIAL | ELECTRON | RHODIUM | UV-vis absorption | Rh complex | RUTHENIUM | CHEMISTRY, MULTIDISCIPLINARY | Supramolecular photocatalyst | HIGHLY EFFICIENT | HYDRIDE | ENGINEERING, CHEMICAL | HYDROGEN | Electrochemical measurements | IRIDIUM COMPLEXES | CARBON-DIOXIDE REDUCTION | CO2 reduction
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 08/2015, Volume 54, Issue 35, pp. 10280 - 10283
The first Cp* Rh-III-catalyzed arylation of unactivated C(sp(3))-H bonds is presented. The unactivated primary C(sp(3))-H bond of 2-alkylpyridines can be... 
ACTIVATION | H BOND | INTERMOLECULAR AMIDATION | N BOND | CARBON-HYDROGEN BONDS | CHEMISTRY, MULTIDISCIPLINARY | arylation | triarylmethanes | boroxines | FUNCTIONALIZATION | RH(III) CATALYST | CROSS-COUPLING REACTIONS | ARYL BORONIC ACIDS | C(sp)-H activation | Rh-III catalysis | DUAL ROLE
Journal Article
Catalysis Communications, ISSN 1566-7367, 08/2019, Volume 128, p. 105701
Rh(III)-catalyzed oxidative cross-coupling of C(sp ) H bonds with C(sp ) H bonds has been accomplished under mild conditions. This method furnishes a... 
Quinones | Rh(III) catalyst | C(sp3)[sbnd]H functionalization | Thiophenes | 8-Methylquinolines | FUNCTIONALIZATION | C-H BOND | C(sp)-H functionalization | INTERMOLECULAR AMIDATION | CHEMISTRY, PHYSICAL
Journal Article
ACS Catalysis, ISSN 2155-5435, 03/2016, Volume 6, Issue 3, pp. 1971 - 1980
C–H activation under redox-neutral conditions, especially by Rh­(III) catalysis, has offered attractive synthetic strategies. Previous work in redox-neutral... 
C-H bond activation | isoindole | olefin | Rh(III) catalyst | N-sulfinyl imine | N-S bond cleavage | DIRECTING GROUP | RHODIUM-CATALYZED SYNTHESIS | ONE-POT SYNTHESIS | EFFICIENT SYNTHESIS | CHEMISTRY, PHYSICAL | OXYGEN-ATOM TRANSFER | INTERNAL OXIDANT | SUBSTITUTED PYRIDINE-DERIVATIVES | SULFONIC-ACID GROUP | REGIOSELECTIVE SYNTHESIS | INDOLE SYNTHESIS
Journal Article
ACS Sustainable Chemistry and Engineering, 01/2019, Volume 7, Issue 2, pp. 2648 - 2657
Journal Article
ACS Catalysis, ISSN 2155-5435, 10/2018, Volume 8, Issue 10, pp. 9508 - 9519
By virtue of a synergistically dual-directing-group (the O–NHAc part and the hydroxyl group)-assisted strategy, the efficient and practical Rh­(III)-catalyzed... 
chalcones | experimental and computational studies | Rh(III) catalyst | propargyl alcohols | benzofurans | N-phenoxyacetamides | ROOM-TEMPERATURE | AMINO-ACID SYNTHESIS | ANNULATION | CHEMISTRY, PHYSICAL | ALKYNES | ALKENES | BENZAMIDES | BOND ACTIVATION | CATALYZED DIRECT ARYLATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2018, Volume 57, Issue 27, pp. 8255 - 8259
Journal Article
Asian Journal of Organic Chemistry, ISSN 2193-5807, 07/2018, Volume 7, Issue 7, pp. 1338 - 1342
Maleimides are not known to undergo oxidative-Heck reaction because they lack a syn-periplanar beta-hydrogen atom. Herein, we report a C-H activation-based... 
oxidative Heck reaction | Synthetic methods | directing group | Catalyst | maleimides | DESIGN | ARYLATION | CHEMISTRY, ORGANIC | ALKYNES | SALTS | FREE-RADICALS | POTENT | BIOLOGICAL EVALUATION | INHIBITORS | ANHYDRIDES | Rh-III-Catalyst | UNSATURATED SYSTEMS
Journal Article
JOURNAL OF PHYSICAL CHEMISTRY A, ISSN 1089-5639, 11/2016, Volume 120, Issue 46, pp. 9151 - 9158
The mechanism of redox-neutral Rh(III)-catalyzed coupling reactions of arylnitrones with alkynes was investigated by density functional theory (DFT)... 
FUNCTIONALIZATION | QUINOLINE N-OXIDES | RH(III) CATALYST | DFT | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | INDOLINES | CHEMISTRY, PHYSICAL | BOND ACTIVATION | COMBINATION | INSIGHT | CYCLIZATION | ATOM TRANSFER
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 06/2016, Volume 52, Issue 50, pp. 7870 - 7873
The dual character of benzoquinone is exploited for the synthesis of benzo[a]carbazole derivatives starting from 3-ethylindole derivatives. A diene is... 
Journal Article
RSC Advances, ISSN 2046-2069, 04/2015, Volume 5, Issue 41, pp. 32826 - 32834
A variety of cesium supported catalysts with amorphous SiO 2 as a carrier were prepared by vacuum impregnation and ultrasonic impregnation methods, which were... 
SELECTIVE OXIDATION | RH(III) CATALYSTS | TO-TAIL DIMERIZATION | SURFACE-AREA | OXIDE CATALYST | ZEOLITE CATALYSTS | PROPIONIC-ACID | PROPANE OXIDATION | ACETIC-ACID | CHEMISTRY, MULTIDISCIPLINARY | METHACRYLIC-ACID SYNTHESIS
Journal Article
by Wang, P and Wang, DL and Liu, H and Zhao, XL and Lu, Y and Liu, Y
ORGANOMETALLICS, ISSN 0276-7333, 07/2017, Volume 36, Issue 13, pp. 2404 - 2411
A novel three-step tandem hydroformylation-acetalization-hydrogenolysis was first proposed to produce alcohols (derivatives) from olefins, and the developed... 
KETONES | RHODIUM | LIGANDS | INTERNAL ALKENES | RUTHENIUM COMPLEXES | HYDROLYSIS | CHEMISTRY, ORGANIC | RH/RU DUAL CATALYST | TRANSFER HYDROGENATION | ALDEHYDES | EFFICIENT | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical Communications, ISSN 1359-7345, 2016, Volume 52, Issue 50, pp. 7870 - 7873
The dual character of benzoquinone is exploited for the synthesis of benzo[a]carbazole derivatives starting from 3-ethylindole derivatives. A diene is... 
RH(III) CATALYST | DESIGN | PYRAZOLE ANALOGS | DIELS-ALDER REACTION | BIOLOGICAL EVALUATION | INHIBITORS | PROTEINS | ARYNES | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | Diels-Alder reactions | Benzoquinone | Synthesis | Derivatives | Dienes | Oxidizing agents
Journal Article
by Xie, PP and Guo, W and Chen, DM and Xia, YZ
CATALYSIS SCIENCE & TECHNOLOGY, ISSN 2044-4753, 08/2018, Volume 8, Issue 16, pp. 4005 - 4009
Journal Article
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