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rhodium-catalyzed cyanation (13) 13
chemistry, organic (12) 12
phenyl-p-toluenesulfonamide (6) 6
catalysis (5) 5
chemistry, multidisciplinary (5) 5
nitriles (5) 5
activation (4) 4
aryl (4) 4
cyanation (4) 4
functionalization (4) 4
alkynes (3) 3
arenes (3) 3
aromatic compounds (3) 3
c-h activation (3) 3
chemistry (3) 3
cyanamides (3) 3
cyclisation (3) 3
cyclization (3) 3
indoles (3) 3
katalyse (3) 3
allylation (2) 2
aryl halides (2) 2
aryl iodides (2) 2
arylation (2) 2
bonding (2) 2
c-h bonds (2) 2
chemistry, applied (2) 2
cobalt (2) 2
copper (2) 2
coupling reactions (2) 2
cyanamide (2) 2
cycloaddition (2) 2
c−h activation (2) 2
derivatives (2) 2
electrophilic cyanation (2) 2
index medicus (2) 2
indole (2) 2
kupfer (2) 2
one-pot synthesis (2) 2
organic chemistry (2) 2
pyrrol (2) 2
pyrrole (2) 2
reaction-mechanism (2) 2
reaktionsmechanismus (2) 2
review (2) 2
rhodium (2) 2
sodium-cyanide (2) 2
synthesis (2) 2
terminal alkynes (2) 2
tertiary-amines (2) 2
thiophen (2) 2
thiophene (2) 2
1,2,3-triazole (1) 1
1,2,3-triazoles (1) 1
1,4-addition/enantioselective protonation (1) 1
2+2+2 cycloaddition (1) 1
2,2′-azobisisobutyronitrile (1) 1
2-azobisisobutyronitrile (1) 1
acetates (1) 1
acid esters (1) 1
aliphatic amides (1) 1
aliphatic compounds (1) 1
alkene (1) 1
alkenes (1) 1
alkine (1) 1
allyl compounds (1) 1
allylic carbonates (1) 1
allylic compounds (1) 1
alpha,beta-unsaturated carbonyl-compounds (1) 1
alpha-aminonitriles (1) 1
alpha-cyanation (1) 1
alpha-cyano carboxylates (1) 1
amidation (1) 1
amino acid (1) 1
amino acids (1) 1
amino-acids (1) 1
aminocyanation (1) 1
aminohalogenation (1) 1
aminosäuren (1) 1
and cyano-group sources (1) 1
annulation (1) 1
aromatic imines (1) 1
asymmetric catalysis (1) 1
asymmetric hydrogenation (1) 1
atom transfer-reactions (1) 1
azavinyl carbenes (1) 1
azid (1) 1
azides (1) 1
azobisisobutyronitril (1) 1
azobisisobutyronitrile (1) 1
benzamid (1) 1
benzamide (1) 1
benzofuran (1) 1
benzonitriles (1) 1
benzothiophene (1) 1
benzyl cyanide (1) 1
beta-keto-esters (1) 1
bidentate ligands (1) 1
bisborane (1) 1
bisphosphonate (1) 1
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Chemistry – A European Journal, ISSN 0947-6539, 12/2016, Volume 22, Issue 50, pp. 17958 - 17961
The manganese‐catalyzed cyanation of inert C−H bonds was achieved within a heterobimetallic catalysis regime. The manganese(I) catalysis proved widely... 
cyanation | C−H activation | heterocycle | amino acid | manganese | ACTIVATION | CARBON-HYDROGEN BONDS | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | INDOLES | FUNCTIONALIZATION | C-H activation | RHODIUM-CATALYZED CYANATION | N-TYPE REACTIONS | AMINO-ACIDS | PHENYL-P-TOLUENESULFONAMIDE | Amino acids | Chemotherapy | Catalysis | Cancer | Manifolds | Carbon-carbon composites | Catalysts | Pyrroles | Chemical bonds | Activation
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 12/2014, Volume 136, Issue 51, pp. 17722 - 17725
The first cobalt-catalyzed cyanation, halogenation, and allylation via C-H activation have been realized. These formal S-N-type reactions generate valuable... 
MILD | DIRECT ARYLATION | RHODIUM-CATALYZED CYANATION | ROBUSTNESS SCREEN | AROMATIC IMINES | RAPID ASSESSMENT | ELECTRON-DEFICIENT ARENES | CARBON-CARBON BONDS | CHEMISTRY, MULTIDISCIPLINARY | DIRECT ALKYLATION | COBALT
Journal Article
Chemical Communications, ISSN 1359-7345, 08/2014, Volume 50, Issue 61, pp. 8412 - 8415
Copper-promoted N-cyanation of aliphatic sec-amine by CuCN is achieved via oxidative coupling. This procedure employs O-2 as a clean oxidant. Notably,... 
METAL-FREE SYNTHESIS | CUPRIC ACETATE | CROSS-COUPLING REACTIONS | SULFOXIMINES | RHODIUM-CATALYZED CYANATION | ARYL HALIDES | CYANAMIDES | TERMINAL ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | PHENYL-P-TOLUENESULFONAMIDE | Coupling | Oxidants | Bonding | Aliphatic compounds | Oxidizing agents
Journal Article
Chemical Communications, ISSN 1359-7345, 2019, Volume 55, Issue 9, pp. 1209 - 1212
A rhodium-catalyzed aromatic C-H bond direct cyanation with safe, bench-stable, and commercially available dimethylmalononitrile as the cyanating agent has... 
HALIDES | TRANSNITRILATION | CARBON | NITRILES | RHODIUM-CATALYZED CYANATION | ARENES | CHLORIDES | LITHIUM REAGENTS | BOND | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD
Journal Article
Asian Journal of Organic Chemistry, ISSN 2193-5807, 10/2019, Volume 8, Issue 10, pp. 1850 - 1853
Here an efficient and versatile method for cyanation using p‐toluenesulfonyl cyanide as a safe “CN” source under Rh(III)‐catalysis has been successfully... 
cyanation | indole | C−H activation | toluenesulfonyl cyanide | rhodium | ALLYLATION | AMIDATION | CHEMISTRY, ORGANIC | OXIDATIVE CYANATION | (HETERO)ARENES | INDOLES | C-H activation | RHODIUM-CATALYZED CYANATION | SODIUM-CYANIDE | BOND ACTIVATION | ARYL | DERIVATIVES
Journal Article
ACS Catalysis, ISSN 2155-5435, 09/2016, Volume 6, Issue 9, pp. 5989 - 6005
The cyano group is well known as a versatile intermediate for transformations into a multitude of useful functional groups such as carboxyl, carbamoyl,... 
and cyano-group sources | cyanation | benzonitriles | arenes | α-aminonitriles | TERTIARY-AMINES | CYANO SOURCE | CHEMISTRY, PHYSICAL | alpha-aminonitriles | DIRECT TRANSFORMATION | COUPLING REACTIONS | RHODIUM-CATALYZED CYANATION | SODIUM-CYANIDE | BENZYL CYANIDE | RECENT PROGRESS | DIRECT OXIDATIVE CYANATION | PHENYL-P-TOLUENESULFONAMIDE
Journal Article
by Wang, JY and Sun, B and Zhang, L and Xu, TW and Xie, YY and Jin, C
ORGANIC CHEMISTRY FRONTIERS, ISSN 2052-4129, 01/2020, Volume 7, Issue 1, pp. 113 - 118
A novel avenue of C-CN bond construction was facilely achieved via the TBHP-mediated oxidative coupling reaction between quinoxalin-2(1H)-one derivatives and... 
ELECTROPHILIC CYANATION | RHODIUM-CATALYZED CYANATION | TERTIARY-AMINES | H BOND CYANATION | COUPLING REACTION | ARYLATION | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | ARYL IODIDES | BETA-KETO-ESTERS | ALPHA-CYANATION
Journal Article
Organic Letters, ISSN 1523-7060, 02/2014, Volume 16, Issue 3, pp. 892 - 895
A facile and general synthesis of various N-substituted cyanamides was accomplished by the Tiemann rearrangement of amidoximes with benzenesulfonyl chlorides... 
CHEMISTRY, ORGANIC | ARYL | ONE-POT SYNTHESIS | RHODIUM-CATALYZED CYANATION | PHENYL-P-TOLUENESULFONAMIDE | CARBODIIMIDES
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 2018, Volume 16, Issue 40, pp. 7346 - 7350
Cp*Co(iii)-catalysed selective alkylation of directed C-H bonds of arenes and heteroarenes has been accomplished employing donor-acceptor carbenes, derived... 
FUNCTIONALIZATION | ACTIVATION | INSERTION | RHODIUM-CATALYZED CYANATION | DIVERGENT SYNTHESIS | CHEMISTRY, ORGANIC | DIAZO-COMPOUNDS | INDOLES
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 07/2017, Volume 2017, Issue 27, pp. 3965 - 3968
The cobalt(III)‐catalyzed chelation‐assisted allylation of arene C–H bonds was accomplished by employing allyl carbonates. The important features of the... 
C–C coupling | Allylic compounds | Nitrogen heterocycles | Cobalt | Allylation | C-C coupling | ROOM-TEMPERATURE | ACTIVATION | ALLYLIC CARBONATES | ANNULATION | CHEMISTRY, ORGANIC | ALKYNES | FUNCTIONALIZATION | RHODIUM-CATALYZED CYANATION | ACETATES | INDOLE SYNTHESIS | CYCLIZATION
Journal Article
by Mo, SY
SYNLETT, ISSN 0936-5214, 06/2014, Volume 25, Issue 9, pp. 1337 - 1338
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2014, Volume 53, Issue 20, pp. 5170 - 5174
A metal‐free, Lewis acid promoted intramolecular aminocyanation of alkenes was developed. B(C6F5)3 activates N‐sulfonyl cyanamides, thus leading to a formal... 
Lewis acids | reaction mechanisms | alkenes | heterocycles | boron | AMINOHALOGENATION | PALLADIUM | TRIS(PENTAFLUOROPHENYL)BORANE | LEWIS-ACID | CARBOAMINATION | CHEMISTRY, MULTIDISCIPLINARY | DIASTEREOSELECTIVE SYNTHESIS | PYRROLIDINES | RHODIUM-CATALYZED CYANATION | ARYL | Lewis acid | Alkenes | Nitriles | Strategy | Cleavage | Activation | Transformations | Bonding | Cyanamides
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 05/2019, Volume 21, Issue 9, pp. 3451 - 3455
Site selective amide reductions of the cyclic undecapeptide, cyclosporine A, have been developed using the combination of a heteroleptic borane catalyst and a... 
HYDROGENATION | METAL-FREE REDUCTION | SECONDARY AMIDES | NITRILES | CHEMISTRY | CHEMISTRY, ORGANIC | NONIMMUNOSUPPRESSIVE CYCLOPHILIN INHIBITORS | RHODIUM-CATALYZED REDUCTION | STRECKER REACTION | ACID ESTERS | BIS(PENTAFLUOROPHENYL)BORANE
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 07/2018, Volume 59, Issue 29, pp. 2816 - 2819
A mild and efficient procedure was developed for the [Cp∗Rh(III)]-catalyzed, 1,2,3-triazole directed C H coupling with diazomethylene-diphosphonates. This... 
Bisphosphonate | C-H activation | 1,2,3-Triazole | Carbenoid | Rhodium-catalyzed
Journal Article
Beilstein Journal of Organic Chemistry, ISSN 1860-5397, 06/2016, Volume 12, Issue 1, pp. 1203 - 1228
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 11/2015, Volume 357, Issue 16‐17, pp. 3707 - 3717
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2007, Volume 692, Issue 4, pp. 761 - 767
Journal Article