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Organic Letters, ISSN 1523-7060, 11/2017, Volume 19, Issue 21, pp. 5908 - 5911
A direct C–H cyanoalkylation of heteroaromatic N-oxides and quinones with cyclobutanone oximes is reported. This redox-neutral, operationally simple... 
KETONES | HETEROCYCLES | O-BENZOYLOXIMES | AMINES | TERTIARY CYCLOALKANOLS | TIN | CHEMISTRY, ORGANIC | IMINYL RADICALS | ALKYL NITRILES | ALDEHYDES | RING-CLEAVAGE
Journal Article
Organic Letters, ISSN 1523-7060, 02/2018, Volume 20, Issue 4, pp. 1034 - 1037
An efficient synthesis of cyanoalkylated heteroarenes via iron-catalyzed direct C–H cyanoalkylation of heteroarenes has been developed. Structurally diverse... 
ALLYLIC ALCOHOLS | CYCLOBUTANONE O-BENZOYLOXIMES | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | QUINOXALINONE DERIVATIVES | ALKYL NITRILES | IMINYL RADICALS | INHIBITORS | RING-CLEAVAGE | OXIME ESTERS | UNACTIVATED ALKENES
Journal Article
Synthesis (Germany), ISSN 0039-7881, 02/2018, Volume 50, Issue 3, pp. 548 - 554
Journal Article
Organic Letters, ISSN 1523-7060, 03/2019, Volume 21, Issue 6, pp. 1766 - 1769
Despite the significant progress that has been made in the area of catalyst-dependent chemistry, the exploration of a greener and more environmentally benign... 
ACTIVATION | CHEMISTRY | CHEMISTRY, ORGANIC | BOND-CLEAVAGE | N-CHLOROAMINES | RING-CLEAVAGE | NICKEL-CATALYZED CHEMO | C-H CYANOALKYLATION
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 04/2019, Volume 55, Issue 32, pp. 4655 - 4658
Herein, we disclose an interesting iron-catalyzed approach for the carbonylation of a tertiary carbon radical. The tertiary carbon radical generated from a... 
FUNCTIONALIZATION | OXIDATION | OXYGEN | ALKYLATION | MONOXIDE | CHEMISTRY | CASCADE | RING-CLEAVAGE | BOND | OXIME ESTERS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2018, Volume 83, Issue 7, pp. 4239 - 4249
Metal-catalyzed cyanoalkylation/cyclization of olefinic 1,3-dicarbonyls with cycloketone oxime esters has been developed under redox-neutral conditions. This... 
ALKENES | NITRILES | CYCLOBUTANONE O-BENZOYLOXIMES | CHEMISTRY, ORGANIC | IMINYL RADICALS | RING-CLEAVAGE | DERIVATIVES | CYCLIZATION | 2,3-DIHYDROFURANS | C-H CYANOALKYLATION | IMIDATION
Journal Article
Organic Letters, ISSN 1523-7060, 09/2018, Volume 20, Issue 17, pp. 5523 - 5527
A unified strategy for intermolecular remote C­(sp3)–H and C–C vinylation of O-acyl oximes with vinyl boronic acids has been achieved. This strategy is enabled... 
FUNCTIONALIZATION | INTRAMOLECULAR HYDROGEN ABSTRACTION | NITROGEN-CENTERED RADICALS | ACYL OXIMES | CHEMISTRY, ORGANIC | BOND FORMATION | RECENT PROGRESS | GENERATION | RING-CLEAVAGE | CYCLOBUTANONE OXIME ESTERS | 1,5-HYDROGEN TRANSFER
Journal Article
Organic Letters, ISSN 1523-7060, 08/2018, Volume 20, Issue 15, pp. 4614 - 4617
An iron-catalyzed redox-neutral, decarboxylative olefination of cycloketone oxime esters with α,β-unsaturated carboxylic acids has been developed. This... 
ORGANIC-SYNTHESIS | CROSS-COUPLING REACTIONS | CINNAMIC-ACIDS | CYCLOBUTANONE O-BENZOYLOXIMES | TERTIARY CYCLOALKANOLS | CHEMISTRY, ORGANIC | IMINYL RADICALS | H BONDS | RING-CLEAVAGE | HYPERVALENT IODINE REAGENTS | PHOTOREDOX CATALYSIS
Journal Article
by Zhang, JJ and Duan, XH and Wu, Y and Yang, JC and Guo, LN
CHEMICAL SCIENCE, ISSN 2041-6520, 01/2019, Volume 10, Issue 1, pp. 161 - 166
An efficient transition-metal free C-C bond cleavage/borylation of cycloketone oxime esters has been described. In this reaction, the B-2(OH)(4) reagent not... 
B BOND | MEDICINAL CHEMISTRY | CROSS-COUPLING REACTIONS | CYCLOBUTANONE O-BENZOYLOXIMES | ACID PROTEASOME INHIBITORS | ARYL HALIDES | BIOLOGICAL EVALUATION | COPPER-CATALYZED BORYLATION | RING-CLEAVAGE | CONJUGATE ADDITIONS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Science, ISSN 2041-6520, 2019, Volume 10, Issue 1, pp. 161 - 166
An efficient transition-metal free C-C bond cleavage/borylation of cycloketone oxime esters has been described. In this reaction, the B (OH) reagent not only... 
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 01/2018, Volume 83, Issue 2, pp. 1046 - 1055
The copper-catalyzed cyclization of activated alkenes with cyclobutanone O-acyl oximes under redox-neutral conditions has been reported. This facile protocol... 
H FUNCTIONALIZATION | C BOND-CLEAVAGE | O-BENZOYLOXIMES | ALKYLARYLATION | RADICAL CYCLIZATION | CHEMISTRY, ORGANIC | CASCADE | ACRYLAMIDES | GENERATION | OXIDATIVE CYCLIZATION | RING-CLEAVAGE | Chemical reactions | Usage | Ring formation (Chemistry) | Chemical properties | Indole
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 71, pp. 9925 - 9928
On the basis of the strategy of iminyl radical-mediated C-C bond cleavage, a visible light photocatalytic radical addition/cyclization cascade is described,... 
VISIBLE-LIGHT | H CYANOALKYLATION | NITROGEN-CENTERED RADICALS | CYCLOBUTANONE O-BENZOYLOXIMES | LIGHT PHOTOREDOX CATALYSIS | GENERATION | RING-CLEAVAGE | OXIME ESTERS | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | CARBOXYLIC-ACIDS | Cleavage | Photocatalysis
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 09/2018, Volume 54, Issue 71, pp. 9925 - 9928
On the basis of the strategy of iminyl radical-mediated C-C bond cleavage, a visible light photocatalytic radical addition/cyclization cascade is described,... 
Journal Article
by Anand, D and He, YW and Li, LY and Zhou, L
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 01/2019, Volume 17, Issue 3, pp. 533 - 540
The photocatalytic thiolation, selenylation and borylation of cycloketone oxime esters through iminyl radical-triggered C-C bond cleavage were described. The... 
H CYANOALKYLATION | NITRILES | AMINES | CYCLOBUTANONE O-BENZOYLOXIMES | CHEMISTRY, ORGANIC | IMINYL RADICALS | RING-CLEAVAGE | INDOLES | ACCESS
Journal Article
by Gu, YR and Duan, XH and Chen, L and Ma, ZY and Gao, P and Guo, LN
ORGANIC LETTERS, ISSN 1523-7060, 02/2019, Volume 21, Issue 4, pp. 917 - 920
An efficient iron-catalyzed intermolecular remote C(sp(3))-H heteroarylation of alkyl ketones has been developed via an iminyl radical-triggered... 
FUNCTIONALIZATION | ARYLATION | ACYL OXIMES | CHEMISTRY, ORGANIC | HYDROGEN-ATOM | ALKOXYL RADICALS | IRON | QUINOXALIN-2(1H)-ONES | RING-CLEAVAGE | C-H BONDS | CYCLIZATION
Journal Article
Tetrahedron, ISSN 0040-4020, 04/2014, Volume 70, Issue 15, pp. 2515 - 2522
A stereocontrolled approach to functionalized acyclic β -amino acid derivatives was accomplished from - or -2-aminocyclohexenecarboxylates derived from... 
Wittig reaction | Amino acids | Oxidation | Functionalization | Ring cleavage
Journal Article
Chemical science, ISSN 2041-6520, 07/2018, Volume 9, Issue 27, pp. 5883 - 5889
Fine-tuned organic photoredox catalysts are introduced for the metal-free alkynylation of alkylnitrile radicals generated oxidative ring opening of cyclic... 
Journal Article
Chemical Science, ISSN 2041-6520, 2018, Volume 9, Issue 27, pp. 5883 - 5889
Fine-tuned organic photoredox catalysts are introduced for the metal-free alkynylation of alkylnitrile radicals generated via oxidative ring opening of cyclic... 
C BOND-CLEAVAGE | NITRILES | CYCLOBUTANONE O-BENZOYLOXIMES | IMINYL RADICALS | VINYLBENZIODOXOLONES | GENERATION | RING-CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | ALKENYLATION | DECARBOXYLATIVE ALKYNYLATION | CARBOXYLIC-ACIDS | Oxidation | Catalysis | Catalysts | Ethers | Cascades | Ring opening
Journal Article
by Ren, RG and Wu, Z and Zhu, C
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 2016, Volume 52, Issue 52, pp. 8160 - 8163
A manganese-catalyzed regioselective sp(3) C-S bond formation through C-C bond cleavage of cyclobutanols is described. A variety of primary and secondary alkyl... 
TERT-CYCLOBUTANOLS | H FLUORINATION | KETONES | ACTIVATION | VINYL AZIDES | STRATEGY | CYCLOPROPANOLS | ASYMMETRIC ARYLATION | OXIDATIVE RING-CLEAVAGE | PORPHYRIN | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 03/2018, Volume 54, Issue 22, pp. 2800 - 2803
Alkenes bearing a stereocenter in the allylic position were found to undergo Kulinkovich hydroxycyclopropanation with good diastereoselectivity. For the... 
Journal Article
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