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ruo4-catalyzed ketohydroxylation (43) 43
chemistry, organic (25) 25
oxidation (18) 18
chemistry, multidisciplinary (16) 16
alkenes (14) 14
ketones (14) 14
olefins (13) 13
catalysis (12) 12
chemical properties (11) 11
molecular structure (9) 9
oxidation-reduction reaction (8) 8
stereoisomerism (8) 8
dihydroxylation (7) 7
molecular-oxygen (7) 7
alcohols (6) 6
analysis (6) 6
asymmetric dihydroxylation (6) 6
index medicus (6) 6
metal-free (6) 6
ruthenium (6) 6
aerobic dioxygenation (5) 5
cyclization (5) 5
derivatives (5) 5
n-hydroxyphthalimide (5) 5
oxidation-reduction (5) 5
scope (5) 5
selective oxidation (5) 5
hydrogen-peroxide (4) 4
hydroxylation (4) 4
ketones - chemical synthesis (4) 4
ketones - chemistry (4) 4
oxidative cleavage (4) 4
peracetic-acid (4) 4
ring-closing metathesis (4) 4
selectivity (4) 4
stereoselective-synthesis (4) 4
acid (3) 3
aldehydes (3) 3
alkenes - chemistry (3) 3
chemical synthesis (3) 3
crystallography, x-ray (3) 3
difunctionalization (3) 3
dioxygenation (3) 3
efficient (3) 3
enantioselective synthesis (3) 3
epoxidation (3) 3
homogeneous catalysis (3) 3
hydrocarbons (3) 3
isoprenoid polyenes (3) 3
models, molecular (3) 3
oxygen (3) 3
polycyclization (3) 3
ruthenium tetraoxide (3) 3
structure (3) 3
transformation (3) 3
unactivated alkenes (3) 3
1,2-diols (2) 2
aerobic oxidation (2) 2
alcohols - chemistry (2) 2
alkylation (2) 2
alpha,beta-unsaturated aldehydes (2) 2
alpha-hydroxy ketones (2) 2
alpha-hydroxy-ketones (2) 2
amination (2) 2
aminohydroxylation (2) 2
asymmetric catalysis (2) 2
benzoin condensation (2) 2
bimetallic palladium complex (2) 2
biosynthesis (2) 2
bond isomerization sequence (2) 2
catalysts (2) 2
catalyzed oxidative transformation (2) 2
chemistry, physical (2) 2
complexes (2) 2
copper (2) 2
cycloaddition (2) 2
dimethyl carbonate (2) 2
diols (2) 2
epoxides (2) 2
epoxomicin (2) 2
functionalization (2) 2
high enantiomeric purity (2) 2
lösungsmittel (2) 2
manganese (2) 2
organic chemistry (2) 2
oxidant (2) 2
oxidants (2) 2
oxidation-reaction (2) 2
oxidizing agents (2) 2
peroxides (2) 2
phenanthren (2) 2
phenanthrene (2) 2
polyols (2) 2
potassium permanganate (2) 2
pyren (2) 2
pyrene (2) 2
radicals (2) 2
reaction mechanisms (2) 2
reactivity (2) 2
ruthenium - chemistry (2) 2
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Journal of Organic Chemistry, ISSN 0022-3263, 06/2015, Volume 80, Issue 11, pp. 5572 - 5580
An efficient catalytic approach for the synthesis of substituted peroxides, alcohols, and ketones through a catalyst-controlled highly selective dioxygenation... 
RUO4-CATALYZED KETOHYDROXYLATION | AEROBIC DIOXYGENATION | CONJUGATED DIENES | CHEMISTRY, ORGANIC | N-HYDROXYPHTHALIMIDE | HYDROGEN-PEROXIDE | O BOND FORMATION | C-H BONDS | METAL-FREE | MOLECULAR-OXYGEN | UNACTIVATED ALKENES | Catalysts | Ketones | Olefins | Peroxides | Chemical properties | Research | Chemical synthesis | Alcohols
Journal Article
Tetrahedron: Asymmetry, ISSN 0957-4166, 2005, Volume 16, Issue 21, pp. 3453 - 3459
α-Hydroxy ketones serve as versatile intermediates in organic chemistry. Although this functional group combination allows a variety of synthetic manipulation,... 
TRANSFORMATION | ORGANIC-SYNTHESIS | ALKENES | RUO4-CATALYZED KETOHYDROXYLATION | ACID | METATHESIS CATALYSTS | SCOPE | ASYMMETRIC DIHYDROXYLATION | CHEMISTRY, PHYSICAL | CIS-DIHYDROXYLATION | OLEFINS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2017, Volume 139, Issue 51, pp. 18504 - 18507
The total synthesis of (±)-aspergilline A (1) is described. Key features of the synthesis include pyrrolinone formation via reaction of an intermediate... 
OXIDATION | CYCLOADDITION | RUO4-CATALYZED KETOHYDROXYLATION | ACID | ACETALS | INDOLIZIDINES | INHIBITORS | CYCLOPROPENONE KETALS | DERIVATIVES | PYRROLIZIDINES | CHEMISTRY, MULTIDISCIPLINARY | Amines | Chemical properties | Chemical synthesis | Analysis | Pyrrole | Methyl groups
Journal Article
Synthesis, ISSN 0039-7881, 02/2020, Volume 52, Issue 3, pp. 353 - 364
Journal Article
Tetrahedron, ISSN 0040-4020, 07/2017, Volume 73, Issue 29, pp. 4160 - 4171
Journal Article
Organic Letters, ISSN 1523-7060, 10/2006, Volume 8, Issue 21, pp. 4759 - 4762
The utility of Grubbs' 2nd generation metathesis catalyst has been expanded by the development of two tandem olefin metathesis/oxidation protocols. These... 
DIHYDROXYLATION | RUO4-CATALYZED KETOHYDROXYLATION | RING-CLOSING METATHESIS | BOND ISOMERIZATION SEQUENCE | ENYNE | CHEMISTRY, ORGANIC | SELECTIVITY | RCM | IN-SITU
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 10/2017, Volume 2017, Issue 37, pp. 5424 - 5438
Dioxygenation of olefins is a valuable synthetic tool for the construction of 1,2‐diols and α‐oxygenated ketones. The use of radical approaches to achieve this... 
Transition metals | Alkenes | Radical reactions | Dioxygenation | Metal‐free | Photoredox | Alcohols | Metal-free | RUO4-CATALYZED KETOHYDROXYLATION | HYDROXAMIC ACIDS | ALPHA-OXYGENATED KETONES | CHEMISTRY, ORGANIC | N-HYDROXYPHTHALIMIDE | UNACTIVATED ALKENES | AEROBIC DIOXYGENATION | BETA-KETOPHOSPHONATES | TERMINAL ALKENES | MOLECULAR-OXYGEN | Olefins
Journal Article
Tetrahedron, ISSN 0040-4020, 11/2015, Volume 71, Issue 45, pp. 8517 - 8520
An efficient method of copper-catalyzed 1,2-dihydroxylaminations of alkenes have been demonstrated under air conditions by using PhI(OAc)2 as oxidant to... 
Copper-catalyzed | 1,2-Dihydroxylamination | Styrenes | Radical addition | N-Hydroxyphthalimide | OXIDATION | RUO4-CATALYZED KETOHYDROXYLATION | CHEMISTRY, ORGANIC | BOND FORMATION | DIFUNCTIONALIZATION | ALKENES | AEROBIC DIOXYGENATION | OLEFINS | EFFICIENT | METAL-FREE | MOLECULAR-OXYGEN | Copper
Journal Article
Tetrahedron, ISSN 0040-4020, 06/2016, Volume 72, Issue 22, pp. 3068 - 3072
A mild metal-free acid-catalyzed 1,2-dihydroxylaminations of alkenes with N-hydroxyphthalimide and 2,2,6,6-tetramethylpiperidine N-oxyl (TEMPO) has been... 
Acid-catalyzed | TEMPO | C–O coupling | N-hydroxyphthalimide | 1,2-Dihydroxylaminations | C-O coupling | OXIDATION | RUO4-CATALYZED KETOHYDROXYLATION | CHEMISTRY, ORGANIC | DIFUNCTIONALIZATION | FUNCTIONALIZATION | ARYL DIAZONIUM SALTS | AEROBIC DIOXYGENATION | PROGRESS | OLEFINS | METAL-FREE | MOLECULAR-OXYGEN | Trapping | Ketones | Alkenes | Styrenes | Tetrahedrons | Coupling | Derivatives | Radicals
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2008, Volume 73, Issue 8, pp. 3218 - 3227
Sequential catalysis has evolved as a powerful concept within the past years and allows the more efficient use of catalytically active expensive transition... 
TANDEM CATALYSIS | RUO4-CATALYZED KETOHYDROXYLATION | BOND ISOMERIZATION SEQUENCE | ALARM PHEROMONE | KHARASCH ADDITIONS | RADICAL CYCLIZATION | COMPLEXES | CHIRAL AUXILIARIES | CHEMISTRY, ORGANIC | RUTHENIUM | OLEFIN METATHESIS | Oxidation-reduction reaction | Chemical properties | Catalysis | Rubidium | Analysis | Olefins
Journal Article
Synthesis, ISSN 0039-7881, 02/2016, Volume 48, Issue 3, pp. 429 - 436
Abstract A new procedure for the oxidation of sulfides to sulfones utilizing heterogeneous ruthenium reagent has been developed. A small amount of ruthenium... 
paper | dimethyl carbonate | sulfones | green chemistry | RuO | sulfides | SYSTEM | SELECTIVE OXIDATION | RUO4-CATALYZED KETOHYDROXYLATION | CHEMISTRY, ORGANIC | CLEAVAGE | RuO4 | EFFICIENT OXIDATION | ALLYLIC ALCOHOLS | TETRAOXIDE | AEROBIC OXIDATION | RECYCLABLE CATALYST | PERACETIC-ACID
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2007, Volume 129, Issue 32, pp. 9964 - 9975
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 12/2017, Volume 2017, Issue 46, pp. 6919 - 6925
-Hydroxy ketones are valuable synthons in organic chemistry. Here we show that oxidation of vic-diols to -hydroxy ketones with H2O2 can be achieved with an in... 
SELECTIVE OXIDATION | Hydrogen peroxide | RUO4-CATALYZED KETOHYDROXYLATION | DIRECT CONVERSION | SODIUM-HYPOCHLORITE | BIMETALLIC PALLADIUM(II) COMPLEX | ALKENES | Hydroxyl ketone | 1,2-DIOLS | ALPHA-HYDROXYLATION | Homogeneous catalysis | Earth-abundant metals | OLEFINS | Oxidation | Manganese | CHEMISTRY, ORGANIC | Oxidation-reduction reaction | Glycols | Ketones | Olefins
Journal Article
Synlett, ISSN 0936-5214, 02/2013, Volume 24, Issue 3, pp. 276 - 280
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 11/2014, Volume 16, Issue 21, pp. 5674 - 5677
I-2-catalyzed oxo-acyloxylation of alkenes and enol ethers with carboxylic acids providing for the high yield synthesis of a-acyloxyketones and esters is... 
OXIDATION | DIHYDROXYLATION | KETONES | RUO4-CATALYZED KETOHYDROXYLATION | SELECTIVE BENZOYLATION | ACETOXYLATION | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | HIGHLY EFFICIENT | METAL-FREE | CARBOXYLIC-ACIDS
Journal Article
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