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Journal of the American Chemical Society, ISSN 0002-7863, 09/2010, Volume 132, Issue 38, pp. 13191 - 13193
The first invertive B-alkyl Suzuki−Miyaura coupling has been achieved. The coupling of enantioenriched α-(acylamino)benzylboronic esters with aryl bromides and... 
HALIDES | PALLADIUM | ACID | C-N | RETENTION | TRANSMETALATION | STEREOCHEMISTRY | ALKYLBORANES | ARYL | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Synthetic Communications, ISSN 0039-7911, 11/2014, Volume 44, Issue 21, pp. 3173 - 3182
An efficient approach toward the construction of multistereogenic binaphthol (BINOL)-derived alkaloids with C 2 -axial and sp 3 central chirality has been... 
BINOL | inversion | multistereogenic chirality | retention | Mitsunobu reaction | cinchona alkaloids | AZA-MICHAEL REACTION | CATALYSIS | ESTERIFICATION | CHEMISTRY, ORGANIC | 9-EPIMERS | FUNCTIONALIZATION | ALCOHOLS | PRIMARY AMINE | QUININE | ACCESS
Journal Article
Heterocycles, ISSN 0385-5414, 02/2009, Volume 78, Issue 2, pp. 331 - 336
Two isolable thiirane 1-imides 21 and 22 were synthesized successfully by imination of anti- and syn-2'-adamantylidene-9-benzonorbornenylidene sulfides 19 and... 
Inversion of Configuration | Thiirane 1-Imide | Retention of Configuration | Aziridine | 1,2-Thiazetidine | TOLYLSULPHONYLSULPHIMIDES | CHEMISTRY | CHEMISTRY, ORGANIC | SINGLET
Journal Article
CHEMISTRY-AN ASIAN JOURNAL, ISSN 1861-4728, 09/2018, Volume 13, Issue 17, pp. 2414 - 2417
Suzuki-Miyaura coupling of nonbenzylic -(acylamino)alkylboron compounds with aryl halides is established. A Pd/PCy2Ph catalyst promotes the reaction... 
HALIDES | HYDROBORATION | ASYMMETRIC-SYNTHESIS | RETENTION | CONFIGURATION | SECONDARY | organoboron compounds | INVERSION | CHEMISTRY, MULTIDISCIPLINARY | NUCLEOPHILES | asymmetric synthesis | stereospecific reaction | CONSTRUCTION | ALPHA-(ACYLAMINO)BENZYLBORONIC ESTERS | palladium | synthetic methods | Palladium | Synthesis | Enantiomers | Organic compounds
Journal Article
Annals of Nuclear Energy, ISSN 0306-4549, 01/2015, Volume 75, pp. 476 - 482
For a detailed evaluation of the IVR (In-Vessel corium Retention) through the ERVC (External Reactor Vessel Cooling) during a severe accident, the melt pool... 
Thermodynamic analysis | Layer inversion | Severe accident | Thermal stratification | IVR-ERVC | Three-layer formation | NUCLEAR SCIENCE & TECHNOLOGY | RETENTION | Marine accidents | Analysis | Thermodynamics | Nuclear reactors | Accidents | Melt pools | Inversions | Nuclear engineering | Graphs | Pools | Density
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2014, Volume 20, Issue 35, pp. 11225 - 11228
Journal Article
NATURE COMMUNICATIONS, ISSN 2041-1723, 01/2015, Volume 6
Stereo-specific reaction mechanisms play a fundamental role in chemistry. The back-side attack inversion and front-side attack retention pathways of the... 
ENERGY | RETENTION | MULTIDISCIPLINARY SCIENCES | AB-INITIO | NUCLEOPHILIC-SUBSTITUTION | S(N)2 REACTIONS | CONFIGURATION | DYNAMICS | ATOM
Journal Article
JOURNAL OF PHYSICAL CHEMISTRY A, ISSN 1089-5639, 03/2015, Volume 119, Issue 12, pp. 3134 - 3140
The double-inversion and front-side attack transition states as well as the proton-abstraction channels of the X- + CH3Y [X,Y = F, Cl, Br, I] reactions are... 
ANIONS | IDENTITY S(N)2 REACTIONS | ENERGY | CH3X+F-X | METHYL HALIDES | RETENTION | AB-INITIO | CONFIGURATION | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | DYNAMICS | CHEMISTRY, PHYSICAL | BASIS-SETS
Journal Article
Carbohydrate Research, ISSN 0008-6215, 04/2019, Volume 476, pp. 53 - 59
A rapid mass spectrometry method for determining the anomeric configuration of the sugar at the reducing end of an oligosaccharide was demonstrated. The method... 
Inversion | Glycoside hydrolases | Anomeric configuration | Retention | Mass spectrometry | Mechanism | Carbohydrate-active enzymes | MALTASE-GLUCOAMYLASE | ACTIVE-SITE | BIOCHEMISTRY & MOLECULAR BIOLOGY | CHEMISTRY, ORGANIC | COLLISION-INDUCED DISSOCIATION | ENZYME DYNAMICS | FORMS | SUBSTRATE-SPECIFICITY | GLUCOSE | PURIFICATION | X-RAY | CHEMISTRY, APPLIED | Enzymes | Hydrolases
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2016, Volume 55, Issue 38, pp. 11664 - 11667
Journal Article
ACS Omega, ISSN 2470-1343, 03/2019, Volume 4, Issue 3, pp. 5012 - 5018
Nitrosobenzene has been demonstrated to participate in the Mitsunobu reaction in an analogous manner to dialkyl azodicarboxylates. The protocol using... 
PHOSPHORUS | DIMETHYLMALONYLTRIALKYLPHOSPHORANES | MECHANISM | REDUCTION | RETENTION | CONFIGURATION | TRIPHENYLPHOSPHINE | INVERSION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2017, Volume 139, Issue 28, pp. 9519 - 9522
Coupling reactions between benzylamines and boronic esters have been investigated. ortho-Lithiated benzylamines react with boronic esters and a N-activator to... 
NUCLEOPHILES | ALLYLBORANES | CROSS-COUPLING REACTIONS | DESIGN | TRIARYLMETHANES | RETENTION | CONFIGURATION | SECONDARY | ORGANOBORONIC ESTERS | INVERSION | CHEMISTRY, MULTIDISCIPLINARY | Communication
Journal Article
Chemical Science, ISSN 2041-6520, 10/2014, Volume 5, Issue 4, pp. 1361 - 1367
Palladium-catalysed cross-coupling of secondary C(sp(3)) organometallic reagents has been a long-standing challenge in organic synthesis, due to the problems... 
ESTERS | CONFIGURATION | ALKYLZINC REAGENTS | ORGANIC HALIDES | INVERSION | ORGANOLITHIUM COMPOUNDS | DERIVATIVES | SELECTIVITY | ARYL CHLORIDES | ALKENYLATION | HALIDES | RETENTION | CHEMISTRY | ARYL | ALKYL GRIGNARD | CHEMISTRY, MULTIDISCIPLINARY | Carbon-carbon composites | Cross coupling | Aromatic compounds | Isomerization | Metalorganic compounds | Bromides | Chemical reactions | Bonding
Journal Article
Nuclear Engineering and Design, ISSN 0029-5493, 10/2014, Volume 278, pp. 163 - 170
COSMOS (COrium configuration of the molten State in the MOst Severe accidents) tests using prototypic materials have been performed to investigate the layer... 
NUCLEAR SCIENCE & TECHNOLOGY | IN-VESSEL RETENTION | Melting | Inversions | Nuclear reactor components | Crucibles | Pools | Cosmos | Ingots | Accidents
Journal Article
Synthesis, ISSN 0039-7881, 07/2013, Volume 45, Issue 13, pp. 1759 - 1763
Abstract The use of potassium carbonate in addition to silver oxide­ is shown to increase the enantiospecificity of the Suzuki–Miyaura­ cross-coupling reaction... 
paper | cross-coupling | palladium | chiral | enantiospecific | Suzuki | ACIDS | RETENTION | CONFIGURATION | CHEMISTRY, ORGANIC | CATALYTIC ASYMMETRIC HYDROBORATION | BORONIC ESTERS | RHODIUM COMPLEXES | INVERSION | ALKENES | OLEFINS | ENANTIOSELECTIVE HYDROBORATION
Journal Article
Chemical Research in Chinese Universities, ISSN 1005-9040, 8/2013, Volume 29, Issue 4, pp. 678 - 681
A controllable diastereoselective C(sp 2)-C(sp 3) Negishi coupling reaction of secondary benzylic zinc reagents with aryl bromides to form medicinally... 
Chemistry | Analytical Chemistry | Chemistry/Food Science, general | Physical Chemistry | Negishi coupling | Palladium | Inorganic Chemistry | Benzylic zinc | 2-Arylphenylethylamine | Organic Chemistry | Stereoselective | HALIDES | RETENTION | INVERSION | CHEMISTRY, MULTIDISCIPLINARY | ZINC | SECONDARY ALKYL ELECTROPHILES | BETA-PHENYLETHYLAMINE | ESTERS
Journal Article
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