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European Journal of Inorganic Chemistry, ISSN 1434-1948, 10/2017, Volume 2017, Issue 38-39, pp. 4533 - 4540
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2015, Volume 54, Issue 35, pp. 10173 - 10177
{Rh(xantphos)}‐based phosphido dimers form by PC activation of xantphos (4,5‐bis(diphenylphosphino)‐9,9‐dimethylxanthene) in the presence of amine–boranes.... 
P ligands | X‐ray diffraction | homogeneous catalysis | amine–boranes | rhodium | X-ray diffraction | amine-boranes | MECHANISM | MOLECULAR-STRUCTURE | CRYSTAL-STRUCTURES | ADDUCTS | AMMONIA-BORANE | BOND-CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | DEHYDROGENATION | DIHYDROGEN | LIGANDS | METAL-COMPLEXES | Bimetals | Rhodium | Catalysts | Forming | Activation | Dimers | Formations | Catalysis | Communications
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2009, Volume 131, Issue 40, pp. 14168 - 14169
Catalytic hydrogenation of carbon dioxide in aqueous potassium hydroxide was performed using a newly synthesized isopropyl-substituted PNP-pincer iridium... 
HOMOGENEOUS HYDROGENATION | FORMIC-ACID | ELECTRON-RICH | RHODIUM | IRIDIUM | PINCER COMPLEXES | CO2 HYDROGENATION | RUTHENIUM | ALKANE DEHYDROGENATION | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | Analysis | Carbon dioxide | Substitution reactions | Catalysis | Iridium | Chemical properties | Hydrogenation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2018, Volume 57, Issue 18, pp. 4956 - 4959
A general and operationally convenient method for intermolecular amination of C(sp3)−H bonds is described. This technology allows for efficient... 
reaction mechanisms | C−H oxidation | amination | sulfamates | rhodium | BOND AMINATION | NITRENE TRANSFER-REACTIONS | CATALYST | RH-2(ESP) | CHEMISTRY, MULTIDISCIPLINARY | CHALLENGES | FUNCTIONALIZATION | C-H oxidation | CARBOXYLATE | AZIRIDINATION | ASSIGNMENT | C-H AMINATION | Oxidation | Amination | Substrates | Molecular chains | Aluminum oxide
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2015, Volume 137, Issue 3, pp. 1258 - 1272
The photochemical reactions of Tp′Rh­(PMe3)­H2 (1) and thermal reactions of Tp′Rh­(PMe3)­(CH3)H (1a, Tp′ = tris­(3,5-dimethylpyrazolyl)­borate) with substrates... 
POTENTIAL BASIS-SETS | ALIPHATIC ETHERS | TRANSITION-METAL-COMPLEXES | OXIDATIVE-ADDITION | RHODIUM-TRISPYRAZOLYLBORATE | THERMODYNAMIC SELECTIVITY | FLUORINATED PYRIDINES | POLARIZATION FUNCTIONS | SIGMA-COMPLEXES | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | Silicon compounds | Chemical properties | Chemical reaction, Rate of | Structure | Carbon compounds | Analysis
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 09/2011, Volume 50, Issue 17, pp. 7919 - 7921
We have succeeded in obtaining unique one-dimensional (1D) chain complexes (1, 2, and 3) comprised of two types of metal species: rhodium and platinum. These... 
ALPHA-PYRIDONE BLUE | MIXED OXIDATION-STATES | DIMER | ESR | CRYSTAL-STRUCTURE | COMPOUND | CHEMISTRY, INORGANIC & NUCLEAR | Platinum compounds | Metal bonding | Molecular structure | Rhodium | Chemical properties | Research | Coordination compounds | Structure
Journal Article