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chemistry, organic (420) 420
rhodium-catalyzed hydroformylation (401) 401
chemistry, multidisciplinary (261) 261
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amines (32) 32
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Organic Letters, ISSN 1523-7060, 09/2017, Volume 19, Issue 17, pp. 4544 - 4547
An alkylation of C–H bonds with maleimides by a rhodium-catalyzed reaction of aromatic amides containing an 8-aminoquinoline moiety as the directing group is... 
FUNCTIONALIZATION | CHEMISTRY, ORGANIC | ACTIVATION | 1,4-ADDITION | RHODIUM-CATALYZED ALKYLATION | BIDENTATE
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 12/2014, Volume 136, Issue 51, pp. 17722 - 17725
The first cobalt-catalyzed cyanation, halogenation, and allylation via C-H activation have been realized. These formal S-N-type reactions generate valuable... 
MILD | DIRECT ARYLATION | RHODIUM-CATALYZED CYANATION | ROBUSTNESS SCREEN | AROMATIC IMINES | RAPID ASSESSMENT | ELECTRON-DEFICIENT ARENES | CARBON-CARBON BONDS | CHEMISTRY, MULTIDISCIPLINARY | DIRECT ALKYLATION | COBALT
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 5/2015, Volume 44, Issue 11, pp. 3378 - 339
Being mono-aza analogues of sulfoxides and sulfones, sulfimides and sulfoximines, respectively, are important compounds in asymmetric synthesis, crop... 
SULFOXIDES | AMINATION | AZIDES | HYPERVALENT IODINE | SULFIDES | N-SULFONYLSULFILIMINES | NITROGEN TRANSFER | NITRENE TRANSFER-REACTIONS | SULFILIMINES | CHEMISTRY, MULTIDISCIPLINARY | RHODIUM-CATALYZED IMINATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 15, pp. 5204 - 5209
A series of diphosphine ligand constructed porous polymers with stable and flexible frameworks have been successfully synthesized under the solvothermal... 
NANOPARTICLES | ACID | ASYMMETRIC HYDROFORMYLATION | PHASE CATALYSIS | PERFORMANCE | RHODIUM-CATALYZED HYDROFORMYLATION | COMPLEXES | CO2 | HOMOGENEOUS CATALYSIS | HRH(CO)(PPH3) | CHEMISTRY, MULTIDISCIPLINARY | Ligands | Research | Chemical properties | Polymers | Chemical synthesis
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 07/2018, Volume 59, Issue 29, pp. 2816 - 2819
A mild and efficient procedure was developed for the [Cp∗Rh(III)]-catalyzed, 1,2,3-triazole directed C H coupling with diazomethylene-diphosphonates. This... 
Bisphosphonate | C-H activation | 1,2,3-Triazole | Carbenoid | Rhodium-catalyzed
Journal Article
ChemCatChem, ISSN 1867-3880, 2019, Volume 11, Issue 16, pp. 3791 - 3796
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 05/2015, Volume 44, Issue 11, pp. 3378 - 3390
Being mono-aza analogues of sulfoxides and sulfones, sulfimides and sulfoximines, respectively, are important compounds in asymmetric synthesis, crop... 
Availability | Asymmetry | Searching | Crops | Chemists | Tools | Sulfur | Optimization
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 04/2018, Volume 59, Issue 16, pp. 1568 - 1572
A high regioselective rhodium-catalyzed C H coupling of 2-arylindoles with diazo compounds via NH-indole-directed C H bond activation has been developed. The... 
Diazo compounds | 2-Arylindoles | C[sbnd]H functionalization | Rhodium-catalyzed
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2018, Volume 83, Issue 24, pp. 15195 - 15201
Rhodium-catalyzed transannulation of N-perfluoroalkylated 1,2,3-triazoles with 1,3-dienes under microwave heating proceeded chemoselectively via the formal... 
REARRANGEMENT | AZIDES | ANNULATION | 1,2,3-TRIAZOLES | CHEMISTRY, ORGANIC | FLUORINE | RHODIUM-CATALYZED TRANSANNULATION | GENERATION | ALKYNES
Journal Article
CHEMICAL SOCIETY REVIEWS, ISSN 0306-0012, 2007, Volume 36, Issue 7, pp. 1069 - 1084
Activation of sp(3) C - H bonds adjacent to nitrogen in heterocycles is an attractive transformation that is emerging as a practical method in organic... 
LITHIOAMINE SYNTHETIC EQUIVALENTS | ORGANIC-SYNTHESIS | N-BOC-PYRROLIDINE | ENANTIOSELECTIVE DEPROTONATION | COUPLING REACTION | ASYMMETRIC DEPROTONATIONS | RHODIUM-CATALYZED REACTION | LITHIATION-SUBSTITUTION | THREO-METHYLPHENIDATE | CHEMISTRY, MULTIDISCIPLINARY | CYCLIC AMINES
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 08/2016, Volume 45, Issue 16, pp. 4552 - 4566
Since the first discovery of carbocupration of alkynes in the 1970s a tremendous amount of research has been carried out in this field. The exceptionally high... 
ALKYLIDENECYCLOPROPANE DERIVATIVES | ACYCLIC SYSTEMS | QUATERNARY STEREOGENIC CENTERS | ASYMMETRIC-SYNTHESIS | BUILDING-BLOCKS | RHODIUM-CATALYZED HYDROFORMYLATION | CHEMISTRY | ALKYNES | CYCLOPROPENE DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS
Journal Article
Organic Letters, ISSN 1523-7060, 02/2014, Volume 16, Issue 3, pp. 892 - 895
A facile and general synthesis of various N-substituted cyanamides was accomplished by the Tiemann rearrangement of amidoximes with benzenesulfonyl chlorides... 
CHEMISTRY, ORGANIC | ARYL | ONE-POT SYNTHESIS | RHODIUM-CATALYZED CYANATION | PHENYL-P-TOLUENESULFONAMIDE | CARBODIIMIDES
Journal Article
Organic Letters, ISSN 1523-7060, 04/2017, Volume 19, Issue 7, pp. 1504 - 1507
An efficient synthesis of tetrahydrocarboline-type products and polycyclic spiroindolines has been achieved. The transformation proceeds via... 
AZAVINYL CARBENES | REARRANGEMENT | ANNULATION | 1,2,3-TRIAZOLES | CHEMISTRY, ORGANIC | CASCADE | RHODIUM-CATALYZED TRANSANNULATION | DERIVATIVES | ACCESS | TRIAZOLES | ALKALOIDS
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 11/2019, Volume 60, Issue 48, p. 151284
This manuscript describes the reaction of dienes with carbonyls in the presence of molecular iodine under visible light irradiation to furnish the... 
Visible light | Lactone | Radical reaction | Iodine | ALKENES | DIENES | LACTONES | RHODIUM-CATALYZED HYDROFORMYLATION | HYDROSILYLATION | CHEMISTRY, ORGANIC
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 02/2015, Volume 51, Issue 21, pp. 4507 - 4510
The Rh(ii)-catalyzed formal [3+2] and [3+3] cycloadditions of 1-tosyl 1,2,3-triazoles with 2H-azirines have been developed, which enable the efficient... 
Cycloaddition | Synthesis
Journal Article
Chemical Communications, ISSN 1359-7345, 2019, Volume 55, Issue 9, pp. 1209 - 1212
A rhodium-catalyzed aromatic C-H bond direct cyanation with safe, bench-stable, and commercially available dimethylmalononitrile as the cyanating agent has... 
HALIDES | TRANSNITRILATION | CARBON | NITRILES | RHODIUM-CATALYZED CYANATION | ARENES | CHLORIDES | LITHIUM REAGENTS | BOND | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD
Journal Article
Organic Letters, ISSN 1523-7060, 03/2019, Volume 21, Issue 5, pp. 1402 - 1406
A new metal-free reductive amination protocol using a pinacol-derived chlorohydrosilane/pyridine system for the preparation of aminoalkylphenols is described.... 
KETONES | IMINES | ESTERS | SECONDARY | CHEMISTRY, ORGANIC | ALDEHYDES | RHODIUM-CATALYZED REDUCTION | AMIDES | BASE | Letter
Journal Article
05/2017, Volume 7, Issue 45, pp. 2847 - 28418
The development of simple and efficient methods for construction of substituted γ-lactams is an important synthetic goal because such ring skeletons are... 
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 11/2017, Volume 19, Issue 21, pp. 5764 - 5767
A convenient, Rh(II)-catalyzed, denitrogenative reaction of N-sulfonyl-1,2,3-triazoles and isatins to access... 
ELECTROPHILIC REARRANGEMENTS | ACTIVATION | ASYMMETRIC-SYNTHESIS | AZIDES | ANNULATION | CONVERSION | 1,2,3-TRIAZOLES | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | RHODIUM-CATALYZED TRANSANNULATION | AMIDES
Journal Article
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