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ruppert-prakash reagent (48) 48
chemistry, organic (31) 31
ruppert–prakash reagent (21) 21
fluorine (20) 20
chemistry, multidisciplinary (16) 16
trifluoromethylation (15) 15
carbonyl-compounds (13) 13
medicinal chemistry (13) 13
nucleophilic trifluoromethylation (13) 13
difluorocarbene (12) 12
difluoromethylation (11) 11
chemical tests and reagents (8) 8
chemistry, inorganic & nuclear (8) 8
cycloalkanes (7) 7
fluoroform (7) 7
perfluoroalkylation (7) 7
reagents (7) 7
synthesis (7) 7
aldehydes (6) 6
amines (6) 6
chemistry (6) 6
cycloaddition (6) 6
derivatives (6) 6
fluor (6) 6
index medicus (6) 6
asymmetric-synthesis (5) 5
catalyzed trifluoromethylation (5) 5
fluorides (5) 5
fluorination (5) 5
gem-difluoroolefination (5) 5
oxidative trifluoromethylation (5) 5
substrates (5) 5
trimethylchlorosilan (5) 5
trimethylchlorosilane (5) 5
activation (4) 4
alkenes (4) 4
catalysis (4) 4
chemisches reaktionsvermögen (4) 4
copper (4) 4
imines (4) 4
ketones (4) 4
organic chemistry (4) 4
reactivity (4) 4
stereoselective-synthesis (4) 4
trifluoromethyltrimethylsilane (4) 4
9-trifluoromethylacridines (3) 3
arenes (3) 3
aryl boronic acids (3) 3
building-blocks (3) 3
carbon (3) 3
chemical properties (3) 3
chemical synthesis (3) 3
chemistry, applied (3) 3
continuous-flow (3) 3
copper-mediated difluoromethylation (3) 3
cucf3 (3) 3
efficient precursor (3) 3
efficient synthesis (3) 3
generation (3) 3
kohlenstoff (3) 3
kontinuierliche strömung (3) 3
methylation (3) 3
n-substituted isatoic anhydrides (3) 3
nucleophilic difluoromethylation (3) 3
organofluorine compounds (3) 3
reaction-condition (3) 3
reaktionsbedingung (3) 3
siladifluoromethylation (3) 3
terminal alkynes (3) 3
thiols (3) 3
tmscf3 (3) 3
acetates (2) 2
acids (2) 2
active-pharmaceutical-ingredients (2) 2
agrochemicals (2) 2
alcohols (2) 2
alkene (2) 2
alkynes (2) 2
alpha,beta-unsaturated carboxylic-acids (2) 2
amino-acids (2) 2
aminosäuren (2) 2
analogs (2) 2
anion (2) 2
anions (2) 2
aromatic compounds (2) 2
aryl iodides (2) 2
arzneilich wirksamer bestandteil (2) 2
base (2) 2
bearing (2) 2
bicyclic compounds (2) 2
biological activity (2) 2
boronic acids (2) 2
carboxylic acids (2) 2
centers (2) 2
chemical sciences (2) 2
continuous flow (2) 2
convenient synthesis (2) 2
coupling reactions (2) 2
cuprates (2) 2
difluoromethyl thioethers (2) 2
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Chemistry – An Asian Journal, ISSN 1861-4728, 11/2017, Volume 12, Issue 21, pp. 2794 - 2798
Journal Article
Journal of Fluorine Chemistry, ISSN 0022-1139, 12/2015, Volume 180, pp. 186 - 191
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 08/2016, Volume 2016, Issue 23, pp. 4099 - 4104
Journal Article
Synthesis, ISSN 0039-7881, 08/2017, Volume 49, Issue 15, pp. 3394 - 3406
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 03/2014, Volume 20, Issue 10, pp. 2750 - 2754
Journal Article
Beilstein Journal of Organic Chemistry, ISSN 1860-5397, 11/2013, Volume 9, Issue 1, pp. 2404 - 2409
The trifluoromethylation of aryl iodides catalyzed by copper(I) salt with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide and Zn dust... 
Trifluoromethyl | Ruppert-Prakash reagent | Organo-fluorine | Trifluoromethylation | Trifluoromethyl zinc | NUCLEOPHILIC TRIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | CUCF3 | trifluoromethyl | COPPER | FLUORINATION | OXIDATIVE TRIFLUOROMETHYLATION | PERFLUOROALKYLATION | trifluoromethylation | FLUOROFORM | organo-fluorine | trifluoromethyl zinc | Ruppert–Prakash reagent
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2011, Volume 50, Issue 31, pp. 7153 - 7157
Journal Article
Mendeleev Communications, ISSN 0959-9436, 07/2015, Volume 25, Issue 4, pp. 239 - 244
α-Fluorinated organosilanes Me3SiCF2X serve as versatile reagents for the synthesis of organofluorine compounds. Most reactions start from Lewis base... 
NUCLEOPHILIC TRIFLUOROMETHYLATION | DIFLUOROMETHYLATION | DIFLUOROCARBENE | TRIFLUOROMETHYLTRIMETHYLSILANE | RUPPERT-PRAKASH REAGENT | IMINES | DIFLUOROHOMOLOGATION | FLUOROALKYLATION | CARBONYL-COMPOUNDS | 1ST EXAMPLE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of Fluorine Chemistry, ISSN 0022-1139, 12/2015, Volume 180, pp. 186 - 191
Direct S-difluoromethylation of aryl and aliphatic thiols using the Ruppert-Prakash reagent is demonstrated. The reaction produces trimethylsilyldifluoromethyl... 
Difluoromethyl thioethers | RSCF | Ruppert-Prakash reagent | Thiols | Difluoromethylation | Nucleophilic (arylsulfanyl)difluoromethylation | TMS | TMSCF | Siladifluoromethylation
Journal Article
Tetrahedron, ISSN 0040-4020, 09/2015, Volume 71, Issue 38, pp. 6824 - 6831
Utilization of a mixed solvent system of DMF/HMPA=1/1 (v/v) to the KF/CuI/TMSCF3 reagent system proved to significantly affect the reaction, realizing... 
Trifluoromethyl copper reagents | Trifluoromethylation | Iodopyridinone | Ruppert–Prakash reagent | Hexamethylphospholic triamide | Ruppert-Prakash reagent | ACIDS | ARENES | CHEMISTRY, ORGANIC | CUCF3 | PERFLUOROALKYLATION | SELECTIVE TRIFLUOROMETHYLATION | COPPER REAGENT | POTENT | LIGANDS | ARYL IODIDES | EFFICIENT
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 10/2016, Volume 2016, Issue 29, pp. 4965 - 4969
A deoxygenative difluoromethylenation of carbonyl compounds has been developed by using readily available, inexpensive trifluoromethyltrimethylsilane, LiI, and... 
Ketones | Aldehydes | Fluorine | Olefination | Ruppert–Prakash reagent | Ylides | Ruppert-Prakash reagent | ANALOGS | GEM-DIFLUOROOLEFINATION | CHEMISTRY, ORGANIC | INHIBITORS
Journal Article