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Journal of the American Chemical Society, ISSN 0002-7863, 02/2019, Volume 141, Issue 6, pp. 2257 - 2262
A Negishi cross-coupling of alkylpyridinium salts and alkylzinc halides has been developed. This is the first example of alkyl-alkyl bond formation via... 
BORONIC ACIDS | AMINO-GROUPS | ESTERS | BOND FUNCTIONALIZATION | SECONDARY | ARYL | PYRIDINIUM SALTS | BENZYLIC AMMONIUM-SALTS | CHEMISTRY, MULTIDISCIPLINARY | NICKEL-CATALYZED BORYLATION | CARBOXYLIC-ACIDS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2014, Volume 136, Issue 27, pp. 9521 - 9523
The use of low-cost iron­(III) acetoacetate (Fe­(acac)3) and tetra­methyl­ethylene­diamine (TMEDA) enables the direct cross-coupling of alkyl halides with... 
HALIDES | PALLADIUM | REAGENTS | CROSS-COUPLING REACTION | ESTERS | SECONDARY | ARYL | CHEMISTRY, MULTIDISCIPLINARY | Esters - chemistry | Ferric Compounds - chemistry | Boronic Acids - chemistry | Molecular Structure | Catalysis | Boronic Acids - chemical synthesis | Esters - chemical synthesis | Hydrocarbons, Halogenated - chemistry | Boron | Iron | Chemical properties | Research
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 01/2020, Volume 22, Issue 2, pp. 666 - 669
A catalytic conjunctive cross-coupling reaction is developed that allows the construction of chiral organoboronic esters from alkylboron ate complexes and... 
SECONDARY | CHEMISTRY, ORGANIC | AMINATION | ASYMMETRIC-SYNTHESIS | BORON | ALKALOIDS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2016, Volume 55, Issue 5, pp. 1849 - 1853
Journal Article
Organic Chemistry Frontiers, ISSN 2052-4110, 10/2015, Volume 2, Issue 10, pp. 1411 - 1421
The formation of C-C bonds directly by catalytic reductive cross-coupling of two different electrophiles represents one of the practical synthetic protocols... 
CROSS-COUPLINGS | UNACTIVATED TERTIARY ALKYL | ARYL HALIDES | KETONE FORMATION | SECONDARY | CHEMISTRY, ORGANIC | ORGANIC HALIDES | CARBOXYLATION | BROMIDES | GRIGNARD-REAGENTS | TOSYLATES
Journal Article
ACS Catalysis, ISSN 2155-5435, 07/2017, Volume 7, Issue 7, pp. 4697 - 4706
Transition metal-catalyzed cross-coupling reactions have created an epoch in modern synthetic organic chemistry, offering a variety of insights into... 
alkyl electrophiles | cross-coupling | catalysis | single-electron transfer | radicals | UNACTIVATED SECONDARY | NUCLEOPHILIC-SUBSTITUTION | SILICON | C-S | CHEMISTRY, PHYSICAL | PHOTOSENSITIZED DECARBOXYLATION | COPPER | CARBON BOND FORMATION | AMINATION | ORGANIC HALIDES | REDOX-ACTIVE ESTERS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2016, Volume 138, Issue 43, pp. 14222 - 14225
A copper-catalyzed C­(sp3)–Si cross-coupling of aliphatic C­(sp3)–I electrophiles using a Si–B reagent as the silicon pronucleophile is reported. The reaction... 
HALIDES | AUXILIARY BASIS-SETS | ROUTE | B BOND ACTIVATION | SILANES | ZETA VALENCE QUALITY | SECONDARY | ALLYLIC SUBSTITUTION | CHEMISTRY, MULTIDISCIPLINARY | SILYLATION | BORYLATION | Usage | Analysis | Chemical bonds | Silicon | Chemical properties | Ring formation (Chemistry) | Research | Electrophiles
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 09/2019, Volume 141, Issue 37, pp. 14864 - 14869
Transition-metal catalysis has the potential to address shortcomings in the classic S(N)2 reaction of an amine with an alkyl electrophile, both with respect to... 
HALIDES | SECONDARY | COUPLINGS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 05/2017, Volume 19, Issue 10, pp. 2536 - 2539
A Ni-catalyzed reductive cross-coupling reaction between two electrophiles, amides and aryl iodides, has been developed. This work is the first example using... 
HALIDES | FUNCTIONALIZATION | PALLADIUM | KETONE SYNTHESIS | SECONDARY ALKYL BROMIDES | NICKEL CATALYSIS | ESTERS | COMPLEXES | CHLORIDES | CHEMISTRY, ORGANIC | CLEAVAGE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2017, Volume 139, Issue 39, pp. 13929 - 13935
A highly efficient strategy for remote reductive cross-electrophile coupling has been developed through the ligand-controlled nickel migration/arylation. This... 
ARYL BROMIDES | HALIDES | NUCLEOPHILES | CATALYSIS | ALKENE ISOMERIZATION-HYDROBORATION | SECONDARY ALKYL ELECTROPHILES | NICKEL | NEGISHI ARYLATIONS | CARBOXYLATION | H BOND FUNCTIONALIZATION | CHEMISTRY, MULTIDISCIPLINARY | Arylation | Ligands | Usage | Research | Electrophiles
Journal Article
by Duan, JC and Du, YF and Pang, XB and Shu, XZ
CHEMICAL SCIENCE, ISSN 2041-6520, 10/2019, Volume 10, Issue 37, pp. 8706 - 8712
We report here the coupling reactions between vinyl/aryl and alkyl C-O electrophiles that can be derived from chemical feedstocks and naturally occurring... 
FUNCTIONALIZATION | TERTIARY ALKYL | METALLAPHOTOREDOX CATALYSIS | NICKEL | ARYL HALIDES | ESTERS | SECONDARY | CO-CATALYSIS | OXIDATIVE ADDITION | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
ACS CATALYSIS, ISSN 2155-5435, 01/2020, Volume 10, Issue 1, pp. 36 - 42
The nickel-catalyzed carbonylation of aliphatic electrophiles with the most straightforward CO remains challenging. Here, we describe an example of the... 
nickel | BIMETALLIC OXIDATIVE ADDITION | CHEMISTRY, PHYSICAL | alkyl ketones | ELIMINATION | IODIDES | ALLYL HALIDES | secondary aliphatic electrophiles | CARBON-MONOXIDE | BONDS | FLUORINE | ARYL | CARBOXYLATION | carbonylation | ALKYL BROMIDES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2016, Volume 138, Issue 19, pp. 6139 - 6142
The use of low-cost manganese­(II) bromide (MnBr2) and tetramethyl­ethylene­diamine (TMEDA) catalyzes the cross coupling of (bis)­pinacolato­diboron with a... 
HALIDES | PALLADIUM | SUBSTITUTION | REAGENTS | CROSS-COUPLING REACTION | SECONDARY | ALKYLBORONIC ESTERS | ELECTROPHILES | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | ARYL CHLORIDES | Chemical properties | Catalysis | Chemical compounds | Analysis
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2018, Volume 8, Issue 1, pp. 310 - 313
1,1-Diarylalkanes are important structural frameworks which are widespread in biologically active molecules. Herein, we report a reductive relay cross-coupling... 
alkyl electrophiles | high-valent nickel | 1,1-diarylalkanes | migratory cross-coupling | β-hydride elimination | HALIDES | HYDROCARBONS | NEGISHI ARYLATIONS | UNACTIVATED TERTIARY ALKYL | SECONDARY | CHEMISTRY, PHYSICAL | FUNCTIONALIZATION | beta-hydride elimination | STEREOCENTERS | CARBOXYLATION | REMOTE | ELECTROPHILES
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 12/2018, Volume 140, Issue 50, pp. 17433 - 17438
A strategy for the installation of small alkyl fragments onto pharmaceutically relevant aliphatic structures has been established via metallaphotoredox... 
NUCLEOPHILES | NICKEL | PHOTOREDOX | GROUP ISOMERIZATION | ARYL HALIDES | COMPLEXES | SECONDARY ALKYL-HALIDES | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS | NEGISHI REACTIONS | TOSYLATES
Journal Article
ADVANCED SYNTHESIS & CATALYSIS, ISSN 1615-4150, 10/2018, Volume 360, Issue 19, pp. 3667 - 3671
Diverse alkenylboronic acids react smoothly with various sp(3)-carbon electrophiles such as unactivated alkyl triflates in the presence of mild bases such as... 
ORGANOBORON COMPOUNDS | ROOM-TEMPERATURE | PALLADIUM | SUZUKI CROSS-COUPLINGS | COMPLEXES | alkenylboronic acids | CHEMISTRY, ORGANIC | sp-carbon electrophiles | BROMIDES | TERTIARY BORONIC ESTERS | SECONDARY ALKYL ELECTROPHILES | cross-coupling | CHEMISTRY, APPLIED | Transition metal-free | GRIGNARD-REAGENTS | BENZYL HALIDES
Journal Article
Organic Letters, ISSN 1523-7060, 12/2014, Volume 16, Issue 24, pp. 6342 - 6345
The first copper-catalyzed/promoted sp3-C Suzuki–Miyaura coupling reaction of gem-diborylalkanes with nonactivated electrophilic reagents is reported. Not only... 
ORGANOBORON COMPOUNDS | FUNCTIONALIZATION | ROOM-TEMPERATURE | CONSTRUCTION | SECONDARY | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | SUZUKI REACTIONS | BROMIDES | ELECTROPHILES | BORYLATION | Boron Compounds - chemistry | Copper - chemistry | Cross-Linking Reagents - chemistry | Esters | Molecular Structure | Catalysis | Hydrocarbons, Halogenated - chemistry
Journal Article
Helvetica Chimica Acta, ISSN 0018-019X, 11/2016, Volume 99, Issue 11, pp. 830 - 847
A new series of Ni NNN pincer complexes were synthesized and characterized. The main difference among these complexes is the substituents on the side arm amino... 
Nickel | Pincer ligands | Cross‐coupling reaction | Alkyl halides | Structure–activity study | Cross-coupling reaction | HALIDES | Structure-activity study | BOND-FORMING REACTIONS | SECONDARY | CHEMISTRY, MULTIDISCIPLINARY | NUCLEOPHILES | CROSS-COUPLINGS | ELECTROPHILES | GRIGNARD-REAGENTS | CATALYSTS | Halides
Journal Article
Organic Letters, ISSN 1523-7060, 05/2017, Volume 19, Issue 10, pp. 2614 - 2617
The stereoselective borylative radical cyclization of alkyl halides containing an alkene moiety was developed using a copper­(I)/diboron catalyst system. The... 
SUBSTITUTION | ROUTE | BROMOACETALS | IODIDES | SECONDARY | CHEMISTRY, ORGANIC | BIOLOGICAL-ACTIVITIES | CATALYST | ELECTROPHILES | DERIVATIVES | RING-CLOSURE
Journal Article
Organic Letters, ISSN 1523-7060, 08/2018, Volume 20, Issue 15, pp. 4677 - 4680
This work illustrates a reductive cross-electrophile coupling protocol for trifluoromethylation of alkyl iodides under Cucatalyzed/Ni-promoted reaction... 
CROSS-COUPLING REACTIONS | DECARBOXYLATIVE TRIFLUOROMETHYLATION | COMPLEXES | SECONDARY | CHEMISTRY, ORGANIC | ORGANIC HALIDES | FLUORINATION | ALKYLBORONIC ESTERS | ELECTROPHILES | BROMIDES | BORYLATION
Journal Article
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