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Organic Letters, ISSN 1523-7060, 01/2018, Volume 20, Issue 2, pp. 357 - 360
The efficient Pd-catalyzed Heck reaction of diverse tertiary alkyl halides with alkenes has been developed. Unactivated tertiary alkyl halides efficiently... 
FUNCTIONALIZATION | CATALYSIS | ALKENES | C-H ARYLATION | VISIBLE-LIGHT PHOTOREDOX | BONDS | SECONDARY | CHEMISTRY, ORGANIC | BORONIC ESTERS | ARYL | ALKENYLATION | Alkenes - chemistry | Molecular Structure | Catalysis | Carbon
Journal Article
Chemical Communications, ISSN 1359-7345, 04/2014, Volume 50, Issue 28, pp. 3725 - 3728
Intermolecular Heck reaction of common alkyl halides, a long-standing problem in palladium catalysis, is realized with a simple Pd/dppf catalyst. Both primary... 
RADICAL ALKENYLATION | BENZYL | OLEFINATION | COUPLING REACTIONS | SECONDARY | ORGANIC HALIDES | ARYL | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | SIMPLE ALKENES | CYCLIZATION
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 03/2014, Volume 50, Issue 28, pp. 3725 - 3728
Intermolecular Heck reaction of common alkyl halides, a longstanding problem in palladium catalysis, is realized with a simple Pd/dppf catalyst. Both primary... 
Catalysts | Halides | Olefins | Palladium | Coupling | Catalysis | Single electrons | Radicals
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2015, Volume 137, Issue 36, pp. 11562 - 11565
A mild Ni-catalyzed reductive arylation of tertiary alkyl halides with aryl bromides has been developed that delivers products bearing all-carbon quaternary... 
CONCISE TOTAL-SYNTHESIS | ALPHA-ARYLATION | KETONE FORMATION | ALLYLATION | UNACTIVATED PRIMARY | SECONDARY | ORGANIC HALIDES | CARBOXYLATION | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS | TOSYLATES | Arylation | Usage | Chemical properties | Metal catalysts | Halides | Isomerization
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2018, Volume 140, Issue 43, pp. 14490 - 14497
This work illustrates the reductive coupling of electron-rich aryl halides with tertiary alkyl halides under Ni-catalyzed cross-electrophile coupling... 
NUCLEOPHILES | CONCISE TOTAL-SYNTHESIS | PHOTOREDOX | TRANSMETALATION | CARBON QUATERNARY STEREOCENTERS | CONSTRUCTION | SECONDARY | DIMERIZATION | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 07/2019, Volume 60, Issue 27, pp. 1792 - 1795
The Cu-catalyzed regioselective alkylation of heteroarenes with functionalized primary, secondary, and tertiary alkyl halides is reported. The reaction... 
Radical chemistry | Copper-catalyzed | Alkylation | Heteroarenes | C-H ALKYLATION | HECK-TYPE ALKENYLATION | SECONDARY | CHEMISTRY, ORGANIC | N-OXIDES | COUMARINS | ETHERS | HETEROCYCLES | RADICAL CYCLIZATION | DIRECT C2-ALKYLATION | EFFICIENT | Copper | Halides
Journal Article
Organic Chemistry Frontiers, ISSN 2052-4110, 10/2015, Volume 2, Issue 10, pp. 1411 - 1421
The formation of C-C bonds directly by catalytic reductive cross-coupling of two different electrophiles represents one of the practical synthetic protocols... 
CROSS-COUPLINGS | UNACTIVATED TERTIARY ALKYL | ARYL HALIDES | KETONE FORMATION | SECONDARY | CHEMISTRY, ORGANIC | ORGANIC HALIDES | CARBOXYLATION | BROMIDES | GRIGNARD-REAGENTS | TOSYLATES
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 12/2015, Volume 17, Issue 24, pp. 6074 - 6077
Novel and general copper-catalyzed cyclopropanol ring opening cross-coupling reactions with difluoroalkyl bromides, perfluoroalkyl iodides, monofluoroalkyl... 
ETHYL BROMODIFLUOROACETATE | MEDIATED DIFLUOROMETHYLATION | ARYL BORONIC ACIDS | ALPHA-ARYLATION | SECONDARY | CHEMISTRY, ORGANIC | GENERAL-APPROACH | SILYL ETHERS | BROMIDES | ALKYL-HALIDES | TRIFLUOROMETHYLATION
Journal Article
Chemical Science, ISSN 2041-6520, 10/2013, Volume 4, Issue 10, pp. 4022 - 4029
The use of bis(pinacolato)diboron as the terminal reductant allows the efficient Ni-catalyzed coupling of unactivated secondary and primary alkyl halides,... 
KETONE FORMATION | SECONDARY | CHLORIDES | SUZUKI REACTIONS | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | GRIGNARD-REAGENTS | FUNCTIONALIZED PRIMARY | NEGISHI REACTIONS | TOSYLATES | Catalysts | Halides | Bromides | Joining | Nickel | Tolerances | Terminals | Catalysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2013, Volume 135, Issue 26, pp. 9604 - 9607
Journal Article
Organic Letters, ISSN 1523-7060, 05/2017, Volume 19, Issue 10, pp. 2614 - 2617
The stereoselective borylative radical cyclization of alkyl halides containing an alkene moiety was developed using a copper­(I)/diboron catalyst system. The... 
SUBSTITUTION | ROUTE | BROMOACETALS | IODIDES | SECONDARY | CHEMISTRY, ORGANIC | BIOLOGICAL-ACTIVITIES | CATALYST | ELECTROPHILES | DERIVATIVES | RING-CLOSURE
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 05/2015, Volume 51, Issue 47, pp. 9655 - 9658
The selective boryl substitution of alkyl halides bearing terminal C&z.dbd; C double bonds has been achieved using a copper(i)/tricyclohexylphosphine or... 
Hydroboration | Alkenes | Catalysts | Halides | Olefins | Chemical bonds | Terminals | Bonding | Bearing
Journal Article
Tetrahedron, ISSN 0040-4020, 09/2018, Volume 74, Issue 39, pp. 5651 - 5658
The nickel catalyzed reductive coupling of allylic carbonates with chloro-cyclotryptamine analogs to construct sterically congested all C(sp ) quaternary... 
Extension | Dienyl carbonate | Chloro-cyclotryptamine | Nickel catalyzed | Allylation | HETEROCYCLIC COMPOUND | SECONDARY | BENZYLATION | CHEMISTRY, ORGANIC | TUMOR-CELLS | 5-N-ACETYLARDEEMIN | TOSYLATES | CONSTRUCTION | MULTIPLE-DRUG RESISTANCE | GRIGNARD-REAGENTS | Halides | Nickel | Carbonates
Journal Article
Organic Letters, ISSN 1523-7060, 11/2016, Volume 18, Issue 22, pp. 5848 - 5851
An efficient methodology has been developed for the one-pot or telescoped synthesis of aliphatic sulfonamides, sulfonyl fluorides, and unsymmetrical sulfones... 
REAGENTS | CATALYZED SYNTHESIS | SECONDARY | CHEMISTRY, ORGANIC | ARYL | DERIVATIVES | DABSO
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2015, Volume 137, Issue 11, pp. 3731 - 3734
A catalytic C–H alkylation using unactivated alkyl halides and a variety of arenes and heteroarenes is described. This ring-forming process is successful with... 
FUNCTIONALIZATION | IODIDES | SUBSTITUTION | CONVERGENT APPROACH | RADICAL CYCLIZATION | ARENES | BONDS | SECONDARY | CHEMISTRY, MULTIDISCIPLINARY | HECK-TYPE REACTIONS | Iodides - chemistry | Molecular Structure | Catalysis | Palladium - chemistry | Bromides - chemistry | Alkylation | Palladium catalysts | Chemical bonds | Chemical properties | Research
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2017, Volume 56, Issue 42, pp. 13103 - 13106
The construction of all C(sp3) quaternary centers has been successfully achieved under Ni‐catalyzed cross‐electrophile coupling of allylic carbonates with... 
quaternary carbon centers | nickel | allylation | tertiary alkyl halides | electrophiles | ALLYLNICKEL COMPLEXES | SECONDARY | BENZYLATION | ENANTIOSELECTIVE CONSTRUCTION | CHEMISTRY, MULTIDISCIPLINARY | TOSYLATES | ARYL BROMIDES | CROSS-COUPLING REACTIONS | ORGANIC HALIDES | GRIGNARD-REAGENTS | Halides | Nickel | Carbonates | Regioselectivity | Quaternary | Chemical reactions | Allyl compounds | Alkylation
Journal Article
Organic Letters, ISSN 1523-7060, 12/2014, Volume 16, Issue 24, pp. 6342 - 6345
The first copper-catalyzed/promoted sp3-C Suzuki–Miyaura coupling reaction of gem-diborylalkanes with nonactivated electrophilic reagents is reported. Not only... 
ORGANOBORON COMPOUNDS | FUNCTIONALIZATION | ROOM-TEMPERATURE | CONSTRUCTION | SECONDARY | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | SUZUKI REACTIONS | BROMIDES | ELECTROPHILES | BORYLATION | Boron Compounds - chemistry | Copper - chemistry | Cross-Linking Reagents - chemistry | Esters | Molecular Structure | Catalysis | Hydrocarbons, Halogenated - chemistry
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2008, Volume 130, Issue 34, pp. 11276 - 11277
Cobalt-catalyzed reactions of haloalkanes with dimethylphenylsilylmethylmagnesium chloride result in highly regioselective dehydrohalogenation. The reaction... 
PRELIGANDS | SODIUM METHOXIDE | METHANOL | ORIENTATION | KINETICS | SECONDARY | ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | LEAVING GROUPS | BASE | Chemical properties | Structure | Cobalt | Magnesium compounds
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2016, Volume 6, Issue 1, pp. 258 - 261
Replacement of a dimethyl amino group of the amidobis­(amine) nickel­(II) pincer complex (1), [(MeN2N)­Ni–Cl], by a pyrrolidino group resulted in a new... 
Kumada coupling | nickel | secondary alkyl halide | pincer ligands | Suzuki-Miyaura coupling | PALLADIUM | ARYLATIONS | PSEUDOHALIDES | BOND-FORMING REACTIONS | CHEMISTRY, PHYSICAL | TERMINAL ALKYNES | CATALYZED DIRECT ALKYLATION | TOSYLATES | Suzuki-Miyaura coupling secondary alkyl halide | ELECTROPHILES | GRIGNARD-REAGENTS
Journal Article
Tetrahedron, ISSN 0040-4020, 2009, Volume 65, Issue 31, pp. 6257 - 6262
Various benzylic halides were smoothly and directly converted into the corresponding aromatic nitriles in high yields using molecular iodine and... 
Benzylic halide | Aromatic nitrile | 1,3-Diiodo-5,5-dimethylhydantoin | Aliphatic nitrile | Aq ammonia | Alkyl halide | Molecular iodine | 2-IMIDAZOLINES | COPPER-CATALYZED OXIDATION | LEAD TETRAACETATE | SECONDARY | CHEMISTRY, ORGANIC | HYPOCHLORITE | ALCOHOLS | OXYGEN | DEHYDROGENATION | PRIMARY AMINES | SYNTHETIC USE | Ammonia | Nitriles | Halides | Nitrites
Journal Article
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