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Journal of the American Chemical Society, ISSN 0002-7863, 07/2013, Volume 135, Issue 26, pp. 9604 - 9607
Journal Article
Organic Letters, ISSN 1523-7060, 05/2017, Volume 19, Issue 10, pp. 2614 - 2617
The stereoselective borylative radical cyclization of alkyl halides containing an alkene moiety was developed using a copper­(I)/diboron catalyst system. The... 
SUBSTITUTION | ROUTE | BROMOACETALS | IODIDES | SECONDARY | CHEMISTRY, ORGANIC | BIOLOGICAL-ACTIVITIES | CATALYST | ELECTROPHILES | DERIVATIVES | RING-CLOSURE
Journal Article
Tetrahedron, ISSN 0040-4020, 01/2014, Volume 70, Issue 2, pp. 212 - 217
An efficient Cu-catalyzed Csp3–O coupling of peroxides with haloalkanes is described. High yields of products were achieved under mild conditions.... 
Aryl–alkyl esters | Copper-catalyzed | Csp3–O coupling | Organic peroxides | Secondary alkyl halides | Aryl-alkyl esters | O coupling | Cross coupling | Halides | Tetrahedrons | Hydrocarbons | Halogenated | Joining | Peroxides
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 05/2015, Volume 51, Issue 47, pp. 9655 - 9658
The selective boryl substitution of alkyl halides bearing terminal C&z.dbd; C double bonds has been achieved using a copper(i)/tricyclohexylphosphine or... 
Hydroboration | Alkenes | Catalysts | Halides | Olefins | Chemical bonds | Terminals | Bonding | Bearing
Journal Article
RSC Advances, 05/2017, Volume 7, Issue 40, pp. 24652 - 24656
The C(sp3)-P bond is formed via the reaction between P-H compounds and non-activated alkyl electrophiles, especially secondary alkyl halides and tosylates.... 
Chemical bonds | Halides | Bonding | Inversions | Alcohols
Journal Article
Tetrahedron, ISSN 0040-4020, 09/2018, Volume 74, Issue 39, pp. 5651 - 5658
The nickel catalyzed reductive coupling of allylic carbonates with chloro-cyclotryptamine analogs to construct sterically congested all C(sp3) quaternary... 
Extension | Dienyl carbonate | Chloro-cyclotryptamine | Nickel catalyzed | Allylation | HETEROCYCLIC COMPOUND | SECONDARY | BENZYLATION | CHEMISTRY, ORGANIC | TUMOR-CELLS | 5-N-ACETYLARDEEMIN | TOSYLATES | CONSTRUCTION | MULTIPLE-DRUG RESISTANCE | GRIGNARD-REAGENTS | Halides | Nickel | Carbonates
Journal Article
Organic Letters, ISSN 1523-7060, 11/2016, Volume 18, Issue 22, pp. 5848 - 5851
An efficient methodology has been developed for the one-pot or telescoped synthesis of aliphatic sulfonamides, sulfonyl fluorides, and unsymmetrical sulfones... 
REAGENTS | CATALYZED SYNTHESIS | SECONDARY | CHEMISTRY, ORGANIC | ARYL | DERIVATIVES | DABSO
Journal Article
Advanced Synthesis and Catalysis, ISSN 1615-4150, 12/2018, Volume 360, Issue 24, pp. 4699 - 4704
A general continuous-flow procedure for direct reductive amination of secondary and primary amines with aromatic and aliphatic aldehydes as well as ketones is... 
C−N bond formation | heterogeneous catalysis | reductive amination | flow chemistry | flow fine synthesis | C-N bond formation | HYDROGENATION | REGENERATION | DIOXIDE | CHEMISTRY, ORGANIC | ALIPHATIC-KETONES | ALDEHYDES | SULFUR | CHEMISTRY, APPLIED | SECONDARY-AMINES | PT/C
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 12/2018, Volume 360, Issue 24, pp. 4699 - 4704
A general continuous‐flow procedure for direct reductive amination of secondary and primary amines with aromatic and aliphatic aldehydes as well as ketones is... 
C−N bond formation | reductive amination | heterogeneous catalysis | flow chemistry | flow fine synthesis | Carbonyl compounds | Hazardous wastes | Amines | Ketones | Catalysts | Aldehydes | Alkylation | Continuous flow | Aliphatic compounds | Organic chemistry | Halides | Direct reduction | Catalysis | Chemical synthesis | Functional groups | Carbonyls
Journal Article
Chinese Journal of Organic Chemistry, ISSN 0253-2786, 09/2015, Volume 35, Issue 9, pp. 1820 - 1833
Recently, great attention has been directed to the transition-metal-catalyzed cross-coupling reactions of non-activated alkyl halides for the construction of... 
Transition-metal | Cross-coupling | Advance | Catalyze | Non-activated alkyl halide | ORGANOBORON COMPOUNDS | ROOM-TEMPERATURE | SECONDARY | CHEMISTRY, ORGANIC | ALPHA-AMINO-ACIDS | BETA-HYDROGENS | ALKYLBORONIC ESTERS | transition-metal | C-H BONDS | catalyze | advance | BORONIC ACIDS | non-activated alkyl halide | cross-coupling | SUZUKI REACTIONS | GRIGNARD-REAGENTS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2008, Volume 130, Issue 34, pp. 11276 - 11277
Cobalt-catalyzed reactions of haloalkanes with dimethylphenylsilylmethylmagnesium chloride result in highly regioselective dehydrohalogenation. The reaction... 
PRELIGANDS | SODIUM METHOXIDE | METHANOL | ORIENTATION | KINETICS | SECONDARY | ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | LEAVING GROUPS | BASE | Chemical properties | Structure | Cobalt | Magnesium compounds
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2016, Volume 6, Issue 1, pp. 258 - 261
Replacement of a dimethyl amino group of the amidobis­(amine) nickel­(II) pincer complex (1), [(MeN2N)­Ni–Cl], by a pyrrolidino group resulted in a new... 
Kumada coupling | nickel | secondary alkyl halide | pincer ligands | Suzuki-Miyaura coupling | PALLADIUM | ARYLATIONS | PSEUDOHALIDES | BOND-FORMING REACTIONS | CHEMISTRY, PHYSICAL | TERMINAL ALKYNES | CATALYZED DIRECT ALKYLATION | TOSYLATES | Suzuki-Miyaura coupling secondary alkyl halide | ELECTROPHILES | GRIGNARD-REAGENTS
Journal Article
Tetrahedron, ISSN 0040-4020, 2009, Volume 65, Issue 31, pp. 6257 - 6262
Various benzylic halides were smoothly and directly converted into the corresponding aromatic nitriles in high yields using molecular iodine and... 
Benzylic halide | Aromatic nitrile | 1,3-Diiodo-5,5-dimethylhydantoin | Aliphatic nitrile | Aq ammonia | Alkyl halide | Molecular iodine | 2-IMIDAZOLINES | COPPER-CATALYZED OXIDATION | LEAD TETRAACETATE | SECONDARY | CHEMISTRY, ORGANIC | HYPOCHLORITE | ALCOHOLS | OXYGEN | DEHYDROGENATION | PRIMARY AMINES | SYNTHETIC USE | Ammonia | Nitriles | Halides | Nitrites
Journal Article
Chemical Communications, ISSN 1359-7345, 12/2005, Issue 46, pp. 5772 - 5774
sp(3) Hybridized electrophiles, never before used in the organo-mediated Morita-Baylis-Hillman reaction, now facilitate the formation of five- and six-membered... 
THIOLS | MICHAEL CYCLOISOMERIZATION | SCOPE | 1,4-PENTADIENES | ALDEHYDES | SECONDARY-AMINES | CHEMISTRY, MULTIDISCIPLINARY | METATHESIS | NUCLEOPHILIC CATALYSIS | PARTNERS
Journal Article
Chemical Communications, ISSN 1359-7345, 10/2013, Volume 49, Issue 94, pp. 11101 - 11103
A cross-coupling reaction between alkyl bromides and chlorides and various Grignard reagents was carried out in the presence of commercially available copper... 
CARBON BOND FORMATION | SECONDARY | ORGANIC HALIDES | FUNCTIONAL-GROUP | ARYL | NICKEL-PHOSPHINE COMPLEXES | TERTIARY | CHEMISTRY, MULTIDISCIPLINARY | TOSYLATES | 1,3-BUTADIENES | HALIDES | REAGENTS | PARTICLES | Nanomaterials | COMPOSITES | Tolerances | Nanostructure | COPPER OXIDE | Nanoparticles | MICROSTRUCTURES | Nanocomposites | Copper | CATALYSTS | Alkynes
Journal Article
Chinese Journal of Organic Chemistry, ISSN 0253-2786, 03/2019, Volume 39, Issue 3, pp. 734 - 746
Nano-gold catalyzed transesterification of the (hetero)aryl ester with alkyl halides via C-O activation has been developed. In a series of supported AuNPs and... 
Halide | Nano-gold catalyst | Transesterification | FREE SELECTIVE OXIDATION | ONE-POT | CHEMISTRY, ORGANIC | ENHANCED ACTIVITY | UNACTIVATED ALKYL | CROSS-COUPLING REACTIONS | EFFICIENT CATALYST | LIQUID-PHASE OXIDATION | transesterification | halide | AEROBIC OXIDATION | nano-gold catalyst | SECONDARY-AMINES | MOLECULAR-OXYGEN
Journal Article
by Chen, HH and Wang, GZ and Han, J and Xu, MY and Zhao, YQ and Xu, HJ
TETRAHEDRON, ISSN 0040-4020, 01/2014, Volume 70, Issue 2, pp. 212 - 217
An efficient Cu-catalyzed C-sp3-O coupling of peroxides with haloalkanes is described. High yields of products were achieved under mild conditions.... 
C-sp3-O coupling | ACTIVATION | Copper-catalyzed | CARBOXYLATES | Organic peroxides | MECHANISM | ESTERIFICATION | CHEMISTRY, ORGANIC | C-H BONDS | ALKENES | Secondary alkyl halides | Aryl alkyl esters | PROMOTED INTRAMOLECULAR CARBOAMINATION | ESTERS | DERIVATIVES | ARTEMISININ
Journal Article
SYNTHESIS-STUTTGART, ISSN 0039-7881, 06/2014, Volume 46, Issue 12, pp. 1583 - 1592
The cross-coupling of alkyl (pseudo)halides with alkyl Grignard reagents is catalyzed efficiently by a cobalt(II) chloride-lithium iodide-1,3-diene catalytic... 
GROUP ISOMERIZATION | COMPLEXES | SECONDARY | CHEMISTRY, ORGANIC | Grignard reagents | BOND FORMATION | cobalt | TOSYLATES | NICKEL | alkyl halides | 1,3-BUTADIENE | quaternary carbon | cross-coupling | 6-HALO-1-HEXENE DERIVATIVES | ORGANIC HALIDES | CATALYSTS
Journal Article
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