X
Search Filters
Format Format
Format Format
X
Sort by Item Count (A-Z)
Filter by Count
Journal Article (588) 588
Publication (50) 50
Book Chapter (17) 17
Book / eBook (10) 10
Book Review (7) 7
Dissertation (6) 6
Conference Proceeding (5) 5
Paper (1) 1
more...
Subjects Subjects
Subjects Subjects
X
Sort by Item Count (A-Z)
Filter by Count
chemistry, organic (224) 224
chemistry, multidisciplinary (175) 175
secondary phosphine oxides (164) 164
catalysis (120) 120
ligands (116) 116
chemistry, inorganic & nuclear (90) 90
chemistry (77) 77
index medicus (72) 72
palladium (71) 71
complexes (66) 66
secondary alcohols (65) 65
oxides (60) 60
derivatives (59) 59
secondary (57) 57
catalysts (53) 53
chemistry, physical (51) 51
alcohols (49) 49
secondary phosphines (47) 47
phosphorus (46) 46
ligand (45) 45
synthesis (45) 45
hydrogenation (44) 44
cross-coupling reactions (43) 43
organic chemistry (40) 40
reduction (40) 40
amines (38) 38
oxidation (38) 38
enantioselective synthesis (33) 33
chemical sciences (32) 32
protein structure, secondary (32) 32
aldehydes (31) 31
asymmetric catalysis (31) 31
analysis (29) 29
phosphine oxide (29) 29
secondary-amines (29) 29
biochemistry & molecular biology (28) 28
chemistry, applied (28) 28
halides (28) 28
phosphine oxides (28) 28
secondary phosphine oxide (28) 28
nanoparticles (27) 27
phosphines (27) 27
aryl halides (26) 26
homogeneous catalysis (26) 26
alkenes (25) 25
phosphine-oxides (25) 25
alkynes (24) 24
chemical properties (24) 24
esters (24) 24
one-pot synthesis (24) 24
reactivity (24) 24
kinetic resolution (23) 23
phosphinoxide (23) 23
ruthenium (23) 23
acid (22) 22
alkylation (22) 22
humans (22) 22
reagents (22) 22
amides (21) 21
asymmetric-synthesis (21) 21
chemical synthesis (21) 21
chemoselective hydrogenation (21) 21
proteins (21) 21
crystal-structure (20) 20
efficient (20) 20
organophosphorus compounds (20) 20
stereoisomerism (20) 20
asymmetric hydrogenation (19) 19
ketones (19) 19
phosphonates (19) 19
tertiary (19) 19
article (18) 18
carbonyl-compounds (18) 18
chemistry/food science, general (18) 18
hydrogen (18) 18
phosphine (18) 18
acids (17) 17
activation (17) 17
arylation (17) 17
chlorides (17) 17
copper (17) 17
organic-synthesis (17) 17
resolution (17) 17
aryl chlorides (16) 16
bond formation (16) 16
boranes (16) 16
chemical reactions (16) 16
conversion (16) 16
cross-coupling (16) 16
highly efficient (16) 16
mechanism (16) 16
models, molecular (16) 16
nickel (16) 16
palladium catalysts (16) 16
phosphin (16) 16
phosphorylation (16) 16
spectroscopy (16) 16
amino acid sequence (15) 15
animals (15) 15
coordination chemistry (15) 15
more...
Library Location Library Location
Library Location Library Location
X
Sort by Item Count (A-Z)
Filter by Count
Gerstein Science - Stacks (4) 4
OISE - Stacks (2) 2
UTL at Downsview - May be requested (2) 2
Engineering & Comp. Sci. - Reference (1) 1
Engineering & Comp. Sci. - Stacks (1) 1
Gerstein Science - Reference (1) 1
Physics - Stacks (1) 1
Robarts - Stacks (1) 1
UofT at Mississauga - Stacks (1) 1
Victoria University E.J. Pratt - Stacks (1) 1
more...
Language Language
Publication Date Publication Date
Click on a bar to filter by decade
Slide to change publication date range


Journal of the American Chemical Society, ISSN 0002-7863, 12/2018, Volume 140, Issue 48, pp. 16450 - 16454
We report a Pd-catalyzed intermolecular hydrophosphinylation of 1,3-dienes to afford chiral allylic phosphine oxides. Commodity dienes and air stable phosphine... 
PHOSPHORUS LIGANDS | HYDROPHOSPHORYLATION | HYDROPHOSPHINYLATION | REDUCTION | 1,3-DIENES | HYDROHYDROXYALKYLATION | COMPLEXES | SECONDARY | POLYMERIZATION | HYDROAMINATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 01/2016, Volume 358, Issue 1, pp. 26 - 29
A novel selective catalytic reduction method of tertiary phosphine oxides to the corresponding phosphines has been developed. Notably, the reaction proceeds... 
organocatalysis | phosphines | phosphine⋅boranes | silanes | reduction | phosphinėboranes | CATALYTIC WITTIG REACTION | ACID | SECONDARY | CHEMISTRY, ORGANIC | BORANES | WASTE | phosphine.boranes | ESTERS | CHEMISTRY, APPLIED | Oxides | Silane | Catalysis | Reduction | Synthesis | Catalysts | Selective catalytic reduction | Phosphine oxide | Phosphines | Adducts
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 02/2019, Volume 60, Issue 8, pp. 575 - 582
The digest is devoted to the most widespread reducing agents which are used for the reduction of tertiary and secondary phosphine oxides, phospholene oxides,... 
Silanes | P (V) compounds | Boranes | Reduction | Aluminum reductants | METAL-FREE REDUCTION | SECONDARY | CHEMISTRY, ORGANIC | TERTIARY | DERIVATIVES
Journal Article
Chemical Science, ISSN 2041-6520, 04/2014, Volume 5, Issue 4, pp. 1322 - 1327
A crystallization-induced asymmetric transformation (CIAT) involving a radical-mediated racemization provides access to enantiopure secondary phosphine oxides.... 
Chemistry(all) | TERT-BUTYLPHENYLPHOSPHINE OXIDE | CARBON BOND FORMATION | PHOSPHORUS-CENTERED RADICALS | REDUCTION | LIGANDS | LITHIUM ALUMINUM-HYDRIDE | KINETIC RESOLUTION | SECONDARY | ASYMMETRIC HYDROGENATION | BORANES | CHEMISTRY, MULTIDISCIPLINARY | Asymmetry | Dynamics | Crystallization | Racemization | Oxides | Transformations | Phosphine oxide
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 05/2012, Volume 256, Issue 9-10, pp. 771 - 803
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 01/2016, Volume 358, Issue 1, pp. 138 - 142
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2015, Volume 80, Issue 3, pp. 1672 - 1688
A direct stereoselective conversion of tertiary hydroxyalkylphosphine oxides to the corresponding tertiary hydroxyalkylphosphine–boranes involving facile... 
BUTYLPHENYLPHOSPHINE OXIDE | PHOSPHORUS | OPTICAL RESOLUTION | LIGANDS | ENANTIOSELECTIVITY | ACID-BORANES | CONVERSION | COMPLEXES | SECONDARY | CHEMISTRY, ORGANIC | LIPASE
Journal Article
TETRAHEDRON LETTERS, ISSN 0040-4039, 10/2016, Volume 57, Issue 40, pp. 4443 - 4451
The well-known stoichiometric phosphine-promoted reactions such as the Wittig, Mitsunobu, Staudinger, Appel reactions, and others are widely used in organic... 
SYSTEM | Wittig | REAGENTS | Phosphine | SECONDARY | CHEMISTRY, ORGANIC | APPEL | ALKENES | Reduction | WITTIG REACTION | MITSUNOBU REACTIONS | Catalysis | Staudinger | DERIVATIVES | Silane | CARBOXYLIC-ACIDS
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2017, Volume 23, Issue 58, pp. 14434 - 14438
Reduction of phosphine oxides to the corresponding phosphines represents the most straightforward method to prepare these valuable reagents. However, existing... 
phosphine oxides | disiloxane | silane reductions | chemoselective methods | synthetic methods | CATALYTIC WITTIG REACTION | SULFIDES | SECONDARY | TERTIARY | CHEMISTRY, MULTIDISCIPLINARY | PHENYLSILANE | WASTE | CARBOXYLIC-ACIDS | Nitriles | Oxides | Aldehydes | Analysis | Silane | Carbonyl compounds | Reduction | Transformation | Phosphine | Reagents | Catalysis | Phosphines | Functional groups | Carbonyls
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 09/2017, Volume 82, Issue 18, pp. 9425 - 9434
The secondary R P-(−)-menthyl alkylphosphine oxide was confirmed as configurationally stable toward base and was used in base-promoted alkylation,... 
N-PHOSPHONYL IMINES | ENANTIOSELECTIVE SYNTHESIS | PURIFICATION GAP CHEMISTRY | CATALYZED ASYMMETRIC ALKYLATION | SECONDARY PHOSPHINE | CHEMISTRY, ORGANIC | BOND FORMATION | NUCLEOPHILIC-ADDITION | PEPTIDE-SYNTHESIS | CHIRAL PHOSPHINES | STEREOSELECTIVE FORMATION
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 10/2018, Volume 360, Issue 20, pp. 3999 - 4004
A rapid method for the reduction of secondary phosphine oxides under mild conditions has been developed, allowing simple isolation of the corresponding free... 
reduction | Phosphine oxide | pinacol borane | CATALYSIS | FREE REDUCTION | STEREOCHEMISTRY | SECONDARY | CHEMISTRY, ORGANIC | BORANES | TERTIARY | ZU PHOSPHINEN | LIGANDS | CHEMISTRY | CHEMISTRY, APPLIED | FACILE | Oxides | Chemical tests and reagents | Silane | Dimethyl sulfide | Reduction | Aluminum | Reagents | Tetrahydrofuran | Reducing agents | Phosphines
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 12/2019, p. 151556
Journal Article
Synthesis, ISSN 0039-7881, 01/2020, Volume 52, Issue 2, pp. 253 - 262
Abstract An alternative metal-free, efficient and practical approach for the preparation of phosphinothioates is established via the aerobic oxidative... 
paper | S-P(O) BOND CONSTRUCTION | S-ARYL | THIOPHOSPHATES | CHEMISTRY, ORGANIC | H-PHOSPHONATES | secondary phosphine oxides | metal-free | sulfonyl hydrazides | GENERAL-METHOD | phosphinothioates | PROMOTED SYNTHESIS | P(O)H COMPOUNDS | QUINONE IMINE KETALS | STEREOSELECTIVE-SYNTHESIS | ANTISENSE OLIGONUCLEOTIDES | cross-dehydrogenative coupling
Journal Article
MOLECULES, ISSN 1420-3049, 11/2019, Volume 24, Issue 21, p. 3859
H-phosphonates, H-phosphinates and secondary phosphine oxides may be preligands, and are important building blocks in the synthesis of pharmaceuticals,... 
HYDROPHOSPHORYL COMPOUNDS | MOLECULAR CALCULATIONS | BIOCHEMISTRY & MOLECULAR BIOLOGY | AB-INITIO | COMPLEXES | H-phosphonates | secondary phosphine oxides | H-phosphinates | CHEMISTRY, MULTIDISCIPLINARY | tautomerism | PROTOTROPIC REARRANGEMENT | quantum chemical calculations | ATOMS | mechanism | ENERGIES | GAUSSIAN-BASIS SETS | h-phosphinates | h-phosphonates
Journal Article
Zeitschrift fur Anorganische und Allgemeine Chemie, ISSN 0044-2313, 08/2017, Volume 643, Issue 14, pp. 916 - 921
Recently, Brønsted acids, such as phosphoric acids, carboxylic acids, and triflic acid, were found to catalyze the reduction of phosphine oxides to the... 
Brønsted acid | 1,1,3,3-Tetramethyldisiloxane | Reduction | Poly(methylhydrosiloxane) | Triphenylphosphine oxide | 1,1,3,3‐Tetramethyldisiloxane | CATALYTIC WITTIG REACTION | ROOM-TEMPERATURE | Bronsted acid | MOLECULAR-STRUCTURE | SECONDARY | CRYSTAL | BORANES | CHEMISTRY, INORGANIC & NUCLEAR | ZU PHOSPHINEN
Journal Article
Chemical Communications, ISSN 1359-7345, 07/2015, Volume 51, Issue 52, pp. 10385 - 10388
A photoinduced reaction between TMDPO (diphenyl(2,4,6-trimethylbenzoyl)-phosphine oxide) and perfluoroalkyl iodides successfully affords... 
PHOTOINITIATORS | VERBINDUNGEN | PHOSPHORIC-ACID | IODOPERFLUOROALKYLATION | SECONDARY | REACTIVITY | POLYMERIZATION | SEPARATION | TERTIARY | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | Synthesis | Iodides | Perfluoroalkyls | Reaction time | Oxides | Ligands | Catalysis | Phosphines
Journal Article
Tetrahedron, ISSN 0040-4020, 04/2012, Volume 68, Issue 15, pp. 3151 - 3155
An efficient method for the reduction of phosphine oxide derivatives into their corresponding phosphines is described. The system InBr /TMDS allows the... 
InBr3 | Reduction | Phosphine | Phosphine oxide | TMDS | HALIDES | MECHANISM | CATALYTIC-SYSTEM | SECONDARY | CHEMISTRY, ORGANIC | ALCOHOLS | ETHERS | AMINES | DEOXYGENATION | ESTERS | ALANE | Tetrahedrons | Derivatives | Phosphines | Aliphatic compounds
Journal Article
by Zhu, RY and Chen, L and Hu, XS and Zhou, F and Zhou, J
CHEMICAL SCIENCE, ISSN 2041-6520, 01/2020, Volume 11, Issue 1, pp. 97 - 106
We report the highly enantioselective synthesis of P-chiral tertiary phosphine oxides featuring an ethynyl group via Cu(i)-catalyzed azide-alkyne... 
PHOSPHORUS LIGANDS | MORITA-BAYLIS-HILLMAN | HYDROGENATION | CATALYZED ASYMMETRIC ALKYLATION | KINETIC RESOLUTION | SECONDARY PHOSPHINE | ALLYLIC ALKYLATION | STEREOGENIC PHOSPHINES | CHEMISTRY, MULTIDISCIPLINARY | METAL-FREE | DESYMMETRIZATION
Journal Article
ORGANOMETALLICS, ISSN 0276-7333, 04/2016, Volume 35, Issue 7, pp. 1030 - 1035
The hydrosilylation/reduction of tertiary and secondary phosphine oxides to phosphines is catalyzed by B(C6F5)(3) or electrophilic fluorophosphonium cations... 
REAGENT | HYDROGENATION | MECHANISM | CONVERSION | HYDROSILYLATION | SECONDARY | CHEMISTRY, ORGANIC | HYDROSILATION | TRIPHENYLPHOSPHINE | TERTIARY | SELECTIVITY | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article