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Advanced Synthesis & Catalysis, ISSN 1615-4150, 10/2018, Volume 360, Issue 20, pp. 3999 - 4004
A rapid method for the reduction of secondary phosphine oxides under mild conditions has been developed, allowing simple isolation of the corresponding free... 
reduction | Phosphine oxide | pinacol borane | CATALYSIS | FREE REDUCTION | STEREOCHEMISTRY | SECONDARY | CHEMISTRY, ORGANIC | BORANES | TERTIARY | ZU PHOSPHINEN | LIGANDS | CHEMISTRY | CHEMISTRY, APPLIED | FACILE | Oxides | Chemical tests and reagents | Silane | Dimethyl sulfide | Reduction | Aluminum | Reagents | Tetrahydrofuran | Reducing agents | Phosphines
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 09/2017, Volume 82, Issue 18, pp. 9425 - 9434
The secondary R P-(−)-menthyl alkylphosphine oxide was confirmed as configurationally stable toward base and was used in base-promoted alkylation,... 
N-PHOSPHONYL IMINES | ENANTIOSELECTIVE SYNTHESIS | PURIFICATION GAP CHEMISTRY | CATALYZED ASYMMETRIC ALKYLATION | SECONDARY PHOSPHINE | CHEMISTRY, ORGANIC | BOND FORMATION | NUCLEOPHILIC-ADDITION | PEPTIDE-SYNTHESIS | CHIRAL PHOSPHINES | STEREOSELECTIVE FORMATION
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 02/2019, Volume 60, Issue 8, pp. 575 - 582
[Display omitted] •Methods of reduction based on borane complexes afford to obtain derivatives protected from reoxidization.•Silanes are the most widespread... 
Silanes | P (V) compounds | Boranes | Reduction | Aluminum reductants | METAL-FREE REDUCTION | SECONDARY | CHEMISTRY, ORGANIC | TERTIARY | DERIVATIVES
Journal Article
TETRAHEDRON LETTERS, ISSN 0040-4039, 10/2016, Volume 57, Issue 40, pp. 4443 - 4451
The well-known stoichiometric phosphine-promoted reactions such as the Wittig, Mitsunobu, Staudinger, Appel reactions, and others are widely used in organic... 
SYSTEM | Wittig | REAGENTS | Phosphine | SECONDARY | CHEMISTRY, ORGANIC | APPEL | ALKENES | Reduction | WITTIG REACTION | MITSUNOBU REACTIONS | Catalysis | Staudinger | DERIVATIVES | Silane | CARBOXYLIC-ACIDS
Journal Article
Chemical Communications, ISSN 1359-7345, 01/2012, Volume 48, Issue 6, pp. 817 - 819
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 10/2017, Volume 82, Issue 19, pp. 10727 - 10731
An efficient and green route to access diverse functionalized ketones via dehydrogenative–dehydrative cross-coupling of primary and secondary alcohols is... 
SECONDARY ALCOHOLS | SOLVENT-FREE CONDITIONS | ATOM ECONOMY | BETA-ALKYLATION | C-C | CHEMISTRY, ORGANIC | BOND FORMATION | IRIDIUM-CNP COMPLEX | EFFICIENT | METAL-FREE | BORROWING-HYDROGEN | Chemical Sciences
Journal Article
Organometallics, ISSN 0276-7333, 06/2018, Volume 37, Issue 11, pp. 1760 - 1772
Tandem alkylation/arylation of primary phosphines PH2R (R = Ph, Cy, Fc, FcCH2; Fc = ferrocenyl) with 5-bromo-6-chloromethylacenaphthene (1) and 2 equiv of... 
DIARYLPHOSPHINES | CROSS-COUPLING REACTIONS | ASYMMETRIC-SYNTHESIS | STABILITY | COMPLEXES | REACTIVITY | CHEMISTRY | CHEMISTRY, ORGANIC | SECONDARY PHOSPHINES | CRYSTAL | MECHANISMS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2018, Volume 140, Issue 48, pp. 16450 - 16454
We report a Pd-catalyzed intermolecular hydrophosphinylation of 1,3-dienes to afford chiral allylic phosphine oxides. Commodity dienes and air stable phosphine... 
PHOSPHORUS LIGANDS | HYDROPHOSPHORYLATION | HYDROPHOSPHINYLATION | REDUCTION | 1,3-DIENES | HYDROHYDROXYALKYLATION | COMPLEXES | SECONDARY | POLYMERIZATION | HYDROAMINATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2015, Volume 21, Issue 22, pp. 8015 - 8018
We demonstrate that the synthesis of new N‐functionalized phosphinecarboxamides is possible by reaction of primary and secondary amines with PCO− in the... 
phosphines | phosphides | carboxamides | anions | phosphorus | Phosphorus | Anions | Phosphides | Carboxamides | Phosphines | DIOXIDE | PRIMARY PHOSPHANES | CATALYZED FORMATION | NA(OCP) | PHOSPHORUS-BORON BONDS | CHEMISTRY, MULTIDISCIPLINARY | LIGANDS | HETEROCYCLES | CHEMISTRY | SODIUM PHOSPHAETHYNOLATE | BUILDING-BLOCK | Chemical Sciences | Other | Communications
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 09/2018, Volume 360, Issue 17, pp. 3233 - 3238
Journal Article
Tetrahedron, ISSN 0040-4020, 04/2012, Volume 68, Issue 15, pp. 3151 - 3155
An efficient method for the reduction of phosphine oxide derivatives into their corresponding phosphines is described. The system InBr3/TMDS allows the... 
InBr3 | Reduction | Phosphine | Phosphine oxide | TMDS | HALIDES | MECHANISM | CATALYTIC-SYSTEM | SECONDARY | CHEMISTRY, ORGANIC | ALCOHOLS | ETHERS | AMINES | DEOXYGENATION | ESTERS | ALANE | Tetrahedrons | Derivatives | Phosphines | Aliphatic compounds
Journal Article