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chemistry, multidisciplinary (4) 4
ligands (4) 4
chemistry, organic (3) 3
complexes (3) 3
asymmetric hydrogenation (2) 2
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Chemistry – A European Journal, ISSN 0947-6539, 07/2008, Volume 14, Issue 22, pp. 6593 - 6596
Access to new chiral reagents: The first catalytic enantioselective synthesis of axially chiral N,N‐dialkylbenzamides was developed in high yields with... 
axial chirality | benzamides | cycloaddition | enantioselective catalysis | rhodium | ASYMMETRIC-SYNTHESIS | DYNAMIC RESOLUTION | ATROPISOMERIC AMIDES | COMPLEXES | TERTIARY AROMATIC AMIDES | BOND ROTATION | CHEMISTRY, MULTIDISCIPLINARY | THERMODYNAMIC CONTROL | KINETIC RESOLUTION | C-C
Journal Article
Research on Chemical Intermediates, ISSN 0922-6168, 12/2019, Volume 45, Issue 12, pp. 5959 - 5974
This paper summarizes the application of the chiral ligand DTBM-SegPHOS in asymmetric catalytic hydrogenation reactions. DTBM-SegPHOS exhibits pronounced... 
Chemistry | Weakly attractive interactions | Physical Chemistry | QuinoxP | Asymmetric hydrogenation | Catalysis | Inorganic Chemistry | DTBM-SegPHOS | Mechanism
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2011, Volume 50, Issue 19, pp. 4475 - 4479
A cationic rhodium(I) complex catalyzes the title reaction of 1,6‐diynes through a [2+2+2] cycloaddition and subsequent electrocyclic ring opening (see scheme;... 
cycloaddition | asymmetric catalysis | enynes | olefination | rhodium | COMPLEXES | TRANSFER HYDROGENATION | CARBONYL-COMPOUNDS | PAECILOMYCINE-A | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | DYNAMIC KINETIC RESOLUTION | KETONES | ESTERS | CONSTRUCTION | CYCLOTRIMERIZATION
Journal Article
Organic Letters, ISSN 1523-7060, 07/2008, Volume 10, Issue 13, pp. 2849 - 2852
A cationic rhodium(I)/Segphos complex catalyzes a [2 + 2 + 2] cycloaddition of internal 1,6-diynes with a phosphonate- or ester-substituted 1,3-butadiyne... 
DIELS-ALDER APPROACH | TETHERED DIYNES | AMINO-ACID | 2+2+2 CYCLOADDITION REACTIONS | ONE-STEP SYNTHESIS | NITRILES | RUTHENIUM-CATALYZED CYCLOADDITION | CHEMISTRY, ORGANIC | ALKYNE CYCLOTRIMERIZATION | 2,2'-BIPYRIDINE LIGANDS | CROSS-CYCLOTRIMERIZATION
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2004, Volume 45, Issue 1, pp. 183 - 185
Graphic Chiral dicationic SEGPHOS–Pd(II) complex achieves a high chemical yield, ( E)-olefin selectivity, anti-diastereoselectivity, along with high... 
SEGPHOS | trifluoropyruvate | palladium | BINAP | carbonyl–ene reaction | Carbonyl-ene reaction | Palladium | Trifluoropyruvate | CATIONIC PALLADIUM(II) | CHEMISTRY, ORGANIC | QUATERNARY CARBON CENTERS | LIGANDS | DIELS-ALDER REACTION | CONSTRUCTION | ESTERS | GLYOXYLATE | carbonyl-ene reaction
Journal Article
Chemistry Letters, ISSN 0366-7022, 9/2008, Volume 37, Issue 9, pp. 934 - 935
A cationic rhodium(I)/(R)-Segphos® [(4,4′-bi-1,3-benzodioxole)-5,5′-diylbis(diphenylphosphine)] complex catalyzes the highly enantioselective [4 + 2]... 
KETONES | ALKENES | 4-ALKYNALS | INSERTION | COMPLEX | CARBOCYCLIZATION | CARBONYL-COMPOUNDS | ALDEHYDES | 2+2+2 CYCLOADDITION | 1,6-DIYNES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
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