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Angewandte Chemie International Edition, ISSN 1433-7851, 05/2017, Volume 56, Issue 22, pp. 6317 - 6320
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 05/2014, Volume 79, Issue 10, pp. 4484 - 4491
The first tail-to-tail dimerization of methacrylonitrile (MAN) has been realized by the cooperative use of N-heterocyclic carbene (NHC) and Brønsted acid... 
STEREOSELECTIVE ANNULATION REACTIONS | TRANSITION-METAL CATALYSIS | STABLE CARBENE | ACTIVATION | ACRYLONITRILE | SELECTIVE DIMERIZATION | LEWIS | CHEMISTRY, ORGANIC | METHACRYLATE | METHYL ACRYLATE | UMPOLUNG | Carbenes | Chemical properties | Research
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2017, Volume 139, Issue 2, pp. 757 - 762
A recently developed metal–organic framework (MOF) catalyst for the dimerization of ethylene has a combination of selectivity and activity that surpasses that... 
TETRAMERIZATION | ALPHA-OLEFINS | METAL-ORGANIC FRAMEWORKS | OLEFIN METATHESIS CATALYSTS | SELECTIVE TRIMERIZATION | COMPLEXES | POLYMERIZATION | OLIGOMERIZATION | ETHENE | CHEMISTRY, MULTIDISCIPLINARY | CHROMIUM CATALYSTS | Density functionals | Molecules | Chemical reactions | Usage | Chemical properties | Metal ions
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2016, Volume 55, Issue 23, pp. 6753 - 6757
It has been established that a cationic rhodium(I)/binap complex catalyzes the cross‐cyclotrimerization of two molecules of a monosubstituted allene with one... 
dimerization | allenes | cyclization | alkynes | rhodium | ACETYLENES | CHEMOSELECTIVE COCYCLOTRIMERIZATION | ENE REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | 2+2+2 CYCLOADDITION REACTIONS | NICKEL | METHYL PROPIOLATE | COUPLING REACTION | SYNTHETIC APPLICATIONS | SELECTIVE SYNTHESIS | CONJUGATED TRIENES | Rhodium | Hydrogen | Catalysis | Allene | Dimerization | Alkynes
Journal Article
ACS Catalysis, ISSN 2155-5435, 12/2018, Volume 8, Issue 12, pp. 11407 - 11422
The mechanistic origin of alkene dimerization on Ni sites supported on aluminosilicates has been ascribed to both coordination–insertion (i.e., Cossee-Arlman)... 
coordination-insertion | dimerization | nickel | zeolite | ethane | alkene | HETEROGENEOUS OLIGOMERIZATION | ZEOLITE-BETA | ELECTRON-SPIN-RESONANCE | SELECTIVE DIMERIZATION | CHEMISTRY, PHYSICAL | ethene | COMPARATIVE CRYSTAL FIELD | PROPANE DEHYDROGENATION | PROPENE OLIGOMERIZATION | ZIEGLER-NATTA CATALYSIS | LEWIS-ACID SITES | CATALYTIC ETHYLENE DIMERIZATION
Journal Article
Organic Letters, ISSN 1523-7060, 07/2011, Volume 13, Issue 14, pp. 3722 - 3725
Highly selective tail-to-tail dimerization of methyl methacrylate has been realized by an N-heterocyclic carbene catalyst, giving dimethyl... 
TRANSITION-METAL CATALYSIS | ACTIVATION | MECHANISM | ACRYLONITRILE | SELECTIVE DIMERIZATION | COMPLEXES | CHEMISTRY, ORGANIC | INTERMEDIATE | RUTHENIUM | ACRYLATE | POLYMERIZATION
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 05/2019, Volume 60, Issue 18, pp. 1234 - 1237
A palladium catalyzed oxidative cross-coupling reaction between terminal alkynes and acrylates was developed. In the presence of palladium catalyst and... 
Cross-dimerization | Conjugated skeleton | Acrylates | Palladium catalyst | Alkynes | ROOM-TEMPERATURE | EFFICIENT ROUTE | CHEMISTRY, ORGANIC | BOND FORMATION | SELECTIVE ACCESS | C-H ACTIVATION | OXIDATIVE OLEFINATION | COUPLING REACTION | SIMPLE ALKENES | CONJUGATE ADDITION | Palladium catalysts | Copper compounds | Palladium | Chemical tests and reagents
Journal Article
Asian Journal of Organic Chemistry, ISSN 2193-5807, 01/2018, Volume 7, Issue 1, pp. 155 - 159
Methods toward the dimerization and homocoupling of terminal alkynes have been established that employ Co complexes along with tBuOK under different... 
dimerization | cobalt | homocoupling | alkynes | ROOM-TEMPERATURE | PALLADIUM | COMPLEX | BOND-FORMING REACTIONS | CHEMISTRY, ORGANIC | TO-HEAD DIMERIZATION | SUPPORTED COPPER-CATALYSTS | HIGHLY EFFICIENT | COUPLING REACTION | CARBON-CARBON | SELECTIVE CROSS-DIMERIZATION
Journal Article
Tetrahedron, ISSN 0040-4020, 01/2017, Volume 73, Issue 2, pp. 148 - 153
Copper (I) or copper (II) salts and oxides promote regioselective head-to-head additive dimerization of aromatic and aliphatic terminal alkynes in the presence... 
Copper salts and oxides | 1,4-diphenylbuta-1,3-diyne | Catalysis | Diethylphosphite | 1,3-enynes | Alkynes | COMPLEX | SELECTIVE DIMERIZATION | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | GRUBBS CATALYST | CARBOPALLADATION | TO-HEAD DIMERIZATION | STEREOSELECTIVE DIMERIZATION | ARYLACETYLENES | COUPLING REACTION | ENYNES | Copper compounds | Copper
Journal Article
Synlett, ISSN 0936-5214, 09/2012, Volume 23, Issue 15, pp. 2261 - 2265
Abstract 2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO) catalyzes the direct oxidation of primary alkyl alcohols to symmetric ­esters at 1–2 mol% loadings. These... 
letter | dimerization | oxidation | catalysis | alcohols | esters | DIMERIC ESTERS | SELECTIVE OXIDATION | BENZYLIC ALCOHOLS | COMPLEXES | ESTERIFICATION | CHEMISTRY, ORGANIC | RUTHENIUM | ALDEHYDES | SECONDARY ALCOHOLS | OXOAMMONIUM SALTS | CARBOXYLIC-ACIDS
Journal Article
ACS Catalysis, ISSN 2155-5435, 10/2014, Volume 4, Issue 10, pp. 3470 - 3480
A series of pincer complexes of Rh has been prepared and tested as catalysts for the dimerization of terminal alkynes. The pincers included... 
catalysis | pincer | phosphine | alkyne dimerization | enyne | rhodium | IRIDIUM | SELECTIVE DIMERIZATION | CHEMISTRY, PHYSICAL | CROSS-DIMERIZATION | TAIL DIMERIZATION | RUTHENIUM | TO-HEAD DIMERIZATION | OXIDATIVE ADDITION | STEREOSELECTIVE DIMERIZATION | PALLADIUM(II) COMPLEXES | LIGAND
Journal Article