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Chemical Science, ISSN 2041-6520, 01/2016, Volume 7, Issue 1, pp. 628 - 641
A beta-diketiminato n-butylmagnesium complex is presented as a selective precatalyst for the reductive hydroboration of organic nitriles with pinacolborane... 
LIQUID-PHASE | LOW-VALENT | HYDROGENATION REACTIONS | CARBOXYLIC-ACID ESTERS | CALCIUM | INTRAMOLECULAR HYDROAMINATION | ORGANOMETALLIC COMPLEXES | PRIMARY AMINES | SELECTIVE REDUCTION | CHEMISTRY, MULTIDISCIPLINARY | AROMATIC NITRILES | Hydroboration | Catalysts | Aromatic compounds | Nitriles | Magnesium | Catalysis | Substrates | Bearing
Journal Article
Chemical science, ISSN 2041-6520, 01/2016, Volume 7, Issue 1, pp. 628 - 641
A β-diketiminato -butylmagnesium complex is presented as a selective precatalyst for the reductive hydroboration of organic nitriles with pinacolborane... 
Journal Article
ACS Catalysis, ISSN 2155-5435, 03/2018, Volume 8, Issue 3, pp. 2001 - 2005
The aluminum-catalyzed hydroboration of alkenes with HBpin is reported using simple commercially available aluminum hydride precatalysts [LiAlH4 or sodium... 
main group | catalysis | aluminum | hydroboration | alkene | REDUCTIVE DEHALOGENATION | COMPLEXES | CHEMISTRY, PHYSICAL | CARBONYL-COMPOUNDS | TERMINAL ALKYNES | ALDEHYDES | HYDROALUMINATION | HYDRIDE | SELECTIVE HYDROBORATION | KETONES | BORON REAGENTS
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2017, Volume 82, Issue 23, pp. 12857 - 12862
We report an operationally convenient room temperature hydroboration of aldehydes and ketones employing Fe­(acac)3 as precatalyst. The hydroboration of... 
SELECTIVE HYDROBORATION | CROSS-COUPLING REACTIONS | 1,1-DISUBSTITUTED ALKENES | ASYMMETRIC REDUCTION | ENANTIOSELECTIVE REDUCTION | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | C-H ACTIVATION | HYDRIDE COMPLEXES | ORGANIC ELECTROPHILES | ALKENE HYDROBORATION | Iron compounds | Hydroboration | Ketones | Analysis | Chemical properties | Aldehydes | Electric properties
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2018, Volume 57, Issue 30, pp. 9485 - 9490
Hydroboration of internal alkynes with N‐heterocyclic carbene boranes (NHC‐boranes) occurs to provide stable NHC (E)‐alkenylboranes upon thermolysis in the... 
carbenes | radical reactions | hydroboration | synthetic methods | alkynes | SELECTIVE HYDROBORATION | ALKENES | CROSS-COUPLING REACTIONS | COMPLEXES | TERMINAL ALKYNES | INTERNAL ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | Pyrolysis | Hydrogen | Heterocyclic compounds | Boranes | Selectivity | Hydroboration | Peroxide | Hydrogen ion concentration | Alkynes
Journal Article
Organic Letters, ISSN 1523-7060, 10/2017, Volume 19, Issue 19, pp. 5422 - 5425
An iron-catalyzed hydroboration of vinylcyclopropane with HBpin is first reported for the preparation of valuable homoallylic organoboronic esters. The iron... 
SELECTIVE HYDROBORATION | HYDROFUNCTIONALIZATION | ACTIVATION | CHEMO | CARBON-CARBON BOND | HYDROSILYLATION | BORYLALKENES ASYMMETRIC-SYNTHESIS | CHEMISTRY, ORGANIC | REGIO | ALLYLIC SUBSTITUTION | ALKENE HYDROBORATION
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 10/2017, Volume 2017, Issue 38, pp. 5814 - 5818
Cobalt(II) catalysts based on flexible PNP or NNN ligands were explored for the regioselective hydroboration of alkenes. A known CoII–PNP pincer complex was... 
N ligands | Hydroboration | Homogeneous catalysts | Alkenes | Regioselectivity | Cobalt | CHEMISTRY, ORGANIC | TRANSFER HYDROGENATION | IRON | ASYMMETRIC HYDROBORATION | ALCOHOLS | 1,1-DISUBSTITUTED ALKENES | AMINES | MARKOVNIKOV-SELECTIVE HYDROBORATION | ARYL ALKENES | ISOMERIZATION-HYDROBORATION | C=N BONDS | Olefins
Journal Article
Organic Letters, ISSN 1523-7060, 04/2018, Volume 20, Issue 7, pp. 1861 - 1865
Trialkylphosphine organocatalysts have enabled regioselective anti-hydroboration of internal alkynes with pinacolborane reagents to provide (E)-disubstituted... 
CONVENIENT SYNTHESIS | ALKYNOATES | SELECTIVE HYDROBORATION | ACETYLENIC ESTERS | TRANS-HYDROBORATION | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | PINACOLBORANE | DIBORATION
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2019, Volume 25, Issue 43, pp. 10063 - 10068
The hydroboration of internal alkynes with pinacolborane as the reagent catalyzed by [Cp*RuCl]4 results in good to excellent levels of regio‐ as well as... 
pinacolborane | ruthenium | alkenyl boronates | hydroboration | trans-addition | HYDROSTANNATION | HYDROGENATION | RHODIUM | FORMAL SYNTHESIS | HYDROSILYLATION | TERMINAL ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | CATALYZED HYDROBORATION | SELECTIVE HYDROBORATION | ALKENES | REDUCTION | Alcohols | Stereoselectivity | Propargyl alcohol | Boron | Hydroboration | Reagents | Substrates | Alkynes
Journal Article
ACS Catalysis, ISSN 2155-5435, 06/2015, Volume 5, Issue 6, pp. 3238 - 3259
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2019, Volume 58, Issue 21, pp. 7025 - 7029
A magnesium‐catalyzed hydroboration of alkynes providing good yields and selectivities for a wide range of terminal and symmetrical and unsymmetrical internal... 
magnesium | DFT | hydroboration | vinyl borane | alkynes | ACIDS | COMPLEXES | REACTIVITY | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | HYDRIDE | SELECTIVE HYDROBORATION | ALKENES | CROSS-COUPLING REACTIONS | Hydroboration | Magnesium | Reaction mechanisms | Functional groups | Alkynes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2016, Volume 55, Issue 9, pp. 3181 - 3186
1,3‐N,O‐chelated complexes of RhI and IrI cooperatively and reversibly stabilized the B−H bond of HBCy2 to afford six‐membered metallaheterocycles (M=Rh (7) or... 
boranes | iridium | hemilability | hydroboration | rhodium | REACTIVITY | COORDINATION | RUTHENIUM | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | H BOND ACTIVATION | SELECTIVE HYDROBORATION | KETONES | LIGAND | SIGMA-BORANE | B-H | Hydroboration | Iridium | Rhodium | Alkenes | Adducts
Journal Article
ACS Catalysis, ISSN 2155-5435, 12/2017, Volume 7, Issue 12, pp. 8454 - 8459
The zinc hydride NacNacZnH (2) (NacNac = [Ar′NC­(Me)­CHC­(Me)­NAr′]−, Ar′ = 2,6-Me2C6H3) catalyzes regioselective hydrosilylation and hydroboration of... 
hydrosilylation | hydroboration | zinc | DFT calculations | N-heterocycles | SMALL MOLECULES | SILABORATION | CHEMISTRY, PHYSICAL | TRANSFER HYDROGENATION | SELECTIVE REDUCTION | REGIOSELECTIVE 1,4-HYDROBORATION | PYRIDINES | HANTZSCH ESTERS | HYDRIDE | DIHYDROPYRIDINES | MAIN-GROUP COMPOUNDS
Journal Article
Dalton Transactions, ISSN 1477-9226, 2017, Volume 46, Issue 24, pp. 7750 - 7757
The first examples for the rhenium-catalysed hydroboration of aldehydes, ketones and aldimines, including heteroaromatic quinoline, are reported herein.... 
SELECTIVE HYDROBORATION | KETONES | LIGANDS | HYDROSILYLATION | ENANTIOSELECTIVE REDUCTION | ZN(II) COMPLEX | CATECHOLBORANE | CARBONYL-COMPOUNDS | ASYMMETRIC HYDROBORATION | EFFICIENT CATALYSTS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article