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semi-pinacol rearrangement (26) 26
chemistry, organic (15) 15
chemistry, multidisciplinary (11) 11
stereoselective construction (8) 8
catalysis (7) 7
ketones (6) 6
semipinacol rearrangement (6) 6
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semi‐pinacol rearrangement (4) 4
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-welwitindolinone-a isonitrile (2) 2
12,13-seco norditerpenoid alkaloid (2) 2
addition cascade (2) 2
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c bond-cleavage (2) 2
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chemistry, inorganic & nuclear (2) 2
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cyclohexenes - chemistry (2) 2
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ethers (2) 2
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gold (2) 2
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iodine (2) 2
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rearrangements (2) 2
rhodium (2) 2
rotenoid (2) 2
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semipinacol rearrangements (2) 2
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structure (2) 2
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trans-himachalenes (2) 2
visible-light photocatalysis (2) 2
-cortistatin-a (1) 1
-deguelin (1) 1
1,5-hydrogen sigmatropic rearrangement (1) 1
12,13- seco norditerpenoid alkaloid (1) 1
1st total-synthesis (1) 1
2,3-aziridino alcohols (1) 1
[ chim.orga ] chemical sciences/organic chemistry (1) 1
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Angewandte Chemie International Edition, ISSN 1433-7851, 05/2017, Volume 56, Issue 21, pp. 5858 - 5861
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 58, pp. 8096 - 8099
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 07/2018, Volume 54, Issue 58, pp. 8096 - 8099
Two photo-catalytic tandem alkyl radical addition/semipinacol rearrangement reactions of cycloalkanol-substituted styrenes with N-acyloxyphthalimides and... 
Journal Article
ACS Catalysis, ISSN 2155-5435, 07/2017, Volume 7, Issue 7, pp. 4435 - 4440
Journal Article
Asian Journal of Organic Chemistry, ISSN 2193-5807, 08/2019, Volume 8, Issue 8, pp. 1390 - 1393
Journal Article
Tetrahedron: Asymmetry, ISSN 0957-4166, 01/2011, Volume 22, Issue 1, pp. 101 - 108
The acid-catalyzed rearrangement of two enantiomerically pure epoxides derived from sesquiterpernic himachalenes, which are the main components of the... 
SUBSTITUTED BENZYLIC ALDEHYDES | CHEMISTRY, ORGANIC | CHEMISTRY, PHYSICAL | TRANS-HIMACHALENES | CIS | BETA-ALKOXY ALCOHOLS | PROMOTED REARRANGEMENT | EPOXIDATION | CHEMISTRY, INORGANIC & NUCLEAR | SEMI-PINACOL REARRANGEMENT | KETONES | SELECTIVE SYNTHESIS | EFFICIENT | Analytical chemistry | Chemical Sciences
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 01/2012, Volume 10, Issue 3, pp. 502 - 505
Under Lewis acid activation, the new alpha-hydroxy-spiro epoxide scaffold 1a underwent an original tandem Payne/Meinwald rearrangement affording the... 
ALDOL ALDOL PROCESS | TEDANOLIDES | SEMI-PINACOL REARRANGEMENT | ORGANIC-SYNTHESIS | STEREOSELECTIVE CONSTRUCTION | CHEMISTRY, ORGANIC | ETHER REARRANGEMENTS | CENTERS | PROMOTED REARRANGEMENT | C1-C-11 FRAGMENT | QUATERNARY CARBON | Organic chemistry | Chemical Sciences
Journal Article
Tetrahedron: Asymmetry, ISSN 0957-4166, 2010, Volume 21, Issue 9, pp. 1272 - 1277
The molecular rearrangement under mild conditions of two epoxides derived from the sesquiterpenic himachalenes has been studied using BF 3·Et 2O as the Lewis... 
GRAPH-SET ANALYSIS | BETA-HIMACHALENE | STEREOCHEMISTRY | SUBSTITUTED BENZYLIC ALDEHYDES | CHEMISTRY, ORGANIC | CHEMISTRY, PHYSICAL | TRANS-HIMACHALENES | CIS | PROMOTED REARRANGEMENT | CHEMISTRY, INORGANIC & NUCLEAR | SEMI-PINACOL REARRANGEMENT | KETONES | SELECTIVE SYNTHESIS | Sesquiterpenes | Catalysis | Analytical chemistry | Chemical Sciences
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 04/2016, Volume 358, Issue 9, pp. 1392 - 1397
A highly regio‐ and stereoselective method to construct a broad range of 7‐oxabicyclo[2.2.1]heptanes, which proceeds through a sequential reaction involving... 
tandem reaction | farnesiferol C | asymmetric synthesis | gold catalysis | semi‐pinacol rearrangement | semi-pinacol rearrangement | GOLD | CHEMISTRY, ORGANIC | ALPHA | SESQUITERPENOIDS | REARRANGEMENT | INHIBITORS | CHEMISTRY, APPLIED | CATALYSTS | Synthesis | Catalysis | Organic compounds | Gold | Chemical synthesis | Heptanes | Isomerization | Alkynes | Synthesis (chemistry) | Construction | Asymmetry | Migration
Journal Article
Synthesis, ISSN 0039-7881, 03/2019, Volume 51, Issue 5, pp. 1139 - 1156
Abstract A general synthetic approach to rotenoids is described, featuring 1) stereospecific, group-selective 1,2-rearrangements of epoxy alcohols, and 2) S N... 
feature | rotenoid | CHEMISTRY, ORGANIC | IDENTIFICATION | CONSTITUTION | DEGUELIN | PINACOL-TYPE REARRANGEMENT | semi-pinacol rearrangement | INSECT TOXINS | isoflavonoid | (+/-)-DEGUELIN | ISOFLAVONOIDS | SNAr cyclization | TRIETHYLALUMINUM | total synthesis | ASYMMETRIC TOTAL-SYNTHESIS | CONCISE SYNTHESIS
Journal Article
CHEMISTRY-AN ASIAN JOURNAL, ISSN 1861-4728, 09/2015, Volume 10, Issue 9, pp. 1874 - 1880
The asymmetric total synthesis of (-)-maoecrystalV, a novel cytotoxic pentacyclic ent-kaurane diterpene, has been accomplished. Key steps of the current... 
ORGANIC-SYNTHESIS | KAPPA-B ACTIVATION | MAOECRYSTAL-V | ALPHA-ARYLATION | CHEMISTRY, MULTIDISCIPLINARY | O-H INSERTION | diels-alder reaction | semi-pinacol rearrangement | ENT-KAURANE DITERPENOIDS | asymmetric synthesis | STEREOCENTERS | STEREOSELECTIVE CONSTRUCTION | SEMIPINACOL REARRANGEMENT | total synthesis | DIAZOCARBONYL | rhodium
Journal Article