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semipinacol rearrangement (140) 140
chemistry, multidisciplinary (70) 70
chemistry, organic (61) 61
index medicus (33) 33
catalysis (31) 31
ketones (24) 24
construction (23) 23
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chemistry (8) 8
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catalyzed trifluoromethylation (7) 7
copper (7) 7
enantioselective total-synthesis (7) 7
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semi-pinacol rearrangement (7) 7
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semipinacol rearrangements (5) 5
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aza-pinacol rearrangement (4) 4
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Angewandte Chemie International Edition, ISSN 1433-7851, 10/2018, Volume 57, Issue 40, pp. 13192 - 13196
An efficient oximation method has been developed on the basis of NO+‐initiated semipinacol rearrangement and subsequent proton elimination. The procedure... 
semipinacol rearrangement | quaternary centers | oximes | oxime ethers | spiro compounds | ISOXAZOLINE | NATURAL-PRODUCTS | STRATEGY | REVERSE-TRANSCRIPTASE | CHEMISTRY, MULTIDISCIPLINARY | ALKENES | KETONES | AMINATION | NITROSONIUM TETRAFLUOROBORATE | N BOND FORMATION | CATION | Alkaloids | Insecticides | Oximes | Quaternary | Reagents | Ethers | Nitrosation | Substrates
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2013, Volume 52, Issue 35, pp. 9266 - 9270
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2017, Volume 56, Issue 21, pp. 5858 - 5861
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 03/2019, Volume 2019, Issue 10, pp. 1964 - 1980
Journal Article
Organic Letters, ISSN 1523-7060, 07/2018, Volume 20, Issue 14, pp. 4227 - 4230
A new and modular electrophilic trifluoromethylthiolation/semipinacol rearrangement of allylic silyl ethers has been developed under mild conditions. This... 
MEDICINAL CHEMISTRY | ELEMENTAL SULFUR | BORONIC ACIDS | HYPERVALENT IODONIUM YLIDE | MEDIATED OXIDATIVE TRIFLUOROMETHYLTHIOLATION | SEMIPINACOL REARRANGEMENT | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | SILVER(I) TRIFLUOROMETHANETHIOLATE | COPPER-CATALYZED TRIFLUOROMETHYLTHIOLATION | BETA-KETO-ESTERS
Journal Article
by Ma, DK and Miao, CB and Sun, JW
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 09/2019, Volume 141, Issue 35, pp. 13783 - 13787
A catalytic asymmetric House-Meinwald rearrangement for the synthesis of both cyclic and acyclic ketones is disclosed. From readily accessible racemic... 
BRONSTED ACID | KETONES | ACTIVATION | ORTHO-QUINONE METHIDES | ARYLATION | SEMIPINACOL REARRANGEMENT | ASYMMETRIC EPOXIDATION | OLEFINS | CHEMISTRY, MULTIDISCIPLINARY | CYCLOPENTANONES
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 26, pp. 8344 - 8347
A novel organocatalytic asymmetric tandem Nazarov cyclization/​semi­pinacol rearrangement reaction using “unactivated” substrates has been developed,... 
BRONSTED ACID | ELECTROCYCLIZATION | CATALYSIS | ACTIVATION | CARBON | HYDROGENATION | RESOLUTION | SEMIPINACOL REARRANGEMENT | STEREOSELECTIVE-SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | Usage | Density functionals | Ring formation (Chemistry) | Research | Chemical properties | Catalysis | Organic compounds
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 06/2016, Volume 57, Issue 26, pp. 2877 - 2879
[Display omitted] •Total synthesis of (±)-Lingzhilactone B has been achieved for the first time.•Key reaction features a semipinacol rearrangement to construct... 
Lingzhilactone B | Total synthesis | Semipinacol rearrangement | CHEMISTRY, ORGANIC | Synthesis | Organic compounds
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2019, Volume 58, Issue 22, pp. 7450 - 7453
An enantioselective catalytic alkoxylation/oxidative rearrangement of allylic alcohols has been established by using a Brønsted acid and chiral organoiodine.... 
organocatalysis | alkoxylation | iodine | asymmetric synthesis | rearrangements | ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | ALKENES | HYPERVALENT IODINE(III) REAGENTS | CONSTRUCTION | SEMIPINACOL REARRANGEMENT | OXIDATIVE REARRANGEMENTS | SPIROCYCLIZATION | DIFLUORINATION | Synthesis | Catalysis | Enantiomers | Organic compounds | Alcohols | Ketones | Proline | Alcohol | Iodine
Journal Article