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Angewandte Chemie International Edition, ISSN 1433-7851, 01/2014, Volume 53, Issue 2, pp. 565 - 570
SiO in a complex: The first silanone that is stable at room temperature (3) is reported. The two‐step synthesis involves carbonylation of the silylidyne... 
chromium | silanones | silicon | silylenes | silylidynes | ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | MOLECULES | TEMPERATURE | INFRARED SPECTROSCOPIC EVIDENCE | GAS-PHASE | CHEMISTRY | MULTIPLE BONDS | MATRIX-ISOLATION | Chromium | Silicon | Oxidation | Synthesis | Nitrous oxides | Carbonyls
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2009, Volume 15, Issue 11, pp. 2476 - 2485
ESi transfer: Anionic compounds capable of transferring a silicon‐containing double bond are reviewed (see figure), particularly reagents with SiSi moieties... 
Si ligands | silicon | Group 14 elements | multiple bonds | anions | conjugation | Anions | Multiple bonds | Silicon | Conjugation | CYCLIC SILENES | GROUP-14 CHEMISTRY | SP-TYPE SILYL ANION | ORGANIC DERIVATIVES | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | LOW COORDINATION | HEAVY ALKENES | SI=SI DOUBLE-BOND | SI DOUBLE-BONDS
Journal Article
The Journal of Physical Chemistry C, ISSN 1932-7447, 04/2014, Volume 118, Issue 14, pp. 7669 - 7677
Oxidation of the surface of well-passivated silicon nanocrystals introduces defects which dramatically affect the optical properties of the material. One such... 
SI NANOCRYSTALS | CORRELATED MOLECULAR CALCULATIONS | MATERIALS SCIENCE, MULTIDISCIPLINARY | OPTICAL-PROPERTIES | CHEMISTRY, PHYSICAL | STATE | NANOSCIENCE & NANOTECHNOLOGY | CONICAL INTERSECTIONS | BAND-GAP | QUANTUM DOTS | POROUS SILICON | LUMINESCENCE | GAUSSIAN-BASIS SETS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2015, Volume 54, Issue 34, pp. 9980 - 9985
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2017, Volume 139, Issue 1, pp. 99 - 102
Although the synthesis of several bis­(disilenes) has already been reported, the number of reported conjugation modes between the SiSi double bonds remains... 
CROSS-CONJUGATION | ANALOG | MAIN-GROUP | COPLANAR OLIGO(P-PHENYLENEDISILENYLENE)S | OLIGOSILANES | SIGMA-BONDS | SI DOUBLE-BONDS | MULTIPLE BONDS | SPIROCONJUGATION | CHEMISTRY, MULTIDISCIPLINARY | Usage | Analysis | Alkadienes | Methyl groups | Chemical bonds | Chemical reactions | Chemical properties
Journal Article
Dalton Transactions, ISSN 1477-9226, 2017, Volume 46, Issue 34, pp. 11271 - 11281
Although many stable disilenes (silicon-silicon doubly-bonded compounds) containing organic pi-electron systems have been reported, stable disilenes with... 
ANALOGS | COMPOUND | COPLANAR OLIGO(P-PHENYLENEDISILENYLENE)S | REACTIVITY | STABLE DISILENES | SI DOUBLE-BONDS | MULTIPLE BONDS | ORGANIC SEMICONDUCTORS | DISILYNE | ELECTROLUMINESCENCE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2015, Volume 21, Issue 40, pp. 14011 - 14021
To get information about the reactivity profile of the donor‐stabilized guanidinatosilicon(II) complexes 2 and 3, a series of oxidative addition reactions was... 
tellurium | sulfur | selenium | silicon compounds | silylenes | Solid state | Nuclear magnetic resonance--NMR | Benzene | Silicon | Nitrous oxide | Coordination compounds | Tellurium | Crystal structure
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2017, Volume 139, Issue 50, pp. 18146 - 18149
The push–pull effect has been widely used to effectively tune π-electron systems. Herein, we report the synthesis and properties of 1-amino-2-boryldisilene 1... 
ACTIVATION | DISILYNE RSISIR R | DIHYDROGEN | SINGLE BOND | MOLECULE | COPLANAR OLIGO(P-PHENYLENEDISILENYLENE)S | SI DOUBLE-BONDS | BORYL-SUBSTITUTED DISILENES | MULTIPLE BONDS | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 02/2016, Volume 45, Issue 4, pp. 900 - 921
Heavier group 14 multiple bonds have intrigued chemists since more than a century. The synthesis of stable compounds with double and triple bonds with silicon,... 
SILICON-COMPOUNDS | INFRARED-SPECTRA | DISILYNE RSISIR R | SI=SI DOUBLE-BONDS | FREE GERMYL CATION | INTRAMOLECULAR STERIC INTERACTIONS | STABILIZED LEAD(II) DERIVATIVES | SIMPLE ORGANIC GROUPS | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | SUBSTITUTED DISILENES
Journal Article
Science, ISSN 0036-8075, 10/2000, Volume 290, Issue 5491, pp. 504 - 506
In contrast to carbon, silicon does not readily form double bonds, and compounds containing silicon-silicon double bonds can usually be stabilized only by... 
Molecules | Spectroscopy | Orbitals | Alkenes | Atoms | Molecular orbitals | Reports | Silicon | Dimers | Chemical bonding | Dienes | AROMATICITY | SI DOUBLE-BONDS | MULTIDISCIPLINARY SCIENCES | SILICON | Complex compounds | Research | Nuclear magnetic resonance | Chemical bonds | Spectrum analysis
Journal Article
Organometallics, ISSN 0276-7333, 03/2018, Volume 37, Issue 5, pp. 632 - 635
The versatile reactivity of disilenides, heavier analogues of vinyl anions, opened the door to novel heavier group 14 structure motifs with residual... 
ANIONS | SI=SI DOUBLE-BONDS | GERMANIUM | REDUCTION | DIANION | DISILENIDES | TIN | CHEMISTRY, ORGANIC | SILICON ANALOG | CLEAVAGE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 2/2016, Volume 45, Issue 4, pp. 9 - 921
Heavier group 14 multiple bonds have intrigued chemists since more than a century. The synthesis of stable compounds with double and triple bonds with silicon,... 
Transition metals | Chemists | Chemical bonds | Transformations | Bonding | Isomers | Functional groups | Alkynes
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 07/2017, Volume 46, Issue 27, pp. 8839 - 8848
A series of aryl disilenes Tip(2)Si=Si(Tip)Ar (2a-c) and para-arylene bridged tetrasiladienes, Tip(2)Si=Si(Tip)-LU-Si(Tip)=SiTip(2) (3a-d) are synthesized by... 
POLYMERS | ELEMENTS | ORGANIC-MOLECULES | 9,9-BIANTHRYL | MOLECULAR-ORBITAL METHODS | COPLANAR OLIGO(P-PHENYLENEDISILENYLENE)S | GAUSSIAN-TYPE BASIS | SI DOUBLE-BONDS | CHARGE-TRANSFER | MULTIPLE BONDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 07/2017, Volume 46, Issue 27, pp. 8839 - 8848
A series of aryl disilenes Tip Si[double bond, length as m-dash]Si(Tip)Ar (2a-c) and para-arylene bridged tetrasiladienes, Tip Si[double bond, length as... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2016, Volume 138, Issue 33, pp. 10421 - 10424
The NHC-stabilized silicon–carbon mixed cumulene (Me3Si)2CSi­(IPr)Si­(IPr)C­(SiMe3)2 (3, IPr = 1,3-diisopropyl-4,5-dimethyl-imidazol-2-ylidene) has been... 
N-HETEROCYCLIC CARBENE | DISILYNE RSISIR R | MOLECULE | DOUBLE-BONDS | STABLE COMPOUND | REACTIVITY | CHEMISTRY | TRIPLE BOND | CHEMISTRY, MULTIDISCIPLINARY | SUBSTITUTED DISILENES | SI=SI
Journal Article
Organometallics, ISSN 0276-7333, 03/2013, Volume 32, Issue 6, pp. 1591 - 1594
The reaction of cyclotrisilenes 1 with 1 equiv of alkyl and aryl isocyanides at 25 °C affords the four-membered trisilacyclobutenes 2 with an exocyclic imine... 
ELEMENTS | CARBENE | DISILYNE RSISIR R | DOUBLE-BONDS | COMPOUND | SILICON | REACTIVITY | CHEMISTRY | CHEMISTRY, ORGANIC | CYCLOPROPENES | SI-SI | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 60, pp. 8399 - 8402
1,2,3-Trisilacyclopentadienes are obtained from the reactions of cyclotrisilene c-Si3R4 (R = iPr3C6H2) with phenyl and diphenyl acetylene, respectively. With... 
DISILENYL SILYLENE | MOLECULAR-ORBITAL METHODS | DOUBLE-BONDS | CRYSTAL-STRUCTURE | GROUP 14 ELEMENTS | REACTIVITY | STABLE DISILENES | BASIS-SETS | MULTIPLE BONDS | SI=SI BONDS | CHEMISTRY, MULTIDISCIPLINARY | Nuclear magnetic resonance--NMR | Conjugation | Benzene | Acetylene
Journal Article