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Accounts of Chemical Research, ISSN 0001-4842, 08/2012, Volume 45, Issue 8, pp. 1365 - 1377
Journal Article
Organic Letters, ISSN 1523-7060, 08/2018, Volume 20, Issue 15, pp. 4672 - 4676
A catalytic, metal-free O–H bond insertion of α-diazoesters in water in the presence of B­(C6F5)3·nH2O (2 mol %) was developed, affording a series of... 
FUNCTIONALIZATION | ACID | SI-H | CHEMISTRY, ORGANIC | METAL-FREE HYDROGENATION | FRUSTRATED LEWIS PAIRS | B(C6F5)-CATALYZED TRANSFER | CARBENOID INSERTION | DIRECT MANNICH | AROMATIC C-H | FACILE PROTOCOL
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2008, Volume 47, Issue 5, pp. 932 - 934
Taking on water: A novel catalytic asymmetric metal–carbenoid insertion reaction with water has been developed with copper complexes of chiral spiro... 
carbenoids | hydroxyesters | insertion | asymmetric catalysis | water | Water | Insertion | Carbenoids | Hydroxyesters | Asymmetric catalysis | SI-H | ESTERS | BONDS | CHEMISTRY, MULTIDISCIPLINARY | DIAZOCARBONYL | Copper - chemistry | Esters - chemistry | Stereoisomerism | Water - chemistry | Molecular Structure | Catalysis | Esters - chemical synthesis | Spiro Compounds - chemistry
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 10/2019, Volume 2019, Issue 37, pp. 6347 - 6351
The effect of tethering a thioether to a rhodium(II) paddlewheel complex are evaluated in Si–H insertion reactions. This study provides further evidence for... 
Insertion | Rhodium | Coordination modes | S ligands | MECHANISM | COMPLEXES | CHEMISTRY, ORGANIC | TRANS INFLUENCE | CATALYST | SI-H INSERTION | CARBENOID INSERTION | RH-RH BOND | STEREOSELECTIVITY | DIAZO ESTERS | CHEMISTRY | Diazo compounds | Hydrogen | Analysis
Journal Article
Organic Letters, ISSN 1523-7060, 07/2018, Volume 20, Issue 13, pp. 4086 - 4089
Supported Au nanoparticles on TiO2 catalyze the insertion of carbenes from α-diazocabonyl compounds into hydrosilanes. It is proposed that the transformation... 
HYDROGENATION | MECHANISM | BONDS | HYDROSILYLATION | DIAZO ESTERS | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | NANOPOROUS GOLD CATALYST | 1,1,3,3-TETRAMETHYLDISILOXANE | ALKYNES | SI-H INSERTION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2017, Volume 56, Issue 27, pp. 7930 - 7934
Allylsilanes have long been recognized as valuable building blocks for organic synthesis. A zinc‐catalyzed reaction of cyclopropenes and hydrosilanes provides... 
carbenes | silanes | zinc catalysis | cyclopropenes | Si-H bond functionalization | ACTIVATION | REAGENTS | HYDROSILYLATION | CYCLOPROPANATION | HOSOMI-SAKURAI REACTION | CHEMISTRY, MULTIDISCIPLINARY | ENANTIOSELECTIVE RH(II) | CHEMISTRY | ALLYLIC SUBSTITUTION | ACCESS | Bonds | Silane | Catalysis | Transformation | Hydrogen bonds | Catalysts | Insertion | Polysiloxanes | Chemical synthesis | Zinc | Organic compounds
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 07/2017, Volume 15, Issue 26, pp. 5441 - 5456
The following review will explore the historical development of Si-H bond insertion reactions, giving an up-to-date account on the metal catalysts often... 
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 2017, Volume 835, pp. 1 - 5
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2016, Volume 138, Issue 7, pp. 2086 - 2089
The unexpectedly facile insertion of Rh or Ir into a B–Ph bond (reversible for Rh) converts a borane/bis­(phosphine) precursor into a boryl/bis­(phosphine) PBP... 
ACTIVATION | RHODIUM | LEWIS-ACID | IRIDIUM COMPLEXES | SI-H | REACTIVITY | METAL | LIGAND | BORANE | OLEFIN | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
by He, FF and Li, F and Koenigs, RM
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 01/2020, Volume 85, Issue 2, pp. 1240 - 1246
Si-H insertion reactions represent an important method for the efficient construction of new C-Si bonds, and typically, they are conducted in the presence of... 
ENANTIOSELECTIVE RH(II) | CATALYZED INSERTION | CARBENE INSERTION | CHEMISTRY, ORGANIC | BOND INSERTION | ALPHA-DIAZOESTERS | ALKYNES | SI-H INSERTION | TRANSFORMATIONS
Journal Article
ACS CATALYSIS, ISSN 2155-5435, 06/2019, Volume 9, Issue 6, pp. 5353 - 5357
Enantioselective transition-metal-catalyzed carbene insertion into Si-H bonds is a promising method for preparing chiral organosilicons; however, all the... 
chiral organosilicons | ORGANIC-SYNTHESIS | DIRHODIUM(II) | ACTIVATION | ASYMMETRIC-SYNTHESIS | CARBON | alkynes | SILICON | CHEMISTRY, PHYSICAL | Si-H bond insertion | asymmetric synthesis | CONSTRUCTION | rhodium carbenes | OXO GOLD CARBENES | HIGHLY ENANTIOSELECTIVE HYDROSILYLATION | C-H
Journal Article
Dalton Transactions, ISSN 1477-9226, 01/2013, Volume 42, Issue 4, pp. 1191 - 1195
The catalytic functionalization of silicon-hydrogen bonds by means of the insertion of carbene units : CHCO2Et from ethyl diazoacetate (EDA) has been achieved... 
ACTIVATION | MECHANISM | HYDROCARBONS | COMPLEXES | ALPHA-(ALKOXYSILYL)ACETIC ESTERS | COPPER | SI-H BOND | CHEMISTRY, INORGANIC & NUCLEAR | Catalysts | Insertion | Transformations | Carbenes | Bonding | Heat of formation | Conversion | Free energy
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 12/2019, Volume 48, Issue 47, pp. 17472 - 17478
The reactivity of a bicyclic (alkyl)(amino)carbene (BICAAC) towards different boranes has been examined in the present work. The reactions with boranes BX3... 
CYCLIC ALKYL(AMINO) CARBENE | ACTIVATION | INTRAMOLECULAR HYDROIMINIUMATION | BORYL RADICALS | STABLE CARBENES | SI-H | ALKYL AMINO CARBENES | N-HETEROCYCLIC CARBENES | BORANE COMPLEXES | C-H | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organic and Biomolecular Chemistry, ISSN 1477-0520, 7/2017, Volume 15, Issue 26, pp. 5441 - 5456
The following review will explore the historical development of Si-H bond insertion reactions, giving an up-to-date account on the metal catalysts often... 
FUNCTIONALIZATION | ENANTIOSELECTIVE RH(II) | ORGANIC-SYNTHESIS | DIAZOACETATE | DIAZO ESTERS | CHEMISTRY, ORGANIC | ALPHA-(ALKOXYSILYL)ACETIC ESTERS | ALLYLSILANES | METALLOPEPTIDES | SI-H BOND | C-H
Journal Article
Research on Chemical Intermediates, ISSN 0922-6168, 11/2017, Volume 43, Issue 11, pp. 6447 - 6504
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2006, Volume 128, Issue 50, pp. 16038 - 16039
Vinylcarbenes are versatile synthetic intermediates, capable of asymmetric cyclopropanation and insertion into unactivated C−H bonds. The vinyldiazolactone... 
REARRANGEMENT | DIRHODIUM(II) | ACTIVATION | ASYMMETRIC-SYNTHESIS | ANNULATION | 7-MEMBERED RINGS | SI-H | CONSTRUCTION | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | TRANSFORMATIONS | Alkenes - chemistry | Vinyl Compounds - chemistry | Cyclization | Molecular Structure | Catalysis | Hydrogen - chemistry | Carbon - chemistry | Lactones - chemistry | Propane - chemistry
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 01/2013, Volume 42, Issue 4, pp. 1191 - 1195
The catalytic functionalization of silicon-hydrogen bonds by means of the insertion of carbene units :CHCO(2)Et from ethyl diazoacetate (EDA) has been achieved... 
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 07/2018, Volume 867, pp. 86 - 91
The cyclobutadiene rhodium complex [(C4Et4)RhCl]2 (generated from [(C4Et4)Rh(p-xylene)]PF6 and BnNEt3Cl) catalyzes the reaction of methyl α-diazophenylacetate... 
Cyclobutadiene | Carbene | Diazo compound | Catalysis | Rhodium | Pi-complex | CYCLOPROPANATION | CHEMISTRY, ORGANIC | CHEMISTRY, INORGANIC & NUCLEAR | SI-H | DERIVATIVES | EFFICIENT | ACCESS | C-H | Diazo compounds | Paraxylene | Olefins | Bonds | Chemical properties
Journal Article
Chemical Communications, ISSN 1359-7345, 07/2014, Volume 50, Issue 52, pp. 6839 - 6842
A new triangular triplatinum(0) complex with bridging diphenyl-germylene ligands, [{Pt( PMe3)}(3)(mu-GePh2)(3)], undergoes insertion of ZC CZ (Z = COOMe) into... 
FLUXIONAL BEHAVIOR | MODELS | CLUSTER COMPLEXES | MOLECULAR-STRUCTURE | ACETYLENE | CRYSTAL-STRUCTURE | CARBONYL CLUSTERS | PHENYLGERMYL LIGANDS | SI-H | PLATINUM | CHEMISTRY, MULTIDISCIPLINARY | Chelating | Planes | Bridging | Insertion | Chemical bonds | Ligands | Alkynes
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 05/2017, Volume 835, pp. 1 - 5
A catalytic system comprising copper(I) and macrocyclic pyridine-containing ligands (Pc-L) proves capable of promoting carbene SiH bond insertions using diazo... 
Macrocyclic ligands | Si–H bond insertions | Diazoalkanes | Pyridine-containing ligands | Copper complexes | Diazo compounds | Alkaloids | Pyridine | Copper
Journal Article
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