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chemistry, multidisciplinary (70) 70
silane alcoholysis (66) 66
silane (62) 62
silanes (60) 60
chemistry, organic (55) 55
catalysis (54) 54
hydrosilylation (42) 42
alcoholysis (36) 36
chemistry, inorganic & nuclear (36) 36
silicon (36) 36
homogeneous catalysis (33) 33
chemistry (32) 32
silanes - chemistry (28) 28
complexes (25) 25
alcohols (24) 24
hydrosilanes (24) 24
polymer science (23) 23
chemical properties (21) 21
polymers (19) 19
analysis (18) 18
molecular structure (18) 18
chemistry, physical (17) 17
alkoxysilanes (16) 16
catalysts (16) 16
derivatives (16) 16
index medicus (16) 16
organosilanes (16) 16
silylation (16) 16
activation (15) 15
ligands (15) 15
hydrolysis (14) 14
nanoparticles (14) 14
polymerization (14) 14
reduction (14) 14
rhodium (14) 14
carbonyl-compounds (13) 13
ethers (13) 13
hydrogen (13) 13
silyl ethers (13) 13
chemical reactions (12) 12
materials science, multidisciplinary (12) 12
conversion (11) 11
nanocomposites (11) 11
organic chemistry (11) 11
reactivity (11) 11
silicon compounds (11) 11
synthesis (11) 11
chemistry, applied (10) 10
crystal-structure (10) 10
alcohols - chemistry (9) 9
dehydrogenation (9) 9
hydrosilation (9) 9
ketones (9) 9
kinetic resolution (9) 9
mechanism (9) 9
organosilicon compounds (9) 9
research (9) 9
rhodium complexes (9) 9
silanes - chemical synthesis (9) 9
siloxanes (9) 9
alkynes (8) 8
carbon (8) 8
functionalization (8) 8
heterogeneous catalysis (8) 8
hydrogenation (8) 8
inorganic chemistry (8) 8
kinetics (8) 8
nuclear magnetic resonance spectroscopy (8) 8
oxidation (8) 8
poly (8) 8
ruthenium (8) 8
silan (8) 8
silicium (8) 8
siloxane (8) 8
alcohol (7) 7
aldehydes (7) 7
alkohole (7) 7
carboxylic-acids (7) 7
catalyst (7) 7
cleavage (7) 7
hydrides (7) 7
katalyse (7) 7
mechanical properties (7) 7
mild (7) 7
nanostructure (7) 7
nanotechnology (7) 7
oxidative addition (7) 7
route (7) 7
solvents (7) 7
stereochemistry (7) 7
transition-metal-complexes (7) 7
allylation (6) 6
carbon-dioxide (6) 6
catalytic silane alcoholysis (6) 6
coatings (6) 6
complex (6) 6
dehydrocoupling (6) 6
dehydrogenative coupling (6) 6
dendrimers (6) 6
ethanol (6) 6
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Journal of the American Chemical Society, ISSN 0002-7863, 08/2006, Volume 128, Issue 33, pp. 10664 - 10665
The activation of alkynyl allyl silanes with a cationic gold catalyst in the presence of alcohols provides vinyl silanes that contain the allyl group at the... 
ORGANIC-SYNTHESIS | CROSS-METATHESIS | 1,6-ENYNES | SEQUENCE | HOMOGENEOUS CATALYSIS | CYCLOISOMERIZATION | OLEFIN METATHESIS | ALLYLSILANES | CHEMISTRY, MULTIDISCIPLINARY | ENYNES | Gold - chemistry | Silanes - chemistry | Alkynes - chemistry | Molecular Structure | Catalysis | Gold compounds | Allylic compounds | Chemical properties | Electric properties
Journal Article
Catalysis Science & Technology, ISSN 2044-4753, 03/2015, Volume 5, Issue 4, pp. 2157 - 2166
.... Our results suggested that the oxorhenium(v) complex 1-catalyzed hydrolysis/alcoholysis of silanes proceeds viathe ionic out-sphere mechanistic pathway... 
Silanes | Hydrolysis | Pathways | Catalysts | Methyl alcohol | Hydrides | Rhenium | Catalysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2003, Volume 125, Issue 21, pp. 6366 - 6367
Tetramethylsilane reacts with 2,2,2-trifluoroethanol (TFE) in the presence of a cationic platinum(II) catalyst [(NN)PtMe(TFE)]+ (NN =... 
SILYL COMPLEXES | METHANE | ALKYL | THERMOLYTIC REARRANGEMENT | OXIDATIVE ADDITION | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | Alcohols - chemistry | Silanes - chemistry | Catalysis | Trimethylsilyl Compounds | Platinum - chemistry | Thermodynamics | Chemical reactions | Research | Observations | Silane | Methyl groups
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2003, Volume 125, Issue 5, pp. 1190 - 1191
A new asymmetric synthesis of chiral silanes has been developed. Chiral phosphine-modified copper complexes catalyze the alcoholysis of prochiral dihydrosilanes with good to excellent stereoselectivity at silicon... 
TEMPORARY SILICON CONNECTION | RHODIUM COMPLEXES | CONJUGATE REDUCTION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | STEREOCHEMISTRY | Alcohols - chemistry | Alkenes - chemistry | Alkynes - chemistry | Catalysis | Stereoisomerism | Silanes - chemical synthesis | Silane | Chemical properties
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 10/2013, Volume 52, Issue 20, pp. 12108 - 12119
9,9-Dimethyl-4,5-bis(diisopropyl­phosphino)­xanthene (xant(PiPr2)2) derivatives RhCl­{xant(PiPr2)2} (1) and IrHCl{xant(PiPr2)[iPrPCH(Me)CH2]} (2) react with... 
CATALYSIS | SILANE ALCOHOLYSIS | DEHALOGENATION | SI-H | REACTIVITY | MECHANISTIC INSIGHT | LIGAND | HYDROSILATION | OXIDATIVE ADDITION | ALKYL-HALIDES | CHEMISTRY, INORGANIC & NUCLEAR | Rhodium | Chemical properties | Iridium
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2009, Volume 131, Issue 3, pp. 908 - 909
New Imido hydride complex 1 catalyzes a variety of silylation reactions that proceed via initial substrate activation but not silane addition. 
KETONES | ACTIVATION | RHODIUM | REDUCTION | NITRILES | HOMOGENEOUS CATALYSIS | OLEFINS | CHIRAL TITANOCENE CATALYST | HYDROSILATION | CHEMISTRY, MULTIDISCIPLINARY | METAL-COMPLEXES | Chemical properties | Catalysis | Aldehydes | Molybdenum | Analysis | Silane
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2012, Volume 134, Issue 42, pp. 17462 - 17465
Journal Article
Chemistry of Materials, ISSN 0897-4756, 06/2010, Volume 22, Issue 11, pp. 3549 - 3555
Nonhydrolytic sol−gel condensation for the synthesis of nanosized inorganic−organic hybrid resin and hydrosilylation reaction under a Pt catalyst for the... 
Optical Materials (including Non-Linear Optic, Photonic, and Optoelectronic Materials) | Hybrid Inorganic/Organic Materials | Sol−Gel Chemistry/Processing | SILANE ALCOHOLYSIS | NANOCOMPOSITES | ROUTES | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | HOMOGENEOUS CATALYSIS | DEGRADATION
Journal Article
ACS Catalysis, ISSN 2155-5435, 07/2011, Volume 1, Issue 7, pp. 698 - 702
...)phenylborate) catalyzes selective alcoholysis of substituted hydrosilanes. The catalytic reaction of PhMeSiH2 and aliphatic alcohols favors the monodehydrocoupled product PhMeHSi... 
alkoxysilane | oxazoline | Silane alcoholysis | zinc hydride | dehydrocoupling | ACTIVATION | CONVERSION | HYDROSILANES | HYDROSILYLATION | COMPLEXES | REACTIVITY | CHEMISTRY, PHYSICAL | SILYLATION | REDUCTION | silane alcoholysis | DERIVATIVES | POLYMETHYLHYDROSILOXANE
Journal Article
Synlett, ISSN 0936-5214, 03/2018, Volume 29, Issue 4, pp. 388 - 396
Abstract It is highly important to develop efficient synthetic methods for various enantioenriched chiral compounds due to their high significance in our life.... 
account | enantioselective desymmetrization | asymmetric catalysis | silicon stereocenters | tetraorganosilanes | dihydrosilanes | ASYMMETRIC-SYNTHESIS | CARBON | HYDROSILYLATION | DIBENZOSILOLES | CHEMISTRY, ORGANIC | SILYLATION | SILACYCLOBUTANES | SILANES | CONSTRUCTION | ACCESS | ALCOHOLYSIS
Journal Article
Synthesis, ISSN 0039-7881, 10/2004, Volume 2004, Issue 14, pp. 2273 - 2276
ABSTRACT A mild method for the synthesis of unsymmetrical bis-alkoxysilanes has been developed. This method utilizes two readily available catalysts (rhodium... 
paper | Alcoholysis | Alkoxysilanes | Silyl ketals | Unsymmetrical | Hydridosilanes | alkoxysilanes | ROUTE | SILANE ALCOHOLYSIS | RHODIUM | silyl ketals | unsymmetrical | hydridosilanes | CYCLOADDITIONS | CHEMISTRY, ORGANIC | TETHERS | alcoholysis
Journal Article
ACS Catalysis, ISSN 2155-5435, 03/2017, Volume 7, Issue 3, pp. 1720 - 1727
Direct coupling of Si–H bonds has emerged as a promising strategy for designing chemically and biologically useful organosilicon compounds. Heterogeneous... 
hydrophobicity | Pd nanoparticles | heterogeneous catalysis | organosilanes | dehydrocoupling | SELECTIVE OXIDATION | NANOTUBE-GOLD NANOHYBRIDS | HYDROGEN GENERATION | TERTIARY-AMINES | CHEMISTRY, PHYSICAL | BOND FORMATION | HYDROLYTIC OXIDATION | SILANE ALCOHOLYSIS | SODIUM-CYANIDE | METAL NANOPARTICLES
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2010, Volume 51, Issue 34, pp. 4573 - 4575
The silylation of primary alcohols was achieved using hydrosilanes and a recyclable ruthenium catalyst without additives under mild conditions. Notably, this... 
CHEMISTRY, ORGANIC | SILANE ALCOHOLYSIS | MECHANISM | KINETIC RESOLUTION | Ruthenium
Journal Article
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, ISSN 0037-9980, 11/2018, Volume 76, Issue 11, pp. 1163 - 1169
Asymmetric catalysis is one of the most attractive and efficient approaches toward synthesis of chiral enantioenriched compounds using achiral compounds as... 
SILACYCLOBUTANES | SILANES | HYDROSILYLATION | CONSTRUCTION | COMPLEXES | DIBENZOSILOLES | CHEMISTRY, ORGANIC | 2+2+2 CYCLOADDITION | ORGANOSILICON COMPOUNDS | SILYLATION | ALCOHOLYSIS
Journal Article
Arkivoc, ISSN 1551-7004, 08/2016, Volume 2016, Issue 4, pp. 371 - 384
Some new branched polysilyl ethers with a ferrocene core were synthesized through treatment of 1,1'-bis[tris(dimethylsilyl)methyl] alkylferrocenes with various... 
Dehydrocoupling | Alcoholysis | Silyl ether | Silane | Ferrocene | POLYMERS | DENDRITIC CARBOSILANES | silyl ether | dehydrocoupling | HYDROSILYLATION | COMPLEXES | CHEMISTRY, ORGANIC | DENDRIMERS | alcoholysis | CYCLIC SILOXANES | FUNCTIONALIZATION | MILD | silane | CHEMISTRY
Journal Article
Synthesis, ISSN 0039-7881, 1999, Volume 1999, Issue 11, pp. 1931 - 1936
The preparation of linear, linear terminal branched as well as branched first and second generation carbosiloxane dendrimers by repetitive hydrosilylation-alcoholysis cycles, starting from Si(OCH2CH=CH2)(4) (1... 
paper | Alcoholysis | Hydrosilylation | Silicon | Carbosiloxane dendrimers | Alcohols | Divergent growth method | silicon | SILANE DENDRIMERS | COMPLEXES | carbosiloxane dendrimers | hydrosilylation | CHEMISTRY | CHEMISTRY, ORGANIC | CASCADE DENDRIMERS | alcohols | alcoholysis | divergent growth method
Journal Article
Chemistry : a European journal, ISSN 1521-3765, 2018, Volume 25, Issue 3, pp. 728 - 732
Journal Article
Canadian Journal of Chemistry, ISSN 1480-3291, 05/2001, Volume 79, Issue 5-6, pp. 949 - 957
The dimeric complex Ru2(µ-Cl)2Cl2(CO)4(PMe3)2 (1) forms an active silane alcoholysis complex in the polar solvent N,N-dimethylamino-acetamide (DMA... 
silane alcoholysis | alcoolyse de silanes | solvant polaire | ruthenium catalyst | polar solvent | catalyseur de ruthénium
Journal Article
Catalysis Science and Technology, ISSN 2044-4753, 2016, Volume 6, Issue 11, pp. 3886 - 3892
A Mn(V)-salen complex was found to be an effective catalyst for the dehydrogenative coupling of hydroxyl groups with hydrosilane. The reaction conditions were... 
SILANE ALCOHOLYSIS | ETHERS | MOLECULAR-WEIGHT | REDUCTION | HYDROSILYLATION | SILYL ESTERS | CHEMISTRY, PHYSICAL | CARBONYL-COMPOUNDS | IRON CATALYSTS | POLY(SILYL ESTER)S | HEXAMETHYLDISILAZANE
Journal Article
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