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Organic Letters, ISSN 1523-7060, 11/2017, Volume 19, Issue 21, pp. 5736 - 5739
An efficient iron-catalyzed carbene insertion reaction of α-diazo carbonyl compounds into the Si–H bond was developed. A wide range of α-silylesters was... 
FUNCTIONALIZATION | ORGANIC-SYNTHESIS | DIAZOACETATES | PALLADIUM | PORPHYRINS | DIAZO ESTERS | CHEMISTRY, ORGANIC | O-H | EFFICIENT | ENANTIOSELECTIVE INSERTION | C-H
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9226, 11/2015, Volume 44, Issue 44, pp. 19344 - 19356
A platinum-catalyzed amide reduction through hydrosilylation with 1,2-bis(dimethylsilyl)benzene (BDSB) was investigated on a theoretical basis. While the... 
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 01/2012, Volume 18, Issue 2, pp. 652 - 658
Rhodium(III) complexes comprising monoanionic C,C,C‐tridentate dicarbene ligands activate SiH bonds and catalyse the hydrolysis of hydrosilanes to form... 
carbenes | silane activation | ligand cooperativity | mesoionic complexes | siloxanes | rhodium | COORDINATION CHEMISTRY | SILICON-HYDROGEN | BUILDING-BLOCKS | CARBONYL-COMPOUNDS | HETEROGENEOUS CATALYSIS | N-HETEROCYCLIC CARBENES | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | SILANE ALCOHOLYSIS | DONOR LIGANDS | HOMOGENEOUS CATALYSIS
Journal Article
Organometallics, ISSN 0276-7333, 12/2007, Volume 26, Issue 25, pp. 6277 - 6289
Laser flash photolysis studies have been carried out with the goal of comparing the reactivities of dimethyl- and diphenylsilylene (SiMe2 and SiPh2,... 
HALOPHILIC REACTIONS | GAS-PHASE REACTION | CARBENE ANALOGS | SILICON-HYDROGEN | AB-INITIO | INSERTION REACTIONS | CHEMISTRY, ORGANIC | ABSOLUTE RATE CONSTANTS | SPECTROSCOPIC OBSERVATION | ORGANOSILICON COMPOUNDS | SINGLET GERMYLENE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 02/2010, Volume 29, Issue 3, pp. 662 - 670
The kinetic behavior of dimethyl-, diphenyl-, and dimesitylsilylene in hexanes solution in the presence of methanol (MeOH), tert-butanol (t-BuOH), and the... 
LASER FLASH-PHOTOLYSIS | CL-H BONDS | SILICON-HYDROGEN | 2-CONSTANT MODEL | RATE CONSTANTS | AB-INITIO | CHEMISTRY, ORGANIC | PROTON-TRANSFER | GAS-PHASE REACTIONS | SINGLET GERMYLENE | OXYGEN-HYDROGEN | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 07/2007, Volume 26, Issue 15, pp. 3807 - 3815
The addition of the ambiphilic compound (Me2PCH2AlMe2)2 (1) to Cp*RhMe2(DMSO) (DMSO = dimethylsulfoxide) (2) gives Cp*RhMe2(PMe2CH2AlMe2·DMSO) (3·DMSO). The... 
SATURATED-HYDROCARBONS | HYDROGEN-BOND ACTIVATION | SILICON-HYDROGEN | ORGANIC-COMPOUNDS | OLEFIN POLYMERIZATION | CHEMISTRY, ORGANIC | OXIDATIVE ADDITION | C-H ACTIVATION | REDUCTIVE ELIMINATION | LOW-TEMPERATURE | HYDRIDE COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Organometallics, ISSN 0276-7333, 10/2006, Volume 25, Issue 22, pp. 5424 - 5434
The reactions of methanol, tert-butanol, and THF with a series of simple germylene derivativesdimethyl- (GeMe2), diphenyl- (GePh2), and dimesitylgermylene... 
SILYLENE | LASER FLASH-PHOTOLYSIS | ARYL-SUBSTITUTED DIGERMANES | GERMYLENE INSERTION | SILICON-HYDROGEN | RATE CONSTANTS | CHEMISTRY, ORGANIC | DIMETHYLSILYLENE | PHOTOCHEMICAL-REACTIONS | GAS-PHASE REACTIONS | OXYGEN-HYDROGEN | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical communications (Cambridge, England), ISSN 1364-548X, 2018, Volume 54, Issue 81, pp. 11419 - 11422
Pd(0)-Catalyzed formal carbene insertion into Si–H bonds has been achieved as an efficient method for C(sp 3 )–Si bond formation. Pd(0)-Catalyzed formal... 
REAGENTS | CATALYZED INSERTION | SILANES | HYDROSILYLATION | COMPLEXES | DIAZO-COMPOUNDS | SILICON-HYDROGEN BOND | ALPHA-DIAZOESTERS | GE BONDS | CHEMISTRY, MULTIDISCIPLINARY | N-TOSYLHYDRAZONES
Journal Article
physica status solidi (RRL) – Rapid Research Letters, ISSN 1862-6254, 01/2015, Volume 9, Issue 1, pp. 53 - 56
Journal Article
Organic Letters, ISSN 1523-7060, 10/2018, Volume 20, Issue 20, pp. 6544 - 6549
The first iron-catalyzed enantioselective Si–H bond insertion reaction of α-diazoesters was developed. A new chiral spiro-bisoxazoline ligand has proven to be... 
ORGANIC-SYNTHESIS | ASYMMETRIC-SYNTHESIS | OPTICAL RESOLUTION | CHEMISTRY, ORGANIC | CHIRAL ORGANOSILICON COMPOUNDS | SILICON-HYDROGEN BOND | INCLUSION CRYSTALLIZATION | BISOXAZOLINE LIGANDS | OXIDATIVE ADDITION | CARBENOID INSERTION | C-H
Journal Article
The Journal of Physical Chemistry A, ISSN 1089-5639, 05/2011, Volume 115, Issue 17, pp. 4231 - 4240
Journal Article
Chemistry Letters, ISSN 0366-7022, 9/2015, Volume 44, Issue 9, pp. 1217 - 1219
Hydrosilylation of CO2 catalyzed by simple fluoride and carbonate salts, such as CsF and K2CO3, is described. Total yields up to 87% for the formylated product... 
CHEMOSELECTIVE HYDROSILYLATION | MECHANISTIC ASPECTS | FORMIC-ACID | N-HETEROCYCLIC CARBENE | SILICON HYDROGEN | DIOXIDE | DIPHOSPHINE COMPLEX | 1 ATM | HETEROGENEOUS CATALYSIS | SELECTIVE REDUCTION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Hongwai yu Jiguang Gongcheng/Infrared and Laser Engineering, ISSN 1007-2276, 08/2016, Volume 45, Issue 8
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2009, Volume 131, Issue 31, pp. 11161 - 11173
Journal Article
Dalton Transactions, ISSN 1477-9226, 10/2015, Volume 44, Issue 44, pp. 19344 - 19356
A platinum-catalyzed amide reduction through hydrosilylation with 1,2-bis(dimethylsilyl) benzene (BDSB) was investigated on a theoretical basis. While the... 
KETONES | SELF-ENCAPSULATION | COMPLEX | MOLECULAR-ORBITAL METHODS | SILICON-HYDROGEN | HYDROSILYLATION | CARBONYL-COMPOUNDS | BASIS-SETS | POLARIZATION FUNCTIONS | CHALK-HARROD MECHANISM | CHEMISTRY, INORGANIC & NUCLEAR | Carbonyl groups | Reduction | Platinum | Insertion | Amides | Activation | Hydrosilylation | Bonding
Journal Article
Organometallics, ISSN 0276-7333, 11/2017, Volume 36, Issue 21, pp. 4123 - 4135
Reported here are several new adducts of the type (RBDI)­M­(HE)2 where RBDI is the β-diiminate ligand [2,6-R2C6H3NCMe]2CH (R = Me, Et, MeO; M = Rh, Ir; HE =... 
INTRAMOLECULAR C-H | MOLECULAR CALCULATIONS | EFFECTIVE CORE POTENTIALS | SILICON-HYDROGEN | TRANSITION-METAL | NEUTRON-DIFFRACTION | CHEMISTRY, ORGANIC | OXIDATIVE ADDITION | HYDROGEN BOND ACTIVATION | COUPLING-CONSTANTS | DIKETIMINATE LIGAND | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
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