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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 11/2017, Volume 56, Issue 47, pp. 14903 - 14907
The regioselective conversion of C-H bonds into C-Si bonds is extremely important owing to the natural abundance and non-toxicity of silicon. Classical... 
regioselectivity | PALLADIUM | ACTIVATION | ARENES | reaction mechanisms | CLEAVAGE | C-H SILYLATION | CATALYZED SILYLATION | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | hydrogen bonding | CROSS-COUPLING REACTIONS | C-H activation | silylation | UNACTIVATED PRIMARY | ARYL
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2018, Volume 140, Issue 51, pp. 18032 - 18038
The functionalization of unactivated C­(sp3)–H bonds of aliphatic amines catalyzed by transition-metal complexes is important because amine-based functionality... 
FUNCTIONALIZATION | ACTIVATION | ENANTIOSELECTIVE SILYLATION | DEHYDROGENATIVE SILYLATION | ARYLATION | NITROGEN | UNACTIVATED C(SP)-H | REGIOSELECTIVE SILYLATION | DIRECTING-GROUP | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2016, Volume 55, Issue 51, pp. 15787 - 15791
Aryl(triethyl)silanes are found to undergo cross‐coupling with iodoarenes in the presence of catalytic amounts of CuBr2 and Ph‐Davephos, as well as cesium... 
cross-coupling | silanes | copper | arenes | C−H silylation | FLUORINATED BENZOTHIADIAZOLE | GENERAL-SOLUTION | INTRAMOLECULAR ACTIVATION | BUILDING-BLOCKS | CHEMISTRY, MULTIDISCIPLINARY | POLYMER SOLAR-CELLS | DEHYDROGENATIVE SILYLATION | CONJUGATED POLYMERS | C-H silylation | ARYL HALIDES | ORGANIC ELECTRONICS
Journal Article
Synlett, ISSN 0936-5214, 09/2017, Volume 28, Issue 15, pp. 1873 - 1884
The silicon-based cross-coupling reaction has attracted much attention over recent decades because there are many advantages in using organosilicon compounds.... 
nickel | silylation | organosilicon reagents | cross-coupling | copper | palladium | amination | PALLADIUM-CATALYZED SILYLATION | BIARYL SYNTHESIS | CHEMISTRY, ORGANIC | C-H SILYLATION | WHITE ELECTROLUMINESCENCE | LIGHT-EMITTING-DIODES | DIVERSITY-ORIENTED SYNTHESIS | DEHYDROGENATIVE SILYLATION | ARYL HALIDES | AROMATIC HETEROCYCLES | SILOXANE TRANSFER AGENTS
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2019, Volume 25, Issue 10, pp. 2407 - 2422
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2016, Volume 55, Issue 9, pp. 3204 - 3207
An electrophilic aromatic substitution (SEAr) with a catalytically generated silicon electrophile is reported. Essentially any commercially available... 
Lewis acids | hydrosilanes | C−H activation | Si−H activation | electrophilic substitution | C-H activation | Si-H activation | ACTIVATION | COMPLEX | BENZENE | MECHANISM | BOND-CLEAVAGE | CATALYZED SILYLATION | CHEMISTRY, MULTIDISCIPLINARY | INDOLES | FUNCTIONALIZATION | N-SILYLATION | Substitution reactions | Lewis acid | Protons | Salts | Catalysts | Aromatic compounds | Metals | Silicon | Crafts
Journal Article
Synthesis, ISSN 0039-7881, 08/2015, Volume 47, Issue 16, pp. 2347 - 2366
Abstract Silylation of hydrocarbons is one of the most important transformations due to the diverse application of organosilanes. Continuous progress is being... 
short review | catalytic | C-H activation | silylation | metal-free | siloles | ORGANIC-SYNTHESIS | C(SP)-H BONDS | ACTIVATION | SILICON-CONTAINING COMPOUNDS | IRIDIUM | HYDROSILANES | CHEMISTRY, ORGANIC | CARBON-HYDROGEN BONDS | CLEAVAGE | CATALYZED REGIOSELECTIVE SILYLATION | DEHYDROGENATIVE SILYLATION
Journal Article
Nature Communications, ISSN 2041-1723, 06/2017, Volume 8, Issue 1, p. 15547
The enantioselective silylation of racemic alcohols, where one enantiomer reacts faster than the other, is an alternative approach to established enzymatic and... 
SILICON-STEREOGENIC SILANES | SECONDARY ALCOHOLS | ENANTIOSELECTIVE SILYLATION | ASYMMETRIC SILYLATION | 1,2-DIOLS | PROTECTION | MULTIDISCIPLINARY SCIENCES | STEREOSELECTIVE SILYLATION | DESYMMETRIZATION
Journal Article
by Xiao, GH and Chen, L and Zhou, B and Deng, GB and Gong, J and Liang, Y
ADVANCED SYNTHESIS & CATALYSIS, ISSN 1615-4150, 09/2018, Volume 360, Issue 18, pp. 3477 - 3481
A palladium-catalyzed domino Heck/silylation reaction of acrylamides with hexamethyldisilane is presented. This transformation, which involves the formation of... 
Acrylamides | Hexamethyldisilane | DIRECTED ORTHO-METALATION | SILICON | COMPLEXES | CHEMISTRY, ORGANIC | Palladium | OXIDATIVE ADDITION | C-H SILYLATION | silylation | INTERMOLECULAR SILYLATION | ARYL HALIDES | BONDS | Hexamethyldistannane | CHEMISTRY, APPLIED | HECK REACTION | SI-SI
Journal Article
Synlett, ISSN 0936-5214, 11/2017, Volume 28, Issue 18, pp. 2468 - 2472
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2016, Volume 55, Issue 30, pp. 8723 - 8727
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2017, Volume 139, Issue 33, pp. 11601 - 11609
Incorporating the silicon element into bioactive organic molecules has received increasing attention in medicinal chemistry. Moreover, organosilanes are... 
IRIDIUM PINCER COMPLEXES | UNACTIVATED C(SP)-H BONDS | TRANSITION-METAL CATALYSIS | DEHYDROGENATIVE SILYLATION | ENANTIOSELECTIVE SILYLATION | ORGANIC TRANSFORMATIONS | CARBON/SILICON SWITCH STRATEGY | ACETAL DIRECTING GROUPS | ALKANE DEHYDROGENATION | REGIOSELECTIVE SILYLATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
ACS Catalysis, ISSN 2155-5435, 05/2017, Volume 7, Issue 5, pp. 3152 - 3156
The regioselective silylation of C­(sp3)–H bonds at the benzylic position in 4-alkylpyridines with hydrosilanes is described. The reaction proceeds in the... 
4-alkylpyridine | hydrosilane | silylation | C-H functionalization | iridium catalyst | PALLADIUM | TRANSITION-METAL-COMPLEXES | ARENES | CHEMISTRY, PHYSICAL | PYRIDINES | AROMATIC-SUBSTITUTION | C-H SILYLATION | DIHYDROGEN COMPLEXES | FUNCTIONALIZATION | DEHYDROGENATIVE SILYLATION | BOND ACTIVATION
Journal Article
Organic Letters, ISSN 1523-7060, 11/2016, Volume 18, Issue 21, pp. 5536 - 5539
The first example of site-selective silylation of C­(sp3)–H bonds mediated by a [1,5]-hydrogen transfer is reported. This reaction occurs selectively at the... 
FUNCTIONALIZATION | NICKEL/MAGNESIUM BIMETALLIC COOPERATION | UNACTIVATED C(SP)-H BONDS | CATALYZED ENANTIOSELECTIVE SILYLATION | DEHYDROGENATIVE SILYLATION | NICKEL | HYDROSILANES | CHEMISTRY, ORGANIC | REGIOSELECTIVE SILYLATION | CLEAVAGE | GRIGNARD-REAGENTS
Journal Article
Tetrahedron, ISSN 0040-4020, 08/2019, Volume 75, Issue 31, pp. 4059 - 4070
The functionalization of primary C–H bonds has been a longstanding challenge in catalysis. Our group has developed a series of silylations of primary C–H bonds... 
Natural product | Oxidation | Iridium | Silylation | C–H bond functionalization | ACTIVATION | DIRECTED HYDROXYLATION | HYDROSILANES | CHEMISTRY, ORGANIC | REGIOSELECTIVE SILYLATION | C-H bond functionalization | FUNCTIONALIZATION | INTERMOLECULAR SILYLATION | DIVERGENT | GERMANYLATION | BORYLATION | Bonds | Catalysis
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 05/2017, Volume 139, Issue 21, pp. 7399 - 7407
A metal-free B(C6F5)(3)-catalyzed approach is developed for the disproportionation reaction of a series of indoles with various hydrosilanes, without any... 
ELECTRON | HYDROGENATION | REDUCTION | INDOLINE | ARENES | POLYMERIZATION | HYDROSILATION | AROMATIC-SUBSTITUTION | C-H SILYLATION | CHEMISTRY, MULTIDISCIPLINARY | BOND SILYLATION
Journal Article
Science, ISSN 0036-8075, 2014, Volume 343, Issue 6173, pp. 853 - 857
Regioselective C-H functionalization of arenes has widespread applications in synthetic chemistry. The regioselectivity of these reactions is often controlled... 
ACTIVATION | HETEROARENES | DIRECT ARYLATION | DEHYDROGENATIVE SILYLATION | IRIDIUM COMPLEXES | MULTIDISCIPLINARY SCIENCES | BOND FUNCTIONALIZATION | CLEAVAGE | BORYLATION | INSIGHTS | Chemical reactions | Chemical properties | Research | Rhodium | Chemical research | Catalysts | Molecular biology | Catalysis
Journal Article