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Inorganic Chemistry, ISSN 0020-1669, 10/2013, Volume 52, Issue 19, pp. 11593 - 11599
Reaction of the donor-stabilized silylene 1 with [Cr(CO)6], [Mo(CO)6], [W(CO)6], or [Fe(CO)5] leads to the formation of the transition-metal silylene complexes... 
CARBONYL-COMPLEXES | BASE-STABILIZED SILYLENE | DIVALENT SILICON | STABLE SILYLENES | COVALENT RADII | N-HETEROCYCLIC SILYLENE | REACTIVITY | STRUCTURAL-CHARACTERIZATION | CRYSTAL-STRUCTURES | BIS(SILYLENE)IRON | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2012, Volume 18, Issue 42, pp. 13355 - 13360
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 09/2015, Volume 300, pp. 1 - 28
Journal Article
Dalton Transactions, ISSN 1477-9226, 2017, Volume 46, Issue 27, pp. 8868 - 8874
A platinum(0) complex bearing a cyclic (alkyl)(amino)silylene and a 1,3-divinyl-1,1,3,3-tetramethyldisiloxane (DVTMS) was synthesized and isolated in the form... 
ACTIVATION | HETEROCYCLIC SILYLENE | PINCER COMPLEXES | BIS(SILYLENE) | PLATINUM SILYLENE COMPLEXES | 2-COORDINATE | REACTIVITY | MULTIPLE BONDS | PAIR | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2012, Volume 51, Issue 46, pp. 11478 - 11482
Breaking the donor limits: The remarkable coordination chemistry of ECHE (E=Si, Ge) ligands with Group 9 metals (Ir, Rh) and their application in catalytic CH... 
iridium | germylene | pincer ligands | rhodium | silylene
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2011, Volume 17, Issue 12, pp. 3490 - 3499
The reactivity of the silylsilylene [{PhC(NtBu)2}SiSi(Cl){(NtBu)2C(H)Ph}] (2) towards diphenylacetylene, azobenzene, 2,6‐diisopropylphenyl azide, sulfur, and... 
carbene homologues | N ligands | silicon | chalcogens | silylenes | ACTIVATION | EXCITED-STATE | N-HETEROCYCLIC SILYLENE | ISOLABLE SILYLENE | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | DICHLOROSILYLENE | BONDS | CHEMISTRY | THERMALLY STABLE SILYLENE | Equivalence | Toluene | X-rays | Silicon | Formations | Selenium | Sulfur | NMR spectroscopy
Journal Article
Organometallics, ISSN 0276-7333, 04/2011, Volume 30, Issue 7, pp. 1748 - 1767
This account describes recent progress (>2006) in the synthesis and structural characterization of isolable N-heterocyclic silylenes (NHSi's) and their... 
SILICON-COMPOUNDS | YLIDE-LIKE SILYLENE | ISOLABLE DIALKYLSILYLENE | STABLE SILYLENE | CARBENE ANALOGS | DOUBLE-BONDS | GROUP 14 ELEMENTS | CHEMISTRY, ORGANIC | SILYLIDENE-PHOSPHANES | OXIDATIVE ADDITION | TRANSITION-METALS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 01/2016, Volume 55, Issue 1, pp. 188 - 192
Treatment of pyridine- stabilized silylene complexes [(eta(5)- C5Me4R)(CO)(2)(H)W= SiH(py)(Tsi)] (R= Me, Et; py = pyridine; Tsi = C(SiMe3)(3)) with an... 
STABLE SILYLENE | silaaldehydes | O HYDROGEN-BONDS | SILYL(SILYLENE)TUNGSTEN COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | BASE | silanones | SILANONE | silicon | tungsten | SILYLENE COMPLEXES | CHEMISTRY | DYNAMIC-BEHAVIOR | HYDRIDO(HYDROSILYLENE)TUNGSTEN COMPLEXES | metallacycles
Journal Article
Organometallics, ISSN 0276-7333, 12/2014, Volume 33, Issue 23, pp. 6885 - 6897
The first neutral bis­(metallylene)­pyridine pincer-type [ENE] ligands (E = SiII, GeII) were synthesized, and their coordination chemistry and reactivity... 
SILYLENE | HYDROGENATION | DONOR LIGANDS | BIS(SILYLENE) | REACTIVITY | DINITROGEN | CHEMISTRY, ORGANIC | BIS(IMINO)PYRIDINE IRON | DICARBONYL | BOND | ATOM | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2010, Volume 49, Issue 51, pp. 10002 - 10005
Twice, and faster: Reaction of the zwitterionic silylene 1 with AsH3 occurs stepwise at ambient temperature to give the first crystalline, donor‐stabilized... 
density functional calculations | N‐heterocyclic silylenes | arsanes | zwitterions | phosphanes | STABLE SILYLENE | N-heterocyclic silylenes | SILICON | COMPOUND | N-HETEROCYCLIC SILYLENE | REACTIVITY | SILYLIDENE-PHOSPHANES | CHEMISTRY, MULTIDISCIPLINARY | SUBSTITUTED DISILENES | DERIVATIVES | DOUBLE-BOND | DISILYNE RSISIR
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 08/2011, Volume 17, Issue 32, pp. 8803 - 8806
Tossing aldehydes into the ring: The reaction of a silacyclopentadienylidene with aldehydes leads to CO bond cleavage with the formation of base‐stabilized... 
aldehydes | silanones | silicon | ring expansion | silylenes | siloles | ACTIVATION | STABLE SILYLENE | CARBONYL-COMPOUNDS | ISOLABLE SILYLENE | CHEMISTRY, MULTIDISCIPLINARY | SILYLENE TRANSFER | OXASILACYCLOPROPANE | DOUBLE-BONDS | CHEMISTRY | GENERATION | Cleavage | Silicon | Formations | Aldehydes | Bonding
Journal Article
Angewandte Chemie, ISSN 0044-8249, 07/2019, Volume 131, Issue 30, pp. 10416 - 10420
A cyclic (amino)metal‐substituted dicoordinated silylene derivative has been synthesized and fully characterized. Of particular interest is that the... 
Metallacyclen | Strukturaufklärung | N-Heterocyclische Silylene | Rhodium | Silylene
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 58, pp. 8124 - 8127
An arene-tethered silylene ligand, L (L = PhC((BuN)-Bu-t)(2)SiCH2C(Bu-t)NAr, Ar = 2,6-(Pr2C6H3)-Pr-i), allowed the synthesis of three-coordinate Fe(ii)... 
FUNCTIONALIZATION | AMBIENT REACTION CONDITIONS | N-2 | COMPLEXES SYNTHESIS | STABLE SILYLENE | REDUCTION | AMMONIA | N-HETEROCYCLIC SILYLENE | REACTIVITY | MOLECULAR DINITROGEN | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2009, Volume 48, Issue 31, pp. 5683 - 5686
Stable? You can bottle it! The base‐stabilized dichlorosilylene L1SiCl2 (see picture; L1=1,3‐bis(2,6‐diisopropylphenyl)imidazol‐2‐ylidene) is stable at room... 
silicon | X‐ray diffraction | dichlorosilylene | silylenes | carbene ligands | Dichlorosilylene | Silylenes | X-ray diffraction | Carbene ligands | Silicon | ENERGY | STABLE SILYLENE | APPROXIMATION | REACTIVITY | TRICHLOROSILANE | CHEMISTRY, MULTIDISCIPLINARY | GERMANIUM(II) | CHEMISTRY | BOND | HYDROXIDE
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 10/2017, Volume 46, Issue 40, pp. 13628 - 13659
This article deals with the synthesis and reactivity of the bis(amidinato)silylene [iPrNC(Ph)NiPr] Si (5), the bis(guanidinato)silylene [iPrNC(NiPr )NiPr] Si... 
Journal Article