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ACS Catalysis, ISSN 2155-5435, 02/2016, Volume 6, Issue 2, pp. 1329 - 1333
A rapid and highly selective oxidative cross-coupling reaction between readily available and shelf-stable arylboronic acids and primary or secondary potassium... 
cross-coupling | oxidation | copper catalysis | single-electron transmetalation | organoboron | ACTIVATION | PHOTOREDOX | CHEMISTRY, PHYSICAL | cross-coupling oxidation | BROMIDES | NUCLEOPHILES | PRIMARY-ALKYL-HALIDES | LIGANDS | CHLORIDES | ARYL | C-H BORYLATION | GRIGNARD-REAGENTS
Journal Article
Chemical Reviews, ISSN 0009-2665, 09/2017, Volume 117, Issue 18, pp. 11796 - 11893
Flow chemistry involves the use of channels or tubing to conduct a reaction in a continuous stream rather than in a flask. Flow equipment provides chemists... 
LUMINESCENT SOLAR CONCENTRATOR | CROSS-COUPLING REACTIONS | ASYMMETRIC ALDOL REACTION | DIELS-ALDER REACTIONS | VISIBLE-LIGHT PHOTOCATALYSIS | SUPERCRITICAL CARBON-DIOXIDE | SUPPORTED PALLADIUM CATALYSTS | FORMAL TOTAL-SYNTHESIS | SINGLE-ELECTRON TRANSMETALATION | IN-SITU GENERATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 08/2015, Volume 80, Issue 16, pp. 7837 - 7848
Over the past two decades, organotrifluoroborates have evolved from being chemical curiosities to important reagents for the elaboration of organic molecules.... 
SUZUKI | SOLVOLYSIS | CROSS-COUPLING REACTIONS | BORONIC ACID | AMINOMETHYLATIONS | SCOPE | POTASSIUM ARYL | CHEMISTRY, ORGANIC | SINGLE-ELECTRON TRANSMETALATION | SALTS | ACCESS
Journal Article
ACS Catalysis, ISSN 2155-5435, 02/2016, Volume 6, Issue 2, pp. 873 - 877
We describe carbazolyl dicyanobenzene (CDCB)-based donor–acceptor (D–A) fluorophores as a class of cheap, easily accessible, and efficient metal-free... 
cross-coupling | photoredox catalysis | visible light | donor-acceptor fluorophores | nickel catalysis | OXIDATION | HALIDES | MERGING PHOTOREDOX | ACIDS | PHOTOCATALYSIS | CHEMISTRY, PHYSICAL | SINGLE-ELECTRON TRANSMETALATION | SYSTEMS | METAL-FREE | TRANSFORMATIONS
Journal Article
Organic Letters, ISSN 1523-7060, 02/2018, Volume 20, Issue 3, pp. 760 - 763
An efficient cross-coupling of sodium or lithium sulfinates with aryl iodides, using a combination of nickel and photoredox catalysis, is described. The dual... 
HALIDES | SODIUM | NICKEL CATALYSIS | SULFUR-DIOXIDE | CHEMISTRY, ORGANIC | SULFONES | INHIBITORS | SINGLE-ELECTRON TRANSMETALATION
Journal Article
ACS Catalysis, ISSN 2155-5435, 04/2017, Volume 7, Issue 4, pp. 2563 - 2575
Photoredox catalysis has experienced a revitalized interest from the synthesis community during the past decade. For example, photoredox/Ni dual catalysis... 
cross-coupling | nickel | catalysis | dual catalysis | photoredox | radicals | VISIBLE-LIGHT PHOTOCATALYSIS | TRANSITION-METAL-COMPLEXES | CHEMISTRY, PHYSICAL | CARBONYL-COMPOUNDS | SINGLE-ELECTRON TRANSMETALATION | C-H BONDS | PHENOL DERIVATIVES | BIDENTATE-CHELATION ASSISTANCE | CROSS-COUPLING REACTIONS | BORYLATED ARYL BROMIDES
Journal Article
Chemical Reviews, ISSN 0009-2665, 08/2018, Volume 118, Issue 16, pp. 7532 - 7585
Transition metal-catalyzed C–H bond functionalizations have been the focus of intensive research over the last decades for the formation of C–C bonds from... 
H FUNCTIONALIZATION | ROOM-TEMPERATURE | DIRECT ARYLATION | ARYL DIAZONIUM SALTS | VISIBLE-LIGHT PHOTOREDOX | PYRIDINE N-OXIDES | SINGLE-ELECTRON TRANSMETALATION | MEDIATED RADICAL ARYLDIFLUOROACETYLATION | CHEMISTRY, MULTIDISCIPLINARY | METAL-FREE | CARBOXYLIC-ACIDS | Chemical Sciences
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 06/2015, Volume 54, Issue 27, pp. 7929 - 7933
The direct decarboxylative arylation of -oxo acids has been achieved by synergistic visible-light-mediated photoredox and nickel catalysis. This method offers... 
decarboxylation | HOMOLYTIC ACYLATION | LIGHT | ALPHA-AMINO-ACIDS | SINGLE-ELECTRON TRANSMETALATION | CHEMISTRY, MULTIDISCIPLINARY | arylation | nickel catalysis | oxo acids | CROSS-COUPLING REACTIONS | C-H ARYLATION | CHEMISTRY | photoredox catalysis | CARBOXYLIC-ACIDS | Nickel | Catalysis | Architecture | Ketones | Acids
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2016, Volume 138, Issue 6, pp. 1760 - 1763
Ni-catalyzed cross-couplings of aryl, benzyl, and alkyl thiols with aryl and heteroaryl iodides were accomplished in the presence of an Ir-photoredox catalyst.... 
HALIDES | CONSTANTS | MECHANISM | LIGHT | C-S | STATE | SINGLE-ELECTRON TRANSMETALATION | BOND | CLEAVAGE | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | Sulfur compounds | Nickel compounds | Chemical properties | Catalysis | Research
Journal Article
Chemical Science, ISSN 2041-6520, 01/2016, Volume 7, Issue 1, pp. 85 - 88
A dual photoredox and gold-catalysed cross-coupling reaction of alkynyltrimethylsilanes and aryldiazonium tetrafluoroborates is described. The reaction... 
ARYLDIAZONIUM SALTS | ARENEDIAZONIUM SALTS | SONOGASHIRA | ARYL IODIDES | SINGLE-ELECTRON TRANSMETALATION | OXIDATIVE ADDITION | REDUCTIVE ELIMINATION | NONACTIVATED ARENES | DIRECT ALKYNYLATION | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS
Journal Article
Chemical Science, ISSN 2041-6520, 2016, Volume 8, Issue 1, pp. 530 - 535
The attractive field of iterative cross-coupling has seen numerous advances, although almost exclusively in the union of sp(2)-hybridized partners.... 
SILICATES | MERGING PHOTOREDOX | NICKEL CATALYSIS | ACIDS | STRATEGY | ARYLATION | SINGLE-ELECTRON TRANSMETALATION | EFFICIENT | TECHNOLOGY | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Organic Letters, ISSN 1523-7060, 06/2018, Volume 20, Issue 12, pp. 3605 - 3608
A three-component reaction of potassium alkyltrifluoroborates, the sulfur dioxide surrogate of DABCO·(SO2)2, and alkenes under photocatalysis in the presence... 
INSERTION | ACYL CHLORIDES | ALKYL | 3-COMPONENT REACTION | CATALYZED AMINOSULFONYLATION | CHEMISTRY | CHEMISTRY, ORGANIC | SINGLE-ELECTRON TRANSMETALATION | RADICAL GENERATION | DUAL CATALYSIS | CARBOXYLIC-ACIDS
Journal Article
Nature Communications, ISSN 2041-1723, 04/2016, Volume 7, Issue 1, p. 11065
The Suzuki-Miyaura cross-coupling is one of the most often utilized reactions in the synthesis of pharmaceutical compounds and conjugated materials. In its... 
ALKENES | ENANTIOSELECTIVE SYNTHESIS | RETENTION | STRATEGY | MULTIDISCIPLINARY SCIENCES | ESTERS | SECONDARY | SINGLE-ELECTRON TRANSMETALATION | INVERSION | DIBORATION | BORYLATION
Journal Article
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 02/2018, Volume 83, Issue 3, pp. 1551 - 1557
The photoredox cross-coupling of aryl halides and potassium alkyl trifluoroborates is a very effective means to form Csp(3)-Csp(2) bonds. However, this... 
ARYL BROMIDES | OXIDATION | SILICATES | CHEMISTRY, ORGANIC | SINGLE-ELECTRON TRANSMETALATION | DUAL CATALYSIS | ALKYLSILICATES
Journal Article
CHEMICAL SCIENCE, ISSN 2041-6520, 05/2017, Volume 8, Issue 5, pp. 3512 - 3522
A photoredox-catalyzed C-H functionalization of heteroarenes using a variety of primary, secondary, and tertiary alkyltrifluoroborates is reported. Using... 
BORONIC ACIDS | MEDICINAL CHEMISTRY | MINISCI REACTION | MARKOVNIKOV ALKENE HYDROFUNCTIONALIZATION | ONE-POT SYNTHESIS | PHOTOREDOX/NICKEL DUAL CATALYSIS | SINGLE-ELECTRON TRANSMETALATION | CHEMISTRY, MULTIDISCIPLINARY | RADICAL-CROSSOVER CYCLOADDITIONS | HETEROAROMATIC BASES | CARBOXYLIC-ACIDS
Journal Article
ACS Catalysis, ISSN 2155-5435, 01/2017, Volume 7, Issue 1, pp. 907 - 911
Journal Article