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site selectivity (212) 212
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Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 9404 - 9432
In this review, synthetic and mechanistic aspects of key methodologies that exploit C–C single-bond cleavage of strained ring systems are highlighted. The... 
INTERMOLECULAR ALKYNE INSERTION | CARBON-CARBON BOND | COUPLING REACTIONS | 3+2 INTRAMOLECULAR CYCLOADDITION | AMINO-SUBSTITUTED CYCLOPROPANES | SITE-SELECTIVITY | (3+2)+2 CARBOCYCLIZATION | OXIDATIVE CYCLIZATION | ENANTIOSELECTIVE CONSTRUCTION | CHEMISTRY, MULTIDISCIPLINARY | NICKEL-CATALYZED CYCLOADDITION
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2019, Volume 25, Issue 13, pp. 3144 - 3144
Solvent polarity decides! β‐[70]‐PCFM fullerenes ([6,6]‐Phenyl‐C61‐Formic acid Methyl ester) are formed as the major product in the reaction of C70 with... 
interface passivation | fullerenes | site-selectivity | cyclopropanation reaction | perovskite solar cells
Journal Article
Ichnos, ISSN 1042-0940, 01/2019, Volume 26, Issue 1, pp. 16 - 19
Crinoids are diverse and well-known from the Permian of Timor, but the literature has failed to document the numerous specimens of crinoid pluricolumnals from... 
Oichnus | Palaeoecology | Site selectivity: Artinskian | Paleopathology | PALEONTOLOGY | ICHNOGENUS | Artinskian | Site selectivity
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 06/2016, Volume 49, Issue 6, pp. 1292 - 1301
In most modern organic chemistry reports, including many of ours, reaction optimization schemes are typically presented to showcase how reaction conditions... 
DIRECTING GROUP | CHIRAL ANION | STERIC PARAMETERS | ALLYLIC ALCOHOLS | HIGH-THROUGHPUT DISCOVERY | FREE-ENERGY RELATIONSHIPS | ENANTIOSELECTIVE REACTION | HECK ARYLATIONS | TRANSFER HYDROGENATION | SITE-SELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 12/2018, Volume 59, Issue 51, pp. 4449 - 4453
[Display omitted] •Direct and regioselective CH functionalization of unactivated benzo[d]isoxazoles.•Visible-light-induced photocatalytic difluoroalkylation of... 
Site-selectivity | Benzo[d]isoxazoles | Difluoroalkylation | Visible-light photocatalysis
Journal Article
Catalysis Communications, ISSN 1566-7367, 04/2019, pp. 23 - 26
2,3-Bis[(2,6-diisopropylphenylimino)butane] nickel/MAO system toward ethylene polymerization displays two active sites with ultraviolet absorption bands at 456... 
Chain walking | Chain transfer | Active site selectivity | Ethylene | Polyethylene microstructure
Journal Article
Chemical Society Reviews, ISSN 0306-0012, 1/2018, Volume 47, Issue 1, pp. 149 - 171
The elaboration of simple arenes in order to access more complex substitution patterns is a crucial endeavor for synthetic chemists, given the central role... 
DIRECTING GROUP | REMOVABLE AUXILIARIES | U-SHAPED TEMPLATE | AMINO-ACID LIGANDS | SELECTIVE ARYLATION | RUTHENIUM CATALYSTS | SITE-SELECTIVITY | NONCOVALENT INTERACTIONS | CHEMISTRY, MULTIDISCIPLINARY | PHENOL DERIVATIVES | ARYLSULFONYL CHLORIDES
Journal Article
Chemical Communications, ISSN 1359-7345, 01/2016, Volume 52, Issue 7, pp. 1338 - 1341
An efficient, scalable, atom-economical, regio-selective air stable Cp*Co(III) catalyzed C-H and C-O coupling via a C-H activation/oxygen atom transfer... 
FUNCTIONALIZATION | POSITION | MILD CONDITIONS | ALLYLATION | EFFICIENT SYNTHESIS | AMIDATION | BOND ACTIVATION | SITE SELECTIVITY | CLEAVAGE | CHEMISTRY, MULTIDISCIPLINARY | CARBON-HYDROGEN | Alkynes - chemistry | Catalysis | Quinolines - chemistry | Cobalt - chemistry
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2013, Volume 135, Issue 42, pp. 15710 - 15713
This report describes the Na2PtCl4 catalyzed C–H arylation of arene substrates with diaryliodonium salts. The site selectivity of these reactions is... 
ACTIVATION | BENZENE | LIGANDS | SIGMA-ARYL COMPLEXES | BOND FUNCTIONALIZATION | SITE-SELECTIVITY | NAPHTHALENE | AROMATIC-COMPOUNDS | REDUCTIVE ELIMINATION | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 03/2017, Volume 19, Issue 5, pp. 1184 - 1187
Treatment of benzocyclobutenones bearing a triflyloxy group adjacent to the four-membered ring with organolithium reagents in the presence of arynophiles... 
KETONES | INSERTION | ACTIVATION | FACILE SYNTHESIS | CHEMISTRY | CHEMISTRY, ORGANIC | SITE-SELECTIVITY | NUCLEOPHILIC-ADDITION | N-ARYLATION | PRECURSORS | ALKYNE
Journal Article
by Fan, ZL and Lu, H and Zhang, A
JOURNAL OF ORGANIC CHEMISTRY, ISSN 0022-3263, 03/2018, Volume 83, Issue 6, pp. 3245 - 3251
[Graphics] To address the challenge of meta nitration of 6-arylpurine substrates, a versatile ruthenium catalyzed meta C-H nitration is developed. The use of a... 
FUNCTIONALIZATION | CROSS-COUPLING REACTIONS | ACTIVATION | PURINE | NUCLEOSIDES | ARENES | ARYLATION | 6-PHENYLPURINE | CHEMISTRY, ORGANIC | SITE-SELECTIVITY | REGIOSELECTIVITY
Journal Article
Synlett, ISSN 0936-5214, 11/2017, Volume 28, Issue 18, pp. 2415 - 2420
Abstract Allenylsilanolates can undergo cross-coupling at the α- or γ-terminus, and site selectivity appears to be determined by the intrinsic transmetalation... 
cluster | cross-coupling | allenes | palladium | site selectivity | organosilanes | transmetalation
Journal Article
Organic Letters, ISSN 1523-7060, 2019, Volume 21, Issue 7, pp. 2134 - 2138
High levels of catalyst control are demonstrated in determining the positional selectivity in C-H alkenylation of isoxazoles. A cationic rhodium-mediated,... 
ASSISTED SYNTHESIS | DIRECTING GROUPS | PALLADIUM | ACTIVATION | OLEFINATION | HETEROCYCLES | BOND FUNCTIONALIZATIONS | ISOMERIZATION | REACTIVITY | CHEMISTRY, ORGANIC | SITE-SELECTIVITY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2019, Volume 58, Issue 41, pp. 14615 - 14619
Incorporation of the CF3 group into arenes has found increasing importance in drug discovery. Herein, we report the first photoredox‐catalyzed cross‐coupling... 
photoredox catalysis | trifluoromethylation | late-stage C−H functionalization | site selectivity | sulfonium salts
Journal Article
Organic Letters, ISSN 1523-7060, 12/2016, Volume 18, Issue 24, pp. 6464 - 6467
A Rh­(III)-catalyzed annulation between salicylaldehydes and diazo compounds with controllable chemoselectivity is described. AgNTf2 favored benzofurans via a... 
EFFICIENT APPROACH | GOLD CATALYSIS | INSERTION REACTIONS | CHEMISTRY, ORGANIC | PYRIDINE N-OXIDES | SITE-SELECTIVITY | BOND ACTIVATION | INTERNAL ALKYNES | HECK REACTION | C-H ACTIVATION | ARYL-ALPHA-DIAZOACETATES
Journal Article
Organic Letters, ISSN 1523-7060, 07/2018, Volume 20, Issue 13, pp. 3776 - 3779
The first catalytic lactonization of unactivated aryl C–H bonds with CO2 to afford important phthalides is reported. Notably, this method features high... 
PALLADIUM | FUNCTIONALIZATIONS | CARBON-DIOXIDE UTILIZATION | CHEMISTRY, ORGANIC | DIRECT CARBOXYLATION | SITE-SELECTIVITY | MEDIATED CARBOXYLATION | AROMATIC-COMPOUNDS | DERIVATIVES | TRANSITION-METAL-FREE | CYCLIZATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2006, Volume 45, Issue 34, pp. 5616 - 5619
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2014, Volume 136, Issue 8, pp. 3013 - 3015
A Rh(I)-catalyzed formal carbene insertion into C–C bond of benzocyclobutenols has been realized by employing diazoesters as carbene precursors. The product... 
ALPHA-DIAZOCARBONYL COMPOUNDS | ACTIVATION | ENANTIOSELECTIVE SYNTHESIS | METAL CARBENE | CONSTRUCTION | SITE-SELECTIVITY | DIAZO-COMPOUNDS | ARYL | CATALYZED CARBON-CARBON | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | Chemical bonds | Influence | Chemical properties | Research | Rhodium | Carbenes
Journal Article
ACS Catalysis, ISSN 2155-5435, 09/2015, Volume 5, Issue 9, pp. 5031 - 5040
Quinoline is an important scaffold in many natural products, biologically active compounds, and functional materials. The C–H functionalization of quinoline... 
quinoline N-oxides | site-selectivity | C-H activation | transition metal catalysts | quinolines | RH(I)-CATALYZED DIRECT ARYLATION | CHEMISTRY, PHYSICAL | HETEROARENES SCOPE | NICKEL/LEWIS ACID CATALYSIS | N-OXIDES | HETEROAROMATIC-COMPOUNDS | OXIDATIVE OLEFINATION | ORGANOZINC REAGENTS | C-8 POSITION | BOND ACTIVATION | LATE-STAGE FUNCTIONALIZATION
Journal Article
Chemical Society (Great Britain). Chemical Society Reviews, ISSN 0306-0012, 01/2018, Volume 47, Issue 1, pp. 149 - 171
The elaboration of simple arenes in order to access more complex substitution patterns is a crucial endeavor for synthetic chemists, given the central role... 
Transition metals | Hydrogen bonds | Regioselectivity | Aromatic compounds | Metals | Chemists | Chemical bonds | Palladium | Catalysis
Journal Article
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