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by Sheng, DH and Zhang, Y and Song, QX and Xu, G and Peng, DD and Hou, HQ and Xie, RG and Shan, DM and Liu, PX
ORGANOMETALLICS, ISSN 0276-7333, 01/2020, Volume 39, Issue 1, pp. 51 - 57
MIL-100 and MIL-101 were synthesized and evacuated to generate a series of heterogeneous catalysts for isomerization of 1-butene. Their crystal structures and... 
MIL-100 | ALUMINUM | N-BUTENE | SKELETAL ISOMERIZATION | CO2 | SITES | CHEMISTRY, ORGANIC | FERRIERITE | ZEOLITE | CH4 | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ACS Catalysis, ISSN 2155-5435, 04/2015, Volume 5, Issue 4, pp. 2270 - 2274
The mechanism of the 1-butene skeletal isomerization catalyzed by zeolites has remained elusive. We present direct evidence that even the initial isobutene... 
monomolecular pathway | zeolites | C scrambling | 1-butene skeletal isomerization | molecular dynamics | SOLID ACID CATALYSTS | ISOBUTENE | CHEMISTRY, PHYSICAL | FERRIERITE | N-BUTENES | ORIGIN | FER ZEOLITE | REACTION-MECHANISM | COKE DEPOSITS | C-13 scrambling | DEACTIVATION
Journal Article
Energy & Fuels, ISSN 0887-0624, 11/2017, Volume 31, Issue 11, pp. 12691 - 12700
For the first time, a sequential fabrication step involving mechanochemistry, recrystallization, and dealumination was developed to convert low-cost natural... 
NATURAL MINERALS | ENGINEERING, CHEMICAL | SOLID ACID CATALYSTS | LARGE-PORT MORDENITE | SKELETAL ISOMERIZATION | ENERGY & FUELS | ALKANE ISOMERIZATION | DIMETHYL ETHER | X-RAY | H-MORDENITE | MOR ZEOLITES | HEXANE
Journal Article
Journal of Catalysis, ISSN 0021-9517, 10/2015, Volume 330, pp. 485 - 496
Journal Article
Industrial and Engineering Chemistry Research, ISSN 0888-5885, 08/2017, Volume 56, Issue 30, pp. 8456 - 8464
The stability of alumina-promoted sulfated zirconia (SZA) was investigated to achieve the isomerization of n-butane in a circulating fluidized bed (CFB) unit.... 
SURFACE-ACIDITY | ENGINEERING, CHEMICAL | SKELETAL ISOMERIZATION | MECHANISM | TEMPERATURE | ACTIVE-SITES | ALKYLATION | SULFATED ZIRCONIA CATALYSTS | HYDROISOMERIZATION | ALUMINA | DEACTIVATION
Journal Article
Applied Catalysis A, General, ISSN 0926-860X, 09/2016, Volume 526, pp. 70 - 76
[Display omitted] •Deactivated Nafion/SiO2 catalysts were regenerated by organic solvents.•Regenerations were both batch and continuous with solvents of... 
Regeneration | Octadecene | Deactivation | Isomerization | SAC-13 | SOLID ACID CATALYSTS | CARBENIUM IONS | ACYLATION | ALKYLATION | STABILITY | CHEMISTRY, PHYSICAL | ION-EXCHANGE-RESINS | ANISOLE | ENVIRONMENTAL SCIENCES | SKELETAL ISOMERIZATION | ACETIC-ANHYDRIDE | OLIGOMERIZATION
Journal Article
Journal of the American Oil Chemists' Society, ISSN 0003-021X, 11/2018, Volume 95, Issue 11, pp. 1357 - 1365
Recent research studies have shown that oleic acid can be isomerized to saturated C18 branched‐chain fatty acids through H+‐Mordenite with modest yields... 
Surface modification | H+‐Mordenite | Oleic acid | Isostearic acid | Mordenite | CHEMICAL LIQUID DEPOSITION | FOOD SCIENCE & TECHNOLOGY | TOLUENE | CATALYST | HZSM-5 | SKELETAL ISOMERIZATION | SITES | ZEOLITES | SILICA | CHEMISTRY, APPLIED | H+-Mordenite | SELECTIVITY
Journal Article
Journal of Catalysis, ISSN 0021-9517, 03/2016, Volume 335, pp. 11 - 23
Journal Article
Applied Catalysis A, General, ISSN 0926-860X, 01/2018, Volume 550, pp. 98 - 104
[Display omitted] •SZA and ZSM-5 have very different pore structures and acidity strength and distribution.•n-Butane makes isobutane over SZA, and propane with... 
Acidity | HZSM-5 | Alumina-promoted sulfated zirconia | Pore structures | n-Butane isomerization | SOLID ACID CATALYSTS | MECHANISM | ACTIVE-SITES | CHEMISTRY, PHYSICAL | ADSORPTION THERMODYNAMICS | MONOMOLECULAR CRACKING | ENVIRONMENTAL SCIENCES | SKELETAL ISOMERIZATION | SULFATED ZIRCONIA CATALYSTS | COKE FORMATION | H-MORDENITE | DEACTIVATION
Journal Article
Applied Catalysis A, General, ISSN 0926-860X, 05/2017, Volume 537, pp. 59 - 65
[Display omitted] •n-Pentane hydroisomerization reactions over Pt/WOx–ZrO2 and Pt/ZSM-22 were compared.•Pt/WOx–ZrO2 presents hydrogen spillover ability and... 
n-Pentane | Skeletal isomerization | Pt/ZSM-22 | Spatial confinement | Hydrogen spillover | Pt/WOx–ZrO2 | ZrO | Pt/WO | TUNGSTEN-OXIDE | MECHANISM | 1-PENTENE ISOMERIZATION | PLATINUM | CHEMISTRY, PHYSICAL | SULFATED ZIRCONIA | HYDROISOMERIZATION | SOLID ACIDS | HYDROGEN | ENVIRONMENTAL SCIENCES | ZEOLITES | Pt/WOx-ZrO2 | ALKANES
Journal Article
APPLIED CATALYSIS A-GENERAL, ISSN 0926-860X, 07/2017, Volume 542, pp. 311 - 316
The relationship between the heterogeneity of active sites and isomerization mechanism of n-butane over alumina-promoted sulfated zirconia (SZA) was elucidated... 
REGENERATION | RAMAN-SPECTROSCOPY | SOLID-ACID CATALYSTS | CHEMISTRY, PHYSICAL | Acidity | DOPED ZRO2 CATALYSTS | ALUMINA | n-Butane isomerization | Oxidizability | ENVIRONMENTAL SCIENCES | SKELETAL ISOMERIZATION | Reaction mechanism | SURFACE | SULFATED ZIRCONIA CATALYSTS | Alumina-promoted sulfated zirconia | H-MORDENITE | DEACTIVATION
Journal Article
Applied Surface Science, ISSN 0169-4332, 08/2016, Volume 378, pp. 489 - 495
[Display omitted] •Modification methods affect the acidity and redox properties of catalysts greatly.•Change in surface properties directly influences the... 
Impregnation | Alumina-promoted sulfated zirconia | Co-precipitation | n-Butane isomerization | ACID CATALYST | PHYSICS, CONDENSED MATTER | ACTIVATION | PHYSICS, APPLIED | MECHANISM | PENTANE ISOMERIZATION | CHEMISTRY, PHYSICAL | SULFATED-ZIRCONIA CATALYSTS | HYDROGEN | SKELETAL ISOMERIZATION | TEMPERATURE | NICKEL | MATERIALS SCIENCE, COATINGS & FILMS | ALKANES
Journal Article
Journal of Catalysis, ISSN 0021-9517, 03/2016, Volume 335, pp. 58 - 61
[Display omitted] •Acid site density effects in 1-butene skeletal isomerization over H-HPM-1 are examined.•Changes (⩽0.5 per unit cell) in framework Al atoms... 
Zeolite H-HPM-1 | 1-Butene skeletal isomerization | Catalyst durability | Brønsted acid site density | ENGINEERING, CHEMICAL | COKE DEPOSITS | CHEMISTRY, PHYSICAL | Bronsted acid site density | FERRIERITE | N-BUTENES | DEACTIVATION | Butylene | Zeolites | Isomerization
Journal Article
Journal of Catalysis, ISSN 0021-9517, 2014, Volume 319, Issue C, pp. 283 - 296
Acid strength effects on alkane isomerization turnover rates and selectivities are probed using hexene isomers as reactants on bifunctional catalysts... 
Heteropolyacids | Deprotonation energy | Keggin polyoxometalates | Bifunctional catalysis | Acid strength | Skeletal isomerization | Ion-pair transition state theory | AB-INITIO | CHEMISTRY, PHYSICAL | CATALYTIC-REACTIONS | SOLID ACIDS | ENGINEERING, CHEMICAL | DFT | CLUSTERS | DEHYDRATION | CONSEQUENCES | ZEOLITES | TUNGSTEN | Isomerization | Employee turnover | Catalysis | Olefins
Journal Article
Applied Catalysis A, General, ISSN 0926-860X, 11/2016, Volume 528, pp. 44 - 51
[Display omitted] •Development of Pt-H3PW12O40/SBA-15 bifunctional catalysts using dual encapsulation or encapsulation/impregnation.•Comparison of their... 
Heteropolyacids | Encapsulation | Bifunctional catalyst | n-hexane | isomerization | Platinum | SBA-15 | BUTANE | CSXH3-XPW12O40 | CHEMISTRY, PHYSICAL | SULFATED ZIRCONIA | SOLID ACIDS | ENVIRONMENTAL SCIENCES | HETEROPOLY ACIDS | SKELETAL ISOMERIZATION | H3PW12O40 | MESOPOROUS SILICA | SUPPORTED PLATINUM | ALKANES
Journal Article
Industrial & Engineering Chemistry Research, ISSN 0888-5885, 12/2014, Volume 53, Issue 50, pp. 19460 - 19470
The single-event kinetic modeling approach is applied to olefins cracking. Experimental data from the literature are used for model development and... 
ENGINEERING, CHEMICAL | SKELETAL ISOMERIZATION | RATE PARAMETERS | ISOMER GROUPS | OLEFINS PROCESS | CHEMICAL THERMODYNAMIC PROPERTIES | CATALYTIC CRACKING | COMPUTER-GENERATION | ZEOLITE | REACTION NETWORKS | N-BUTENES | Networks | Fracture mechanics | Rate constants | Pathways | Olefins | Isomerization | Reaction kinetics | Industrial engineering
Journal Article
Applied Catalysis A, General, ISSN 0926-860X, 08/2012, Volume 433-434, pp. 49 - 57
[Display omitted] ► The addition of WO3 modified the nature and concentration of the acidic sites. ► 13wt% WO3ZrO2 (13WZ) led to the strongest Lewis and... 
Hydrogen uptake | WO3[sbnd]ZrO2 | Protonic acid sites | Lewis acid sites | n-Butane isomerization | TUNGSTEN-OXIDE | ZIRCONIA | PENTANE ISOMERIZATION | PT/WO3-ZRO2 | PLATINUM | CHEMISTRY, PHYSICAL | SOLID ACID | ENVIRONMENTAL SCIENCES | ACID SITES | CALCINATION TEMPERATURE | WO3-ZrO2 | SKELETAL ISOMERIZATION | CATALYSTS
Journal Article
Catalysis Today, ISSN 0920-5861, 2003, Volume 81, Issue 1, pp. 3 - 16
Journal Article